Layer Structure Preservation during Swelling, Pillaring, and Exfoliation of a Zeolite Precursor
MCM-22(P), the precursor to zeolite MCM-22, consists of stacks of layers that can be swollen and exfoliated to produce catalytically active materials. However, the current swelling procedures result in significant degradation of crystal morphology along with partial loss of crystallinity and dissolu...
Saved in:
| Published in | Journal of the American Chemical Society Vol. 130; no. 4; pp. 1507 - 1516 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
30.01.2008
|
| Online Access | Get full text |
Cover
Loading…
| Abstract | MCM-22(P), the precursor to zeolite MCM-22, consists of stacks of layers that can be swollen and exfoliated to produce catalytically active materials. However, the current swelling procedures result in significant degradation of crystal morphology along with partial loss of crystallinity and dissolution of the crystalline phase. Fabrication of polymer nanocomposites and coatings with MCM-22 for separation, barrier, and other applications requires a swelling method that does not alter drastically the crystal morphology and layer structure and preserves the high aspect ratio of the layers. Here, we demonstrate such a method by swelling MCM-22(P) at room temperature. The low-temperature process does not disrupt the framework connectivity present in the parent MCM-22(P) material. By extensive washing with water, the swollen material, MCM-22(PS-RT), evolves to a new ordered layered structure. Interestingly, the swelling procedure is reversible and the swollen material can be restored back to MCM-22(P) by acidification of the sample. The swollen material can also be pillared to produce an MCM-36 analogue. It can also be exfoliated, and layers can be incorporated in a polymer matrix to make nanocomposites. |
|---|---|
| AbstractList | MCM-22(P), the precursor to zeolite MCM-22, consists of stacks of layers that can be swollen and exfoliated to produce catalytically active materials. However, the current swelling procedures result in significant degradation of crystal morphology along with partial loss of crystallinity and dissolution of the crystalline phase. Fabrication of polymer nanocomposites and coatings with MCM-22 for separation, barrier, and other applications requires a swelling method that does not alter drastically the crystal morphology and layer structure and preserves the high aspect ratio of the layers. Here, we demonstrate such a method by swelling MCM-22(P) at room temperature. The low-temperature process does not disrupt the framework connectivity present in the parent MCM-22(P) material. By extensive washing with water, the swollen material, MCM-22(PS-RT), evolves to a new ordered layered structure. Interestingly, the swelling procedure is reversible and the swollen material can be restored back to MCM-22(P) by acidification of the sample. The swollen material can also be pillared to produce an MCM-36 analogue. It can also be exfoliated, and layers can be incorporated in a polymer matrix to make nanocomposites. MCM-22(P), the precursor to zeolite MCM-22, consists of stacks of layers that can be swollen and exfoliated to produce catalytically active materials. However, the current swelling