Comparison of Hansen Solubility Parameter of Asphaltenes Extracted from Bitumen Produced in Different Geographical Regions
The Hansen solubility parameters (HSPs) of asphaltenes extracted from oil sand bitumen samples produced at Athabasca in Canada and also from a vacuum residue fraction (VR) produced in the Middle East were determined by the Hansen solubility sphere method. For calculation of HSPs, the solubilities of...
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Published in | Energy & fuels Vol. 28; no. 2; pp. 891 - 897 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Washington, DC
American Chemical Society
20.02.2014
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Abstract | The Hansen solubility parameters (HSPs) of asphaltenes extracted from oil sand bitumen samples produced at Athabasca in Canada and also from a vacuum residue fraction (VR) produced in the Middle East were determined by the Hansen solubility sphere method. For calculation of HSPs, the solubilities of asphaltenes were determined using a dynamic light scattering (DLS) method by dissolving or dispersing the asphaltenes in various solvents and measuring the particle size distributions thereof. The particle diameters of asphaltenes in good solvents were lower than its detection limit (<1 nm). It was demonstrated in the present study that asphaltenes differing in elemental composition had different HSP values corresponding to dispersion, dipole interaction, and hydrogen-bonding forces (δd, δp, and δh, respectively). Experimental results suggested that the differences in HSP values of the asphaltenes were influenced by the H/C ratio, oxygen content, and average asphaltene molecular weight. |
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AbstractList | The Hansen solubility parameters (HSPs) of asphaltenes extracted from oil sand bitumen samples produced at Athabasca in Canada and also from a vacuum residue fraction (VR) produced in the Middle East were determined by the Hansen solubility sphere method. For calculation of HSPs, the solubilities of asphaltenes were determined using a dynamic light scattering (DLS) method by dissolving or dispersing the asphaltenes in various solvents and measuring the particle size distributions thereof. The particle diameters of asphaltenes in good solvents were lower than its detection limit (<1 nm). It was demonstrated in the present study that asphaltenes differing in elemental composition had different HSP values corresponding to dispersion, dipole interaction, and hydrogen-bonding forces (δd, δₚ, and δₕ, respectively). Experimental results suggested that the differences in HSP values of the asphaltenes were influenced by the H/C ratio, oxygen content, and average asphaltene molecular weight. The Hansen solubility parameters (HSPs) of asphaltenes extracted from oil sand bitumen samples produced at Athabasca in Canada and also from a vacuum residue fraction (VR) produced in the Middle East were determined by the Hansen solubility sphere method. For calculation of HSPs, the solubilities of asphaltenes were determined using a dynamic light scattering (DLS) method by dissolving or dispersing the asphaltenes in various solvents and measuring the particle size distributions thereof. The particle diameters of asphaltenes in good solvents were lower than its detection limit (<1 nm). It was demonstrated in the present study that asphaltenes differing in elemental composition had different HSP values corresponding to dispersion, dipole interaction, and hydrogen-bonding forces (δd, δp, and δh, respectively). Experimental results suggested that the differences in HSP values of the asphaltenes were influenced by the H/C ratio, oxygen content, and average asphaltene molecular weight. The Hansen solubility parameters (HSPs) of asphaltenes extracted from oil sand bitumen samples produced at Athabasca in Canada and also from a vacuum residue fraction (VR) produced in the Middle East were determined by the Hansen solubility sphere method. For calculation of HSPs, the solubilities of asphaltenes were determined using a dynamic light scattering (DLS) method by dissolving or dispersing the asphaltenes in various solvents and measuring the particle size distributions thereof. The particle diameters of asphaltenes in good solvents were lower than its detection limit (<1 nm). It was demonstrated in the present study that asphaltenes differing in elemental composition had different HSP values corresponding to dispersion, dipole interaction, and hydrogen-bonding forces ( delta sub(d), delta sub(p), and delta sub(h), respectively). Experimental results suggested that the differences in HSP values of the asphaltenes were influenced by the H/C ratio, oxygen content, and average asphaltene molecular weight. |
Author | Yamamoto, Hideki Araki, Sadao Sato, Takashi Tanaka, Ryuzo Morimoto, Masato |
AuthorAffiliation | Department of Chemical, Energy and Environmental Engineering Faculty of Environmental and Urban Engineering Japan Petroleum Energy Center Kansai University National Institute of Advanced Industrial Science and Technology |
AuthorAffiliation_xml | – name: Kansai University – name: Japan Petroleum Energy Center – name: Department of Chemical, Energy and Environmental Engineering Faculty of Environmental and Urban Engineering – name: National Institute of Advanced Industrial Science and Technology |
Author_xml | – sequence: 1 givenname: Takashi surname: Sato fullname: Sato, Takashi – sequence: 2 givenname: Sadao surname: Araki fullname: Araki, Sadao – sequence: 3 givenname: Masato surname: Morimoto fullname: Morimoto, Masato – sequence: 4 givenname: Ryuzo surname: Tanaka fullname: Tanaka, Ryuzo – sequence: 5 givenname: Hideki surname: Yamamoto fullname: Yamamoto, Hideki email: yhideki@kansai-u.ac.jp |
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Keywords | Asphaltene Comparative study Solubility Bitumen |
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Snippet | The Hansen solubility parameters (HSPs) of asphaltenes extracted from oil sand bitumen samples produced at Athabasca in Canada and also from a vacuum residue... |
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SubjectTerms | Applied sciences Asphaltenes bitumen Bitumens Canada detection limit Dispersing Dispersions elemental composition Energy Energy. Thermal use of fuels Exact sciences and technology Fuels hydrogen bonding Light scattering Middle East molecular weight oxygen particle size distribution Solubility Solubility parameters Solvents |
Title | Comparison of Hansen Solubility Parameter of Asphaltenes Extracted from Bitumen Produced in Different Geographical Regions |
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