Mechanistic Insight into the Formation of Acetic Acid from the Direct Conversion of Methane and Carbon Dioxide on Zinc-Modified H–ZSM‑5 Zeolite
Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C1-building blocks into useful fuels and chemicals is a subject of great importance. By solid-state NMR spectroscopy, we found that methane and carbon dioxide can be co-converted on a zinc-modified H–ZSM-5 zeolite...
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| Published in | Journal of the American Chemical Society Vol. 135; no. 36; pp. 13567 - 13573 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
11.09.2013
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C1-building blocks into useful fuels and chemicals is a subject of great importance. By solid-state NMR spectroscopy, we found that methane and carbon dioxide can be co-converted on a zinc-modified H–ZSM-5 zeolite (denoted as Zn/H–ZSM-5) to form acetic acid at a low temperature range of 523–773 K. Solid-state 13C and 1H MAS NMR investigation indicates that the unique nature of the bifunctional Zn/H–ZSM-5 catalyst is responsible for this highly selective transformation. The zinc sites efficiently activate CH4 to form zinc methyl species (−Zn–CH3), the Zn–C bond of which is further subject to the CO2 insertion to produce surface acetate species (−Zn–OOCCH3). Moreover, the Brønsted acid sites play an important role for the final formation of acetic acid by the proton transfer to the surface acetate species. The results disclosed herein may offer the new possibility for the efficient activation and selective transformation of methane at low temperatures through the co-conversion strategy. Also, the mechanistic understanding of this process will help to the rational design of robust catalytic systems for the practical conversion of greenhouse gases into useful chemicals. |
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| AbstractList | Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C1-building blocks into useful fuels and chemicals is a subject of great importance. By solid-state NMR spectroscopy, we found that methane and carbon dioxide can be co-converted on a zinc-modified H-ZSM-5 zeolite (denoted as Zn/H-ZSM-5) to form acetic acid at a low temperature range of 523-773 K. Solid-state (13)C and (1)H MAS NMR investigation indicates that the unique nature of the bifunctional Zn/H-ZSM-5 catalyst is responsible for this highly selective transformation. The zinc sites efficiently activate CH4 to form zinc methyl species (-Zn-CH3), the Zn-C bond of which is further subject to the CO2 insertion to produce surface acetate species (-Zn-OOCCH3). Moreover, the Brønsted acid sites play an important role for the final formation of acetic acid by the proton transfer to the surface acetate species. The results disclosed herein may offer the new possibility for the efficient activation and selective transformation of methane at low temperatures through the co-conversion strategy. Also, the mechanistic understanding of this process will help to the rational design of robust catalytic systems for the practical conversion of greenhouse gases into useful chemicals. Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C1-building blocks into useful fuels and chemicals is a subject of great importance. By solid-state NMR spectroscopy, we found that methane and carbon dioxide can be co-converted on a zinc-modified H–ZSM-5 zeolite (denoted as Zn/H–ZSM-5) to form acetic acid at a low temperature range of 523–773 K. Solid-state 13C and 1H MAS NMR investigation indicates that the unique nature of the bifunctional Zn/H–ZSM-5 catalyst is responsible for this highly selective transformation. The zinc sites efficiently activate CH4 to form zinc methyl species (−Zn–CH3), the Zn–C bond of which is further subject to the CO2 insertion to produce surface acetate species (−Zn–OOCCH3). Moreover, the Brønsted acid sites play an important role for the final formation of acetic acid by the proton transfer to the surface acetate species. The results disclosed herein may offer the new possibility for the efficient activation and selective transformation of methane at low temperatures through the co-conversion strategy. Also, the mechanistic understanding of this process will help to the rational design of robust catalytic systems for the practical conversion of greenhouse gases into useful chemicals. Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C₁-building blocks into useful fuels and chemicals is a subject of great importance. By solid-state NMR spectroscopy, we found that methane and carbon dioxide can be co-converted on a zinc-modified H–ZSM-5 zeolite (denoted as Zn/H–ZSM-5) to form acetic acid at a low temperature range of 523–773 K. Solid-state ¹³C and ¹H MAS NMR investigation indicates that the unique nature of the bifunctional Zn/H–ZSM-5 catalyst is responsible for this highly selective transformation. The zinc sites efficiently activate CH₄ to form zinc methyl species (−Zn–CH₃), the Zn–C bond of which is further subject to the CO₂ insertion to produce surface acetate species (−Zn–OOCCH₃). Moreover, the Brønsted acid sites play an important role for the final formation of acetic acid by the proton transfer to the surface acetate species. The results disclosed herein may offer the new possibility for the efficient activation and selective transformation of methane at low temperatures through the co-conversion strategy. Also, the mechanistic understanding of this process will help to the rational design of robust catalytic systems for the practical conversion of greenhouse gases into useful chemicals. Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C1-building blocks into useful fuels and chemicals is a subject of great importance. By solid-state NMR spectroscopy, we found that methane and carbon dioxide can be co-converted on a zinc-modified H-ZSM-5 zeolite (denoted as Zn/H-ZSM-5) to form acetic acid at a low temperature range of 523-773 K. Solid-state (13)C and (1)H MAS NMR investigation indicates that the unique nature of the bifunctional Zn/H-ZSM-5 catalyst is responsible for this highly selective transformation. The zinc sites efficiently activate CH4 to form zinc methyl species (-Zn-CH3), the Zn-C bond of which is further subject to the CO2 insertion to produce surface acetate species (-Zn-OOCCH3). Moreover, the Brønsted acid sites play an important role for the final formation of acetic acid by the proton transfer to the surface acetate species. The results disclosed herein may offer the new possibility for the efficient activation and selective transformation of methane at low temperatures through the co-conversion strategy. Also, the mechanistic understanding of this process will help to the rational design of robust catalytic systems for the practical conversion of greenhouse gases into useful chemicals.Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C1-building blocks into useful fuels and chemicals is a subject of great importance. By solid-state NMR spectroscopy, we found that methane and carbon dioxide can be co-converted on a zinc-modified H-ZSM-5 zeolite (denoted as Zn/H-ZSM-5) to form acetic acid at a low temperature range of 523-773 K. Solid-state (13)C and (1)H MAS NMR investigation indicates that the unique nature of the bifunctional Zn/H-ZSM-5 catalyst is responsible for this highly selective transformation. The zinc sites efficiently activate CH4 to form zinc methyl species (-Zn-CH3), the Zn-C bond of which is further subject to the CO2 insertion to produce surface acetate species (-Zn-OOCCH3). Moreover, the Brønsted acid sites play an important role for the final formation of acetic acid by the proton transfer to the surface acetate species. The results disclosed herein may offer the new possibility for the efficient activation and selective transformation of methane at low temperatures through the co-conversion strategy. Also, the mechanistic understanding of this process will help to the rational design of robust catalytic systems for the practical conversion of greenhouse gases into useful chemicals. |
| Author | Wu, Jian-Feng Yu, Si-Min Wang, Wei David Bai, Shi Wang, Wei Zhang, Chuan-Wei Fan, Yan-Xin Gao, Qiang Huang, Jun |
| AuthorAffiliation | School of Chemical and Biomolecular Engineering State Key Laboratory of Applied Organic Chemistry Lanzhou Institute of Chemical Physics Chinese Academy of Sciences The University of Sydney National Engineering Research Center for Fine Petrochemical Intermediates Lanzhou University Laboratory for Catalysis Engineering College of Chemistry and Chemical Engineering |
| AuthorAffiliation_xml | – name: Laboratory for Catalysis Engineering – name: Chinese Academy of Sciences – name: National Engineering Research Center for Fine Petrochemical Intermediates – name: College of Chemistry and Chemical Engineering – name: School of Chemical and Biomolecular Engineering – name: State Key Laboratory of Applied Organic Chemistry – name: Lanzhou University – name: Lanzhou Institute of Chemical Physics – name: The University of Sydney |
| Author_xml | – sequence: 1 givenname: Jian-Feng surname: Wu fullname: Wu, Jian-Feng – sequence: 2 givenname: Si-Min surname: Yu fullname: Yu, Si-Min – sequence: 3 givenname: Wei David surname: Wang fullname: Wang, Wei David – sequence: 4 givenname: Yan-Xin surname: Fan fullname: Fan, Yan-Xin – sequence: 5 givenname: Shi surname: Bai fullname: Bai, Shi – sequence: 6 givenname: Chuan-Wei surname: Zhang fullname: Zhang, Chuan-Wei – sequence: 7 givenname: Qiang surname: Gao fullname: Gao, Qiang – sequence: 8 givenname: Jun surname: Huang fullname: Huang, Jun – sequence: 9 givenname: Wei surname: Wang fullname: Wang, Wei email: wang_wei@lzu.edu.cn |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/23981101$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1016/j.jcat.2004.04.029 10.1038/368231a0 10.1002/1521-3773(20000818)39:16<2928::AID-ANIE2928>3.0.CO;2-T 10.1021/jp8058273 10.1021/ja7110916 10.1021/ol800764u 10.1016/j.cattod.2004.09.004 10.1016/j.ssnmr.2009.01.005 10.1002/chem.201202802 10.1039/c0cs00011f 10.1246/cl.2001.1304 10.1021/ja0706302 10.1021/cr000411y 10.1002/anie.200500694 10.1002/anie.200800317 10.1016/S0167-2991(97)80347-3 10.1016/j.pnmrs.2007.08.001 10.1038/417507a 10.1002/anie.201200045 10.1016/S0167-2991(98)80790-8 10.1039/a804699i 10.1002/anie.199522071 10.1016/j.jcat.2006.02.018 10.1021/jp8067766 10.1016/j.cattod.2006.02.029 10.1016/j.cattod.2008.08.043 10.1016/j.jcat.2007.11.002 10.1021/ja309966j 10.1016/S0360-0564(06)50004-5 10.1002/aic.12073 10.1002/anie.201102320 10.1016/j.ccr.2004.05.019 10.1021/cr900122p 10.1016/S0920-5861(00)00456-9 10.1021/jp0728757 