Rational Design and Synthesis of Porous Organic−Inorganic Hybrid Frameworks Constructed by 1,3,5-Benzenetriphosphonic Acid and Pyridine Synthons

• Published in: Inorganic chemistry Vol. 45; no. 3; pp. 977 - 986
• Main Authors: Kong, Deyuan, Zoñ, Jerzy, McBee, Jennifer, Clearfield, Abraham
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 06.02.2006

1,3,5-Benzenetriphosphonic acid, H6BTP, 1,3,5-[(HO)2OP]3C6H3, was reacted hydrothermally with copper salts in the absence and presence of 4,4‘-bipyridine (bpy) and 4,4‘-trimethlyenedipyridine (tbpy) in a 1:1 molar ratio leading to three new organic−inorganic hybrid frameworks. Compound 1, {Cu6[C6H3(...