procedures result in significant degradation of crystal morphology along with partial loss of crystallinity and dissolution of the crystalline phase. Fabrication of polymer nanocomposites and coatings with MCM-22 for separation, barrier, and other applications requires a swelling method that does not alter drastically the crystal morphology and layer structure and preserves the high aspect ratio of the layers. Here, we demonstrate such a method by swelling MCM-22(P) at room temperature. The low-temperature process does not disrupt the framework connectivity present in the parent MCM-22(P) material. By extensive washing with water, the swollen material, MCM-22(PS-RT), evolves to a new ordered layered structure. Interestingly, the swelling procedure is reversible and the swollen material can be restored back to MCM-22(P) by acidification of the sample. The swollen material can also be pillared to produce an MCM-36 analogue. It can also be exfoliated, and layers can be incorporated in a polymer matrix to make nanocomposites.MCM-22(P), the precursor to zeolite MCM-22, consists of stacks of layers that can be swollen and exfoliated to produce catalytically active materials. However, the current swelling procedures result in significant degradation of crystal morphology along with partial loss of crystallinity and dissolution of the crystalline phase. Fabrication of polymer nanocomposites and coatings with MCM-22 for separation, barrier, and other applications requires a swelling method that does not alter drastically the crystal morphology and layer structure and preserves the high aspect ratio of the layers. Here, we demonstrate such a method by swelling MCM-22(P) at room temperature. The low-temperature process does not disrupt the framework connectivity present in the parent MCM-22(P) material. By extensive washing with water, the swollen material, MCM-22(PS-RT), evolves to a new ordered layered structure. Interestingly, the swelling procedure is reversible and the swollen material can be restored back to MCM-22(P) by acidification of the sample. The swollen material can also be pillared to produce an MCM-36 analogue. It can also be exfoliated, and layers can be incorporated in a polymer matrix to make nanocomposites. |
| Author | Maheshwari, Sudeep Bates, Frank S Penn, R. Lee Jordan, Edgar Shantz, Daniel F Kumar, Sandeep Tsapatsis, Michael |
| Author_xml | – sequence: 1 givenname: Sudeep surname: Maheshwari fullname: Maheshwari, Sudeep – sequence: 2 givenname: Edgar surname: Jordan fullname: Jordan, Edgar – sequence: 3 givenname: Sandeep surname: Kumar fullname: Kumar, Sandeep – sequence: 4 givenname: Frank S surname: Bates fullname: Bates, Frank S – sequence: 5 givenname: R. Lee surname: Penn fullname: Penn, R. Lee – sequence: 6 givenname: Daniel F surname: Shantz fullname: Shantz, Daniel F – sequence: 7 givenname: Michael surname: Tsapatsis fullname: Tsapatsis, Michael |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/18179218$$D View this record in MEDLINE/PubMed |
