Vanadium isotope composition of the Bulk Silicate Earth: Constraints from peridotites and komatiites

In order to apply the vanadium (V) stable isotope system for studies of planetary accretion and evolution in the solar system and redox variations in terrestrial magmatic processes, the V isotope composition of the Bulk Silicate Earth (BSE) needs to be precisely constrained. Previous studies have sh...

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Published inGeochimica et cosmochimica acta Vol. 259; pp. 288 - 301
Main Authors Qi, Yu-Han, Wu, Fei, Ionov, Dmitri A., Puchtel, Igor S., Carlson, Richard W., Nicklas, Robert W., Yu, Hui-Min, Kang, Jin-Ting, Li, Chun-Hui, Huang, Fang
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 15.08.2019
Elsevier
Subjects
Bulk Silicate Earth
Earth Sciences
Geochemistry
Komatiite
Partial melting
Peridotite
Sciences of the Universe
Vanadium isotopes
Vanadium isotopes
Peridotite
Partial melting
Komatiite
Bulk Silicate Earth
Earth Partial melting
Bulk Silicate
Online AccessGet full text
ISSN0016-7037
1872-9533
DOI10.1016/j.gca.2019.06.008

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Abstract In order to apply the vanadium (V) stable isotope system for studies of planetary accretion and evolution in the solar system and redox variations in terrestrial magmatic processes, the V isotope composition of the Bulk Silicate Earth (BSE) needs to be precisely constrained. Previous studies have shown that fertile peridotites have systematically higher 51V/50V ratios than MORB. This, however, is in conflict with the theoretical prediction that mantle melting residues should be enriched in 50V rather than 51V. To address these issues, a more precise estimate of the V isotope composition of the BSE is required. This study presents δ51V data for eleven peridotite xenoliths from two late Cenozoic eruption centers at Tariat in central Mongolia, ten komatiites from five localities ranging in age between 3.48 and 2.41 Ga, and four 1.98 Ga picrites from the Onega Plateau in Fennoscandia. The mean δ51V for fertile spinel lherzolites is −0.91 ± 0.06‰ (2SD, n = 8). They show no resolvable difference in V isotope compositions compared to three moderately to highly refractory peridotite xenoliths analyzed, with a mean δ51V of −0.93 ± 0.01‰ (2SD, n = 3). The mean δ51V for the komatiites is −0.91 ± 0.05‰ (2SD, n = 10), which is identical to that for the fertile peridotites. Based on the V isotope compositions of the peridotites and komatiites analyzed in this study, the mean δ51V of the BSE is estimated to be −0.91 ± 0.09‰ (2SD, n = 18). In contrast, the mean δ51V for the Onega Plateau picrites and related cumulates is −0.80 ± 0.05‰ (2SD, n = 4), which is identical to a recent δ51V estimate for MORB. The mean δ51V for picrites and MORB are somewhat higher than the new BSE estimate, indicating that low-degree (<10%) partial melts have higher δ51V than their mantle sources. The new estimate of δ51V for the BSE overlaps with current estimates for δ51V in the silicate Moon and Mars, which may imply that these bodies have a common V isotope composition.
AbstractList In order to apply the vanadium (V) stable isotope system for studies of planetary accretion and evolution in the solar system and redox variations in terrestrial magmatic processes, the V isotope composition of the Bulk Silicate Earth (BSE) needs to be precisely constrained. Previous studies have shown that fertile peridotites have systematically higher 51V/50V ratios than MORB. This, however, is in conflict with the theoretical prediction that mantle melting residues should be enriched in 50V rather than 51V. To address these issues, a more precise estimate of the V isotope composition of the BSE is required. This study presents δ51V data for eleven peridotite xenoliths from two late Cenozoic eruption centers at Tariat in central Mongolia, ten komatiites from five localities ranging in age between 3.48 and 2.41 Ga, and four 1.98 Ga picrites from the Onega Plateau in Fennoscandia. The mean δ51V for fertile spinel lherzolites is −0.91 ± 0.06‰ (2SD, n = 8). They show no resolvable difference in V isotope compositions compared to three moderately to highly refractory peridotite xenoliths analyzed, with a mean δ51V of −0.93 ± 0.01‰ (2SD, n = 3). The mean δ51V for the komatiites is −0.91 ± 0.05‰ (2SD, n = 10), which is identical to that for the fertile peridotites. Based on the V isotope compositions of the peridotites and komatiites analyzed in this study, the mean δ51V of the BSE is estimated to be −0.91 ± 0.09‰ (2SD, n = 18).In contrast, the mean δ51V for the Onega Plateau picrites and related cumulates is −0.80 ± 0.05‰ (2SD, n = 4), which is identical to a recent δ51V estimate for MORB. The mean δ51V for picrites and MORB are somewhat higher than the new BSE estimate, indicating that low-degree (<10%) partial melts have higher δ51V than their mantle sources. The new estimate of δ51V for the BSE overlaps with current estimates for δ51V in the silicate Moon and Mars, which may imply that these bodies have a common V isotope composition.
