Zirconium(IV) Phosphonate–Phosphates as Efficient Ion-Exchange Materials
Layered metal phosphonate–phosphate hybrid materials are known to be ion-exchange materials. Hybrids with zirconium metal centers were synthesized at varying phosphonate–phosphate ratios in order to explore the function and charge preference. The zirconium hybrid materials were found to have a range...
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| Published in | Inorganic chemistry Vol. 55; no. 4; pp. 1651 - 1656 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
15.02.2016
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| Online Access | Get full text |
| ISSN | 0020-1669 1520-510X |
| DOI | 10.1021/acs.inorgchem.5b02555 |
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| Abstract | Layered metal phosphonate–phosphate hybrid materials are known to be ion-exchange materials. Hybrids with zirconium metal centers were synthesized at varying phosphonate–phosphate ratios in order to explore the function and charge preference. The zirconium hybrid materials were found to have a range of applicable uses with preference for highly charged ions (3+) over lower charged ions (1+ and 2+). The addition of a large excess of phosphate altered the selectivity, and these materials were able to remove all ions from solution regardless of charge. In this paper, we describe newly synthesized compounds that are simple to prepare, reproducible, stable, and offer a variety of separation schemes. |
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| AbstractList | Layered metal phosphonate-phosphate hybrid materials are known to be ion-exchange materials. Hybrids with zirconium metal centers were synthesized at varying phosphonate-phosphate ratios in order to explore the function and charge preference. The zirconium hybrid materials were found to have a range of applicable uses with preference for highly charged ions (3+) over lower charged ions (1+ and 2+). The addition of a large excess of phosphate altered the selectivity, and these materials were able to remove all ions from solution regardless of charge. In this paper, we describe newly synthesized compounds that are simple to prepare, reproducible, stable, and offer a variety of separation schemes. |
| Author | Silbernagel, Rita Martin, Caroline H Clearfield, Abraham |
| AuthorAffiliation | Department of Chemistry Texas A&M University |
| AuthorAffiliation_xml | – name: Texas A&M University – name: Department of Chemistry |
| Author_xml | – sequence: 1 givenname: Rita surname: Silbernagel fullname: Silbernagel, Rita – sequence: 2 givenname: Caroline H surname: Martin fullname: Martin, Caroline H – sequence: 3 givenname: Abraham surname: Clearfield fullname: Clearfield, Abraham email: Clearfield@chem.tamu.edu |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26821183$$D View this record in MEDLINE/PubMed |
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| Snippet | Layered metal phosphonate–phosphate hybrid materials are known to be ion-exchange materials. Hybrids with zirconium metal centers were synthesized at varying... Layered metal phosphonate-phosphate hybrid materials are known to be ion-exchange materials. Hybrids with zirconium metal centers were synthesized at varying... |
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| Title | Zirconium(IV) Phosphonate–Phosphates as Efficient Ion-Exchange Materials |
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