| BookMark | eNpt0E1P3DAQBmALgWChPfQPVLm0UqUGPM6Hk2NFoSBWdNWFSy-WnUwqb7MxHTsF_n3dDewBcfKM9MzI8x6y3cENyNg74MfABZysNJdSAtgdNoNC8LQAUe6yGedcpLIqswN26P0qtrmoYJ8dQAWyFlDNmJrrR6RkGWhswkiYLAg90l8drBuSdiQ7_EqW99j3sficLGzfa9qUemiTs4fO9Xayrkt08hNjHzZbmpG8ozdsr9O9x7dP7xG7PT-7Ob1I59-_XZ5-mac6BxlSnWVQ1XUZz8FWdqbUpsjaRghd5C0WCKVpjOEgq1ryukRhCiGLNuIO0YDJjtjHae8duT8j-qDW1jfx23pAN3oluRBS5nmE75_gaNbYqjuya02P6jmSCE4m0JDznrBTjQ2bEwNp2yvg6n_oaht6nPj0YmK79BWbTtb6gA9bqOm3KmUmC3WzWKrqa1lXF9dX6kf0HyavG69WbqQhpvjK3n9H0Z0u |
| CitedBy_id | crossref_primary_10_1002_ange_200705755 crossref_primary_10_1039_C7DT00698E crossref_primary_10_1246_cl_170850 crossref_primary_10_1016_j_apcata_2015_07_003 crossref_primary_10_1039_D0GC00136H crossref_primary_10_1021_cm202364q crossref_primary_10_1021_la505037f crossref_primary_10_1149_2_0601409jes crossref_primary_10_1038_ncomms11811 crossref_primary_10_1021_acs_jpclett_1c01448 crossref_primary_10_1007_s11244_015_0391_z crossref_primary_10_1007_s40242_024_4099_0 crossref_primary_10_1016_j_catcom_2008_04_016 crossref_primary_10_1016_j_molcata_2015_06_006 crossref_primary_10_1126_sciadv_aay8163 crossref_primary_10_1002_cphc_201301033 crossref_primary_10_1039_C9CY00518H crossref_primary_10_1016_j_mcat_2022_112642 crossref_primary_10_1007_s40843_017_9227_y crossref_primary_10_2139_ssrn_4105332 crossref_primary_10_1039_C7DT02241G crossref_primary_10_1038_s41563_020_00822_2 crossref_primary_10_1002_cctc_201600322 crossref_primary_10_1016_j_micromeso_2017_06_045 crossref_primary_10_1016_j_cattod_2011_06_035 crossref_primary_10_3390_catal11030299 crossref_primary_10_1002_anie_202304734 crossref_primary_10_1039_D2CC00617K crossref_primary_10_1134_S0965544124020129 crossref_primary_10_1002_ange_201506822 crossref_primary_10_1021_cm401119d crossref_primary_10_1039_c4dt00165f crossref_primary_10_1002_cctc_202200535 crossref_primary_10_1007_s10562_014_1411_5 crossref_primary_10_1016_j_jcat_2023_115256 crossref_primary_10_1016_j_memsci_2009_10_014 crossref_primary_10_1021_ja908864g crossref_primary_10_1021_jp507719y crossref_primary_10_1002_mame_202000406 crossref_primary_10_1039_C2RA21573J crossref_primary_10_1016_j_micromeso_2020_110251 crossref_primary_10_1039_C4DT00383G crossref_primary_10_1002_chem_201300096 crossref_primary_10_1016_j_micromeso_2013_09_041 crossref_primary_10_1016_j_clay_2012_01_005 crossref_primary_10_1039_c4dt00130c crossref_primary_10_1016_j_micromeso_2018_12_030 crossref_primary_10_1016_j_jcat_2019_02_024 crossref_primary_10_1016_j_micromeso_2019_03_048 crossref_primary_10_1039_D2CE01407F crossref_primary_10_1016_j_micromeso_2016_12_004 crossref_primary_10_1002_admi_202100356 crossref_primary_10_1021_acs_chemrev_0c00016 crossref_primary_10_1021_acs_jpcc_8b02946 crossref_primary_10_1021_cm403527t crossref_primary_10_1039_C7RE00138J crossref_primary_10_1016_j_desal_2022_116023 crossref_primary_10_1021_cs300543z crossref_primary_10_1021_ja111147z crossref_primary_10_1016_j_apcata_2013_10_053 crossref_primary_10_1016_j_jcat_2014_12_022 crossref_primary_10_1021_ie8019032 crossref_primary_10_3390_ma13081822 crossref_primary_10_1002_anie_201506822 crossref_primary_10_1016_j_cjche_2024_12_012 crossref_primary_10_1039_C7CC03256K crossref_primary_10_1016_j_cattod_2012_07_040 crossref_primary_10_1002_cjoc_201700607 crossref_primary_10_1002_cctc_201600120 crossref_primary_10_1080_01614940_2021_1948298 crossref_primary_10_1039_C4TA01692K crossref_primary_10_1016_j_micromeso_2018_08_010 crossref_primary_10_1021_acscatal_5b02862 crossref_primary_10_1021_cm401914u