Synthesis of Stereoregular Uniform Oligomers Possessing a Dense 1,2,3-Triazole Backbone

• Published in: Macromolecules Vol. 56; no. 1; pp. 292 - 304
• Main Authors: Kamon, Yuri, Miura, Junji, Okuno, Koji, Yamasaki, Shota, Nakahata, Masaki, Hashidzume, Akihito
• Format: Journal Article
• Language: English; Japanese
• Published: American Chemical Society 10.01.2023; American Chemical Society (ACS)
• Subjects: absorption; acetone; circular dichroism spectroscopy; cycloaddition reactions; gelation; methanol; molecular weight; polymerization; solubility; tetrahydrofuran; toluene; X-ray diffraction

Recent remarkable progress of precision polymerization techniques has allowed researchers to synthesize polymers of controlled molecular weight, tacticity, and monomer sequence with narrow distributions. However, it is still a challenging subject to synthesize uniform polymers and oligomers, which p...