10.1021/cr068357u 10.1073/pnas.0910461106 10.1002/anie.201000533 10.1039/c1cs15008a 10.1021/ol0348856 10.1016/S0378-3820(03)00061-4 10.1021/ef0102770 10.1039/C1CS15009J 10.1021/om0510223 10.1039/c2sc20434g 10.1021/ar700210f 10.1021/cr00034a001 10.1002/chem.201002258 10.1002/anie.199516711 10.1016/j.cattod.2003.08.007 10.1016/j.catcom.2007.08.023 10.1002/anie.201104071 10.1002/anie.201108634 10.1002/anie.201000634 10.1006/jcat.2001.3223 10.1039/c2cp42066j 10.1016/j.jcat.2012.12.030 10.1002/1521-3773(20001215)39:24<4414::AID-ANIE4414>3.0.CO;2-C 10.1038/446391a 10.1002/anie.199520331 10.1021/cr00036a005 10.1021/ja00048a030 10.1021/ja047158u 10.1002/anie.201108706 10.1039/c0cs00033g 10.1134/S0023158410060121 10.1021/ja106283u 10.1016/S0009-2614(02)01866-3 10.1021/ol900528h 10.1002/0471433489 10.1021/ie2000192 10.1126/science.275.5304.1286 10.1080/01614949708007100 10.1016/j.fuproc.2004.09.003 10.1016/j.apcata.2012.07.024 10.1039/c2cc16882k 10.1246/cl.1995.244 |
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| References | Fujiwara Y. (ref4/cit4b) 1997; 107 Xu J. (ref8/cit8h) 2012; 3 Li L. (ref8/cit8i) 2011; 50 Stepanov A. G. (ref10/cit10f) 2010; 51 Bergman R. G. (ref2/cit2c) 2007; 446 Luzgin M. V. (ref8/cit8d) 2008; 47 Liu H. M. (ref9/cit9l) 2006; 239 He J. (ref9/cit9e) 2012; 51 Zheng H. (ref9/cit9m) 2008; 130 Jessop P. G. (ref22/cit22) 1994; 368 Luzgin M. V. (ref8/cit8e) 2009; 144 Kolyagin Y. G. (ref8/cit8b) 2008; 112 Sakakura T. (ref1/cit1d) 2007; 107 Huang W. (ref5/cit5h) 2010; 56 Jessop P. G. (ref23/cit23c) 2004; 248 Ma D. (ref9/cit9k) 2000; 39 Shi D. (ref21/cit21) 2004; 98 Ivanova I. I. (ref10/cit10d) 2010; 39 ref5/cit5a Havran V. (ref1/cit1e) 2011; 50 Huang W. (ref5/cit5d) 2004; 13 Ochiai H. (ref16/cit16) 2008; 10 Zhang R. G. (ref3/cit3c) 2012; 443 Zhang Y. P. (ref7/cit7c) 2003; 83 Smeets P. J. (ref9/cit9j) 2010; 132 Hunger M. (ref10/cit10b) 2008; 53 Wang W. (ref10/cit10c) 2008; 41 Nizova G. V. (ref4/cit4d) 1998 Zerella M. (ref4/cit4e) 2003; 5 Wang J. G. (ref3/cit3a) 2003; 368 Hammond C. (ref9/cit9b) 2012; 51 Eberstadt M. (ref14/cit14) 1995; 34 Liu C. J. (ref7/cit7a) 2001 Mulvey R. E. (ref15/cit15c) 2006; 25 Ding Y. H. (ref5/cit5e) 2007; 88 Wang W. (ref23/cit23f) 2011; 40 Wu J. F. (ref8/cit8f) 2010; 16 Sun M. (ref20/cit20) 2013; 135 Leitner W. (ref23/cit23b) 1995; 34 Wang X. M. (ref8/cit8g) 2012; 51 Zhang L. (ref10/cit10h) 2012; 48 Kolyagin Y. G. (ref8/cit8c) 2009; 35 Song C. S. (ref2/cit2b) 2006; 115 Lazo N. D. (ref12/cit12) 1992; 114 Wilcox E. M. (ref5/cit5c) 2003; 88 Panjan W. (ref3/cit3b) 2012; 14 Kobayashi K. (ref17/cit17) 2009; 11 Li Y. (ref7/cit7b) 2002; 16 Lunsford J. H. (ref1/cit1b) 2000; 63 Sellers H. (ref5/cit5g) 2009; 113 Woertink J. S. (ref9/cit9i) 2009; 106 Choudhary V. R. (ref9/cit9f) 1997; 275 Blasco T. (ref10/cit10e) 2010; 39 Copéret C. (ref2/cit2d) 2010; 110 Taniguchi Y. (ref4/cit4c) 1998; 114 Starokon E. V. (ref9/cit9d) 2013; 300 Boudier A. (ref15/cit15a) 2000; 39 Pu L. (ref15/cit15b) 2001; 101 Jessop P. G. (ref23/cit23a) 1995; 95 Yu K. M. K. (ref23/cit23d) 2007; 129 Crabtree R. H. (ref1/cit1a) 1995; 95 Hunger M. (ref10/cit10a) 2006; 50 Olah G. A. (ref1/cit1c) 2003 Zhang W. (ref10/cit10g) 2012; 41 Spivey J. J. (ref5/cit5f) 2008; 9 Metzger A. (ref18/cit18) 2010; 49 Hammond C. (ref9/cit9a) 2012; 18 Choudhary V. R. (ref9/cit9g) 2005; 44 Li L. (ref9/cit9c) 2012; 51 Kurioka M. (ref4/cit4a) 1995 Luzgin M. V. (ref13/cit13) 2007; 111 Labinger J. A. (ref2/cit2a) 2002; 417 Kazansky V. B. (ref8/cit8a) 2004; 225 Wesendrup R. (ref6/cit6) 1995; 34 Hunger M. (ref19/cit19) 1997; 39 Huang W. (ref5/cit5b) 2001; 201 Groothaert M. H. (ref9/cit9h) 2005; 127 Stepanov A. G. (ref11/cit11) 2008; 253 Federsel C. (ref23/cit23e) 2010; 49 |