crossref_primary_10_1021_acscatal_0c05332 crossref_primary_10_1021_acs_iecr_0c02409 crossref_primary_10_3390_nano11092327 crossref_primary_10_1007_s10934_022_01304_3 crossref_primary_10_1002_admi_202001409 crossref_primary_10_1016_j_micromeso_2010_11_025 crossref_primary_10_1021_cm4022326 crossref_primary_10_1039_C7ME00097A crossref_primary_10_3390_molecules28134960 crossref_primary_10_1007_s10934_012_9625_7 crossref_primary_10_1016_j_micromeso_2014_06_029 crossref_primary_10_1039_C7TA01792H crossref_primary_10_1039_D2QI00611A crossref_primary_10_1007_s10934_020_00982_1 crossref_primary_10_1021_ie300266p crossref_primary_10_1016_j_micromeso_2014_12_014 crossref_primary_10_1093_nsr_nwac045 crossref_primary_10_2139_ssrn_4171409 crossref_primary_10_1016_j_apcatb_2023_123536 crossref_primary_10_1021_jp910543r crossref_primary_10_1021_cs100042r crossref_primary_10_3390_nano13131942 crossref_primary_10_1039_C5CY00145E crossref_primary_10_1016_j_apcata_2011_12_046 crossref_primary_10_1039_C8DT03044H crossref_primary_10_1016_j_jcat_2016_01_031 crossref_primary_10_1126_science_1208891 crossref_primary_10_1126_science_1205957 crossref_primary_10_1016_j_micromeso_2016_11_007 crossref_primary_10_1021_nn9011829 crossref_primary_10_1021_acs_chemmater_7b02062 crossref_primary_10_1039_D2CP03391G crossref_primary_10_1007_s10853_021_06488_8 crossref_primary_10_1039_C5RA08621C crossref_primary_10_1016_j_micromeso_2014_02_026 crossref_primary_10_1016_j_micromeso_2018_10_009 crossref_primary_10_1016_j_micromeso_2018_04_017 crossref_primary_10_1039_D4DT00288A crossref_primary_10_1016_j_cattod_2016_10_033 crossref_primary_10_1016_j_apcata_2015_02_020 crossref_primary_10_1039_D3CC05427F crossref_primary_10_1016_j_biombioe_2025_107662 crossref_primary_10_1016_j_micromeso_2010_09_017 crossref_primary_10_1002_ange_201708835 crossref_primary_10_1039_C7NJ00740J crossref_primary_10_1039_C5CS00508F crossref_primary_10_1021_acs_jpcc_3c07621 crossref_primary_10_1039_C4TA01384K crossref_primary_10_1016_j_jiec_2022_02_038 crossref_primary_10_1134_S0965544118100158 crossref_primary_10_1016_j_cattod_2013_04_035 crossref_primary_10_1016_j_apcata_2018_12_029 crossref_primary_10_1039_D2QI00928E crossref_primary_10_1021_acs_jpclett_5b01004 crossref_primary_10_1002_aenm_201600441 crossref_primary_10_1039_C8TA09826C crossref_primary_10_1039_C5NJ02809D crossref_primary_10_1016_j_memsci_2013_03_044 crossref_primary_10_1016_j_cattod_2022_07_024 crossref_primary_10_1039_C5SC01912E crossref_primary_10_1016_j_cattod_2019_03_006 crossref_primary_10_1016_j_cej_2025_160714 crossref_primary_10_1016_j_coco_2024_102032 crossref_primary_10_1016_j_micromeso_2014_10_028 crossref_primary_10_1002_aic_14462 crossref_primary_10_1039_C5RA02912K crossref_primary_10_5402_2012_537164 crossref_primary_10_1016_S1872_2067_15_60887_7 crossref_primary_10_1039_c0cy00027b crossref_primary_10_1016_j_coche_2013_06_001 crossref_primary_10_1016_j_cattod_2014_02_035 crossref_primary_10_1016_j_micromeso_2012_03_054 crossref_primary_10_1002_ange_201209638 crossref_primary_10_2139_ssrn_4096905 crossref_primary_10_1039_C4CY00360H crossref_primary_10_1016_j_micromeso_2012_10_005 crossref_primary_10_1021_cr400600f crossref_primary_10_1039_C5TA00364D crossref_primary_10_1016_j_jhazmat_2022_128590 