In order to apply the vanadium (V) stable isotope system for studies of planetary accretion and evolution in the solar system and redox variations in terrestrial magmatic processes, the V isotope composition of the Bulk Silicate Earth (BSE) needs to be precisely constrained. Previous studies have shown that fertile peridotites have systematically higher 51V/50V ratios than MORB. This, however, is in conflict with the theoretical prediction that mantle melting residues should be enriched in 50V rather than 51V. To address these issues, a more precise estimate of the V isotope composition of the BSE is required. This study presents δ51V data for eleven peridotite xenoliths from two late Cenozoic eruption centers at Tariat in central Mongolia, ten komatiites from five localities ranging in age between 3.48 and 2.41 Ga, and four 1.98 Ga picrites from the Onega Plateau in Fennoscandia. The mean δ51V for fertile spinel lherzolites is −0.91 ± 0.06‰ (2SD, n = 8). They show no resolvable difference in V isotope compositions compared to three moderately to highly refractory peridotite xenoliths analyzed, with a mean δ51V of −0.93 ± 0.01‰ (2SD, n = 3). The mean δ51V for the komatiites is −0.91 ± 0.05‰ (2SD, n = 10), which is identical to that for the fertile peridotites. Based on the V isotope compositions of the peridotites and komatiites analyzed in this study, the mean δ51V of the BSE is estimated to be −0.91 ± 0.09‰ (2SD, n = 18). In contrast, the mean δ51V for the Onega Plateau picrites and related cumulates is −0.80 ± 0.05‰ (2SD, n = 4), which is identical to a recent δ51V estimate for MORB. The mean δ51V for picrites and MORB are somewhat higher than the new BSE estimate, indicating that low-degree (<10%) partial melts have higher δ51V than their mantle sources. The new estimate of δ51V for the BSE overlaps with current estimates for δ51V in the silicate Moon and Mars, which may imply that these bodies have a common V isotope composition.
Author Puchtel, Igor S.
Yu, Hui-Min
Ionov, Dmitri A.
Nicklas, Robert W.
Li, Chun-Hui
Wu, Fei
Huang, Fang
Carlson, Richard W.
Kang, Jin-Ting
Qi, Yu-Han
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  orcidid: 0000-0003-1617-3187
  surname: Wu
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  givenname: Dmitri A.
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  surname: Ionov
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  givenname: Robert W.
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  fullname: Nicklas, Robert W.
  organization: Department of Geology, University of Maryland, College Park, MD 20742, USA
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  givenname: Hui-Min
  surname: Yu
  fullname: Yu, Hui-Min
  organization: CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, Anhui, China
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  givenname: Jin-Ting
  surname: Kang
  fullname: Kang, Jin-Ting
  organization: CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, Anhui, China
– sequence: 9
  givenname: Chun-Hui
  surname: Li
  fullname: Li, Chun-Hui
  email: geochemi@ustc.edu.cn
  organization: CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, Anhui, China
– sequence: 10
  givenname: Fang
  orcidid: 0000-0003-1885-3311
  surname: Huang
  fullname: Huang, Fang
  email: fhuang@ustc.edu.cn
  organization: CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, Anhui, China
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Keywords Vanadium isotopes
Peridotite
Partial melting
Komatiite
Bulk Silicate Earth
Earth Partial melting
Bulk Silicate
Language English
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Snippet In order to apply the vanadium (V) stable isotope system for studies of planetary accretion and evolution in the solar system and redox variations in...
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SubjectTerms Bulk Silicate Earth
Earth Sciences
Geochemistry
Komatiite
Partial melting
Peridotite
Sciences of the Universe
Vanadium isotopes
Title Vanadium isotope composition of the Bulk Silicate Earth: Constraints from peridotites and komatiites
URI https://dx.doi.org/10.1016/j.gca.2019.06.008
https://hal.umontpellier.fr/hal-02190228
Volume 259
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