| References_xml | – volume: 225 start-page: 369 year: 2004 ident: ref8/cit8a publication-title: J. Catal. doi: 10.1016/j.jcat.2004.04.029 – volume: 368 start-page: 231 year: 1994 ident: ref22/cit22 publication-title: Nature doi: 10.1038/368231a0 – volume: 39 start-page: 2928 year: 2000 ident: ref9/cit9k publication-title: Angew. Chem., Int. Ed. doi: 10.1002/1521-3773(20000818)39:16<2928::AID-ANIE2928>3.0.CO;2-T – volume: 113 start-page: 2340 year: 2009 ident: ref5/cit5g publication-title: J. Phys. Chem. C doi: 10.1021/jp8058273 – volume: 130 start-page: 3722 year: 2008 ident: ref9/cit9m publication-title: J. Am. Chem. Soc. doi: 10.1021/ja7110916 – volume: 10 start-page: 2681 year: 2008 ident: ref16/cit16 publication-title: Org. Lett. doi: 10.1021/ol800764u – volume: 98 start-page: 505 year: 2004 ident: ref21/cit21 publication-title: Catal. Today doi: 10.1016/j.cattod.2004.09.004 – volume: 35 start-page: 104 year: 2009 ident: ref8/cit8c publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/j.ssnmr.2009.01.005 – volume: 18 start-page: 15735 year: 2012 ident: ref9/cit9a publication-title: Chem.—Eur. J. doi: 10.1002/chem.201202802 – volume: 39 start-page: 5018 year: 2010 ident: ref10/cit10d publication-title: Chem. Soc. Rev. doi: 10.1039/c0cs00011f – start-page: 1304 year: 2001 ident: ref7/cit7a publication-title: Chem. Lett. doi: 10.1246/cl.2001.1304 – volume: 129 start-page: 6360 year: 2007 ident: ref23/cit23d publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0706302 – volume: 101 start-page: 757 year: 2001 ident: ref15/cit15b publication-title: Chem. Rev. doi: 10.1021/cr000411y – volume: 44 start-page: 4381 year: 2005 ident: ref9/cit9g publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200500694 – volume: 47 start-page: 4559 year: 2008 ident: ref8/cit8d publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200800317 – volume: 107 start-page: 275 year: 1997 ident: ref4/cit4b publication-title: Stud. Surf. Sci. Catal. doi: 10.1016/S0167-2991(97)80347-3 – volume: 53 start-page: 105 year: 2008 ident: ref10/cit10b publication-title: Prog. Nucl. Magn. Reson. Spectrosc. doi: 10.1016/j.pnmrs.2007.08.001 – volume: 417 start-page: 507 year: 2002 ident: ref2/cit2a publication-title: Nature doi: 10.1038/417507a – volume: 51 start-page: 4702 year: 2012 ident: ref9/cit9c publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201200045 – volume: 114 start-page: 439 year: 1998 ident: ref4/cit4c publication-title: Stud. Surf. Sci. Catal. doi: 10.1016/S0167-2991(98)80790-8 – start-page: 1885 year: 1998 ident: ref4/cit4d publication-title: Chem. Commun. doi: 10.1039/a804699i – volume: 34 start-page: 2207 year: 1995 ident: ref23/cit23b publication-title: Angew. Chem., Int. Ed. Engl. doi: 10.1002/anie.199522071 – volume: 239 start-page: 441 year: 2006 ident: ref9/cit9l publication-title: J. Catal. doi: 10.1016/j.jcat.2006.02.018 – volume: 112 start-page: 20065 year: 2008 ident: ref8/cit8b publication-title: J. Phys. Chem. C doi: 10.1021/jp8067766 – volume: 115 start-page: 2 year: 2006 ident: ref2/cit2b publication-title: Catal. Today doi: 10.1016/j.cattod.2006.02.029 – volume: 144 start-page: 265 year: 2009 ident: ref8/cit8e publication-title: Catal. Today doi: 10.1016/j.cattod.2008.08.043 – volume: 253 start-page: 11 year: 2008 ident: ref11/cit11 publication-title: J. Catal. doi: 10.1016/j.jcat.2007.11.002 – volume: 135 start-page: 804 year: 2013 ident: ref20/cit20 