crossref_primary_10_1071_CH13543 crossref_primary_10_1016_j_cclet_2014_09_003 crossref_primary_10_1002_anie_200705755 crossref_primary_10_1021_ja410141u crossref_primary_10_1016_j_memsci_2008_07_030 crossref_primary_10_1016_j_cjche_2019_03_027 crossref_primary_10_1002_anie_201209638 crossref_primary_10_1007_s11244_015_0394_9 crossref_primary_10_3390_app8091636 crossref_primary_10_1021_acs_chemmater_6b02155 crossref_primary_10_1038_ncomms8128 crossref_primary_10_1002_aic_16503 crossref_primary_10_1039_C6RA23959E crossref_primary_10_1016_j_carbon_2012_10_055 crossref_primary_10_1039_c3dt53181c crossref_primary_10_1016_j_apsusc_2017_06_114 crossref_primary_10_1002_adma_202307341 crossref_primary_10_1016_j_jcat_2014_09_009 crossref_primary_10_1016_j_micromeso_2012_09_032 crossref_primary_10_1021_jacs_9b03479 crossref_primary_10_1016_j_apcata_2011_01_008 crossref_primary_10_1016_j_cej_2024_151109 crossref_primary_10_1016_j_micromeso_2011_08_014 crossref_primary_10_1021_la200851j crossref_primary_10_1007_s10562_023_04287_1 crossref_primary_10_1016_j_cattod_2015_08_012 crossref_primary_10_1021_acs_cgd_9b00974 crossref_primary_10_1002_ange_202304734 crossref_primary_10_1021_acs_iecr_0c03464 crossref_primary_10_1016_j_cattod_2021_10_004 crossref_primary_10_1039_C2CY20510F crossref_primary_10_1039_C8CE00121A crossref_primary_10_1021_ja0758739 crossref_primary_10_1021_jacs_0c11784 crossref_primary_10_1016_j_micromeso_2014_05_030 crossref_primary_10_1039_C5NJ02829A crossref_primary_10_1021_cm5033833 crossref_primary_10_1016_j_micromeso_2021_111042 crossref_primary_10_1021_acs_chemmater_6b00750 crossref_primary_10_1021_cm303131c crossref_primary_10_1016_j_cattod_2016_01_042 crossref_primary_10_1021_cs500285w crossref_primary_10_1002_cctc_201800040 crossref_primary_10_1016_j_scriptamat_2014_09_024 crossref_primary_10_1002_ejic_200900915 crossref_primary_10_1021_cs2006839 crossref_primary_10_1039_C4DT00120F crossref_primary_10_1002_admi_201901786 crossref_primary_10_1016_j_micromeso_2023_112521 crossref_primary_10_1093_nsr_nwaa236 crossref_primary_10_1007_s10562_022_03964_x crossref_primary_10_1016_j_memsci_2023_121454 crossref_primary_10_1016_j_cej_2024_159058 crossref_primary_10_1016_j_micromeso_2015_12_015 crossref_primary_10_1021_acs_iecr_4c02088 crossref_primary_10_1021_acs_iecr_4c03177 crossref_primary_10_1177_1747519820951401 crossref_primary_10_1039_C6CY02613C crossref_primary_10_1002_anie_201708835 crossref_primary_10_1016_j_apcata_2023_119184 crossref_primary_10_1016_j_micromeso_2021_111629 crossref_primary_10_1002_aic_14099 crossref_primary_10_1021_acs_iecr_8b05472 crossref_primary_10_1007_s11434_010_3737_8 crossref_primary_10_1021_ja908382n crossref_primary_10_1126_science_1221111 crossref_primary_10_1002_anie_201805535 crossref_primary_10_1002_cctc_200900278 crossref_primary_10_1021_ie3031136 crossref_primary_10_1021_cm3032785 crossref_primary_10_1016_j_pecs_2016_04_004 crossref_primary_10_1021_acs_chemmater_5b01030 crossref_primary_10_1039_c1jm13108g crossref_primary_10_1021_jacs_9b13596 crossref_primary_10_1039_c1jm10460h crossref_primary_10_1039_C9NJ06222J crossref_primary_10_1039_C5CY02208H crossref_primary_10_1016_j_cej_2022_141057 crossref_primary_10_1016_j_micromeso_2021_110883 crossref_primary_10_1002_ange_201805535 crossref_primary_10_1016_j_clay_2020_105452 |
| Cites_doi | 10.1021/j100018a037 10.1038/24592 10.1016/j.micromeso.2006.07.015 10.1016/0927-6513(94)00086-B 10.1016/S0032-3861(01)00552-3 10.1021/jp972319k 10.1016/S0920-5861(98)00444-1 10.1002/adma.19960080104 10.1006/jcat.1999.2774 10.1021/jp952871e 10.1021/cm960322v 10.1021/ie0706156 10.1016/j.memsci.2007.09.026, 10.1006/jcat.1999.2503 10.1016/S0376-7388(00)85132-7 10.1126/science.264.5167.1910 10.1021/ja00103a015 10.1016/0144-2449(94)00038-T |
| ContentType | Journal Article |
| Copyright | Copyright © 2008 American Chemical Society |
| Copyright_xml | – notice: Copyright © 2008 American Chemical Society |
| DBID | BSCLL AAYXX CITATION NPM 7X8 |
| DOI | 10.1021/ja077711i |
| DatabaseName | Istex CrossRef PubMed MEDLINE - Academic |
| DatabaseTitle | CrossRef PubMed MEDLINE - Academic |
| DatabaseTitleList | MEDLINE - Academic PubMed |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1520-5126 |
| EndPage | 1516 |
| ExternalDocumentID | 18179218 10_1021_ja077711i ark_67375_TPS_8D698HNK_R a051326667 |
| Genre | Journal Article |
| GroupedDBID | - .K2 02 186 4.4 53G 55A 5GY 5RE 5VS 7~N 85S AABXI ABFLS ABMVS ABPPZ ABPTK ABUCX ABUFD ACGFS ACJ ACNCT ACS AEESW AENEX AETEA AFEFF AFFNX AFMIJ ALMA_UNASSIGNED_HOLDINGS ANTXH AQSVZ BAANH BKOMP CS3 DU5 DZ EBS ED ED~ EJD ET F20 F5P GNL IH9 JG JG~ K2 K78 LG6 P2P ROL RXW TAE TAF TN5 UHB UI2 UKR UPT UQL VF5 VG9 VQA W1F WH7 X XFK YZZ ZCG ZE2 ZHY --- -DZ -ET -~X .DC 6TJ AAHBH AAYOK ABJNI ABQRX ACBEA ACGFO ADHLV ADOJD AGXLV AHGAQ BSCLL CUPRZ GGK IH2 XSW YQT ZCA ~02 AAYXX ABBLG ABLBI ACRPL ADNMO ADXHL AEYZD AGQPQ AHDLI ANPPW CITATION YR5 NPM 7X8 |
| ID | FETCH-LOGICAL-a417t-a3318996102ed7fb6ab53dc22a54de5e16bcbb017897096e2b5275d2edfeeb1b3 |
| IEDL.DBID | ACS |
| ISSN | 0002-7863 1520-5126 |
| IngestDate | Fri Jul 11 12:01:00 EDT 2025 Thu Apr 03 06:56:09 EDT 2025 Thu Apr 24 22:52:53 EDT 2025 Tue Jul 01 04:14:28 EDT 2025 Wed Oct 30 09:48:18 EDT 2024 Thu Aug 27 13:42:37 EDT 2020 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 4 |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a417t-a3318996102ed7fb6ab53dc22a54de5e16bcbb017897096e2b5275d2edfeeb1b3 |
| Notes | istex:380F088430D51CE306B7755758BA90058FE17B51 ark:/67375/TPS-8D698HNK-R ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| PMID | 18179218 |
| PQID | 70227744 |
| PQPubID | 23479 |
| PageCount | 10 |
| ParticipantIDs | proquest_miscellaneous_70227744 pubmed_primary_18179218 crossref_citationtrail_10_1021_ja077711i crossref_primary_10_1021_ja077711i istex_primary_ark_67375_TPS_8D698HNK_R acs_journals_10_1021_ja077711i |
| ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N ACJ VG9 W1F ANTXH ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2008-01-30 |
| PublicationDateYYYYMMDD | 2008-01-30 |
| PublicationDate_xml | – month: 01 year: 2008 text: 2008-01-30 day: 30 |
| PublicationDecade | 2000 |
| PublicationPlace | United States |
| PublicationPlace_xml | – name: United States |
| PublicationTitle | Journal of the American Chemical Society |
| PublicationTitleAlternate | J. Am. Chem. Soc |