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja309966j – volume: 50 start-page: 149 year: 2006 ident: ref10/cit10a publication-title: Adv. Catal. doi: 10.1016/S0360-0564(06)50004-5 – volume: 56 start-page: 1279 year: 2010 ident: ref5/cit5h publication-title: AlChE J. doi: 10.1002/aic.12073 – volume: 50 start-page: 8299 year: 2011 ident: ref8/cit8i publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201102320 – ident: ref5/cit5a – volume: 248 start-page: 2425 year: 2004 ident: ref23/cit23c publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2004.05.019 – volume: 110 start-page: 656 year: 2010 ident: ref2/cit2d publication-title: Chem. Rev. doi: 10.1021/cr900122p – volume: 63 start-page: 165 year: 2000 ident: ref1/cit1b publication-title: Catal. Today doi: 10.1016/S0920-5861(00)00456-9 – volume: 111 start-page: 10624 year: 2007 ident: ref13/cit13 publication-title: J. Phys. Chem. C doi: 10.1021/jp0728757 – volume: 107 start-page: 2365 year: 2007 ident: ref1/cit1d publication-title: Chem. Rev. doi: 10.1021/cr068357u – volume: 106 start-page: 18908 year: 2009 ident: ref9/cit9i publication-title: Proc. Natl. Acad. Sci. U.S.A. doi: 10.1073/pnas.0910461106 – volume: 49 start-page: 6254 year: 2010 ident: ref23/cit23e publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201000533 – volume: 40 start-page: 3703 year: 2011 ident: ref23/cit23f publication-title: Chem. Soc. Rev. doi: 10.1039/c1cs15008a – volume: 5 start-page: 3193 year: 2003 ident: ref4/cit4e publication-title: Org. Lett. doi: 10.1021/ol0348856 – volume: 83 start-page: 101 year: 2003 ident: ref7/cit7c publication-title: Fuel Process. Technol. doi: 10.1016/S0378-3820(03)00061-4 – volume: 16 start-page: 864 year: 2002 ident: ref7/cit7b publication-title: Energy Fuels doi: 10.1021/ef0102770 – volume: 41 start-page: 192 year: 2012 ident: ref10/cit10g publication-title: Chem. Soc. Rev. doi: 10.1039/C1CS15009J – volume: 25 start-page: 1060 year: 2006 ident: ref15/cit15c publication-title: Organometallics doi: 10.1021/om0510223 – volume: 3 start-page: 2932 year: 2012 ident: ref8/cit8h publication-title: Chem. Sci. doi: 10.1039/c2sc20434g – volume: 41 start-page: 895 year: 2008 ident: ref10/cit10c publication-title: Acc. Chem. Res. doi: 10.1021/ar700210f – volume: 95 start-page: 259 year: 1995 ident: ref23/cit23a publication-title: Chem. Rev. doi: 10.1021/cr00034a001 – volume: 16 start-page: 14016 year: 2010 ident: ref8/cit8f publication-title: Chem.—Eur. J. doi: 10.1002/chem.201002258 – volume: 34 start-page: 1671 year: 1995 ident: ref14/cit14 publication-title: Angew. Chem., Int. Ed. Engl. doi: 10.1002/anie.199516711 – volume: 88 start-page: 83 year: 2003 ident: ref5/cit5c publication-title: Catal. Today doi: 10.1016/j.cattod.2003.08.007 – volume: 9 start-page: 685 year: 2008 ident: ref5/cit5f publication-title: Catal. Commun. doi: 10.1016/j.catcom.2007.08.023 – volume: 51 start-page: 2438 year: 2012 ident: ref9/cit9e publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201104071 – volume: 51 start-page: 3850 year: 2012 ident: ref8/cit8g publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201108634 – volume: 49 start-page: 4665 year: 2010 ident: ref18/cit18 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201000634 – volume: 201 start-page: 100 year: 2001 ident: ref5/cit5b publication-title: J. Catal. doi: 10.1006/jcat.2001.3223 – volume: 14 start-page: 16588 year: 2012 ident: ref3/cit3b publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/c2cp42066j – volume: 300 start-page: 47 year: 2013 ident: ref9/cit9d publication-title: J. Catal. doi: 10.1016/j.jcat.2012.12.030 – volume: 39 start-page: 4414 year: 2000 ident: ref15/cit15a publication-title: Angew. Chem., Int. Ed. doi: 10.1002/1521-3773(20001215)39:24<4414::AID-ANIE4414>3.0.CO;2-C – volume: 446 start-page: 391 year: 2007 ident: ref2/cit2c publication-title: Nature doi: 10.1038/446391a – volume: 34 start-page: 2033 year: 1995 ident: ref6/cit6 publication-title: Angew. Chem., Int. Ed. Engl. doi: 10.1002/anie.199520331 – volume: 95 start-page: 987 year: 1995 ident: ref1/cit1a publication-title: Chem. Rev. doi: 10.1021/cr00036a005 – volume: 114 start-page: 8552 year: 1992 ident: ref12/cit12 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00048a030 – volume: 127 start-page: 1394 year: 2005 ident: ref9/cit9h publication-title: J. Am. Chem. Soc. doi: 10.1021/ja047158u – volume: 51 start-page: 5129 year: 2012 ident: ref9/cit9b publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201108706 – volume: 39 start-page: 4685 year: 2010 ident: ref10/cit10e publication-title: Chem. Soc. Rev. doi: 10.1039/c0cs00033g – volume: 51 start-page: 854 year: 2010 ident: ref10/cit10f publication-title: Kinet. Catal. doi: 10.1134/S0023158410060121 – volume: 132 start-page: 14736 year: 2010 ident: ref9/cit9j publication-title: J. Am. Chem. Soc. doi: 10.1021/ja106283u – volume: 368 start-page: 313 year: 2003 ident: ref3/cit3a publication-title: Chem. Phys. Lett. doi: 10.1016/S0009-2614(02)01866-3 – volume: 11 start-page: 2035 year: 2009 ident: ref17/cit17 publication-title: Org. Lett. doi: 10.1021/ol900528h – volume-title: Hydrocarbon Chemistry year: 2003 ident: ref1/cit1c doi: 10.1002/0471433489 – volume: 50 start-page: 7089 year: 2011 ident: ref1/cit1e publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie2000192 – volume: 13 start-page: 113 year: 2004 ident: ref5/cit5d publication-title: J. Nat. Gas Chem. – volume: 275 start-page: 1286 year: 1997 ident: ref9/cit9f publication-title: Science doi: 10.1126/science.275.5304.1286 – volume: 39 start-page: 345 year: 1997 ident: ref19/cit19 publication-title: Catal. Rev.: Sci. Eng. doi: 10.1080/01614949708007100 – volume: 88 start-page: 319 year: 2007 ident: ref5/cit5e publication-title: Fuel Process. Technol. doi: 10.1016/j.fuproc.2004.09.003 – volume: 443 start-page: 50 year: 2012 ident: ref3/cit3c publication-title: Appl. Catal., A doi: 10.1016/j.apcata.2012.07.024 – volume: 48 start-page: 2370 year: 2012 ident: ref10/cit10h publication-title: Chem. Commun. doi: 10.1039/c2cc16882k – start-page: 244 year: 1995 ident: ref4/cit4a publication-title: Chem. Lett. doi: 10.1246/cl.1995.244 |
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| Snippet | Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C1-building blocks into useful fuels and chemicals is a subject of great... Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C₁-building blocks into useful fuels and chemicals is a subject of great... |
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| SubjectTerms | acetates acetic acid Acetic Acid - chemical synthesis Acetic Acid - chemistry carbon dioxide Carbon Dioxide - chemistry catalysts fuels gases greenhouse gases Magnetic Resonance Spectroscopy methane Methane - chemistry Models, Molecular Molecular Structure nuclear magnetic resonance spectroscopy stable isotopes temperature zeolites Zeolites - chemistry zinc Zinc - chemistry |
| Title | Mechanistic Insight into the Formation of Acetic Acid from the Direct Conversion of Methane and Carbon Dioxide on Zinc-Modified H–ZSM‑5 Zeolite |
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