| PublicationYear | 2008 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | Camblor M. A. (ja077711ib00027/ja077711ib00027_1) 1996; 8 Kennedy G. J. (ja077711ib00023/ja077711ib00023_1) 1994; 116 Kresge C. T. (ja077711ib00004/ja077711ib00004_1) 1993 Hunger M. (ja077711ib00030/ja077711ib00030_1) 1995; 15 ja077711ib00010/ja077711ib00010_1 Kresge C. T. (ja077711ib00005/ja077711ib00005_1) 1994 Ray S. S. (ja077711ib00014/ja077711ib00014_1) 2003; 28 Wu P. (ja077711ib00016/ja077711ib00016_1) 2004; 108 Hellring S. D. (ja077711ib00019/ja077711ib00019_1) 1997 Kennedy G. J. (ja077711ib00028/ja077711ib00028_1) 1999; 49 Lawton S. L. (ja077711ib00024/ja077711ib00024_1) 1996; 100 ja077711ib00006/ja077711ib00006_1 Vuono D. (ja077711ib00025/ja077711ib00025_1) 2006; 97 Ma D. (ja077711ib00032/ja077711ib00032_1) 2001; 105 Kolodziejski W. (ja077711ib00031/ja077711ib00031_1) 1995; 99 Roth W. J. (ja077711ib00002/ja077711ib00002_1) 2002; 141 Camblor M. A. (ja077711ib00022/ja077711ib00022_1) 1998; 102 Ravishankar R. (ja077711ib00003/ja077711ib00003_1) 1995; 4 Corma A. (ja077711ib00007/ja077711ib00007_1) 1999; 186 Dorset D. L. (ja077711ib00029/ja077711ib00029_1) 2005; 61 Burkett S. L. (ja077711ib00033/ja077711ib00033_1) 1994; 98 Roth W. J. (ja077711ib00035/ja077711ib00035_1) 1995; 94 Fornes T. D. (ja077711ib00036/ja077711ib00036_1) 2001; 42 Schenkel R. (ja077711ib00015/ja077711ib00015_1) 2002; 142 Giannelis E. P. (ja077711ib00013/ja077711ib00013_1) 1996; 8 Chu C. T. (ja077711ib00018/ja077711ib00018_1) 1993 Aiello R. (ja077711ib00021/ja077711ib00021_1) 2000; 35 Barth J.-O. (ja077711ib00020/ja077711ib00020_1) 2002; 12 He Y. J. (ja077711ib00034/ja077711ib00034_1) 1998; 25 Leonowicz M. E. (ja077711ib00026/ja077711ib00026_1) 1994; 264 Rubin M. K. (ja077711ib00001/ja077711ib00001_1) 1990 Choi J. (ja077711ib00009/ja077711ib00009_1) 2007; 46 Corma A. (ja077711ib00008/ja077711ib00008_1) 1998; 396 Corma A. (ja077711ib00017/ja077711ib00017_1) 2000; 191 Cussler E. L. (ja077711ib00011/ja077711ib00011_1) 1990; 52 ja077711ib00012/ja077711ib00012_1 |
| References_xml | – volume: 99 start-page: 8 issue: 18 year: 1995 ident: ja077711ib00031/ja077711ib00031_1 publication-title: J. Phys. Chem. doi: 10.1021/j100018a037 – volume-title: Patent 5258569 year: 1993 ident: ja077711ib00018/ja077711ib00018_1 – volume-title: Patent 4954325 year: 1990 ident: ja077711ib00001/ja077711ib00001_1 – volume: 396 start-page: 356 issue: 6709 year: 1998 ident: ja077711ib00008/ja077711ib00008_1 publication-title: Nature (London) doi: 10.1038/24592 – ident: ja077711ib00006/ja077711ib00006_1 – volume: 28 start-page: 1641 issue: 11 year: 2003 ident: ja077711ib00014/ja077711ib00014_1 publication-title: Prog. Polym. Sci. – volume: 97 start-page: 87 year: 2006 ident: ja077711ib00025/ja077711ib00025_1 publication-title: Microporous Mesoporous Mater. doi: 10.1016/j.micromeso.2006.07.015 – volume: 94 start-page: 8 year: 1995 ident: ja077711ib00035/ja077711ib00035_1 publication-title: Stud. Surf. Sci. Catal. – volume: 4 start-page: 93 issue: 1 year: 1995 ident: ja077711ib00003/ja077711ib00003_1 publication-title: Microporous Materials doi: 10.1016/0927-6513(94)00086-B – volume: 42 start-page: 09940 issue: 25 year: 2001 ident: ja077711ib00036/ja077711ib00036_1 publication-title: Polymer doi: 10.1016/S0032-3861(01)00552-3 – volume: 102 start-page: 51 issue: 1 year: 1998 ident: ja077711ib00022/ja077711ib00022_1 publication-title: J. Phys. Chem. B doi: 10.1021/jp972319k – volume: 25 start-page: 224 year: 1998 ident: ja077711ib00034/ja077711ib00034_1 publication-title: Microporous Mesoporous Mater. – ident: ja077711ib00012/ja077711ib00012_1 – volume: 98 start-page: 53 issue: 17 year: 1994 ident: ja077711ib00033/ja077711ib00033_1 publication-title: J. Phys. Chem. B – volume: 108 start-page: 19131 issue: 50 year: 2004 ident: ja077711ib00016/ja077711ib00016_1 publication-title: J. Phys. Chem. B – volume-title: Patent 5278115 year: 1994 ident: ja077711ib00005/ja077711ib00005_1 – volume-title: Patent 5266541 year: 1993 ident: ja077711ib00004/ja077711ib00004_1 – volume: 105 start-page: 1779 issue: 9 year: 2001 ident: ja077711ib00032/ja077711ib00032_1 publication-title: J. Phys. Chem. B – volume-title: Patent 5639931 year: 1997 ident: ja077711ib00019/ja077711ib00019_1 – volume: 49 start-page: 399 issue: 4 year: 1999 ident: ja077711ib00028/ja077711ib00028_1 publication-title: Catal. Today doi: 10.1016/S0920-5861(98)00444-1 – volume: 8 start-page: 35 issue: 1 year: 1996 ident: ja077711ib00013/ja077711ib00013_1 publication-title: Adv. Mater. (Weinheim, Germany) doi: 10.1002/adma.19960080104 – volume: 191 start-page: 224 issue: 1 year: 2000 ident: ja077711ib00017/ja077711ib00017_1 publication-title: J. Catal. doi: 10.1006/jcat.1999.2774 – volume: 100 start-page: 98 issue: 9 year: 1996 ident: ja077711ib00024/ja077711ib00024_1 publication-title: J. Phys. Chem. doi: 10.1021/jp952871e – volume: 8 start-page: 2417 issue: 10 year: 1996 ident: ja077711ib00027/ja077711ib00027_1 publication-title: Chem. Mater. doi: 10.1021/cm960322v – volume: 12 start-page: 373 issue: 2 year: 2002 ident: ja077711ib00020/ja077711ib00020_1 publication-title: J. Mater. Chem. – volume: 142 start-page: 76 year: 2002 ident: ja077711ib00015/ja077711ib00015_1 publication-title: Stud. Surf. Sci. Catal. – volume: 46 start-page: 7106 issue: 22 year: 2007 ident: ja077711ib00009/ja077711ib00009_1 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie0706156 – ident: ja077711ib00010/ja077711ib00010_1 doi: 10.1016/j.memsci.2007.09.026, – volume: 35 start-page: 595 year: 2000 ident: ja077711ib00021/ja077711ib00021_1 publication-title: Microporous Mesoporous Mater. – volume: 186 start-page: 63 issue: 1 year: 1999 ident: ja077711ib00007/ja077711ib00007_1 publication-title: J. Catal. doi: 10.1006/jcat.1999.2503 – volume: 52 start-page: 88 issue: 3 year: 1990 ident: ja077711ib00011/ja077711ib00011_1 publication-title: J. Membrane Sci. doi: 10.1016/S0376-7388(00)85132-7 – volume: 264 start-page: 13 issue: 5167 year: 1994 ident: ja077711ib00026/ja077711ib00026_1 publication-title: Science (Washington, DC, United States) doi: 10.1126/science.264.5167.1910 – volume: 61 start-page: 527 issue: 5 year: 2005 ident: ja077711ib00029/ja077711ib00029_1 publication-title: J. Acta Crystallogr., Sect. A – volume: 116 start-page: 3 issue: 24 year: 1994 ident: ja077711ib00023/ja077711ib00023_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00103a015 – volume: 141 start-page: 279 year: 2002 ident: ja077711ib00002/ja077711ib00002_1 publication-title: Stud. Surf. Sci. Catal. – volume: 15 start-page: 92 issue: 3 year: 1995 ident: ja077711ib00030/ja077711ib00030_1 publication-title: Zeolites doi: 10.1016/0144-2449(94)00038-T |
| SSID | ssj0004281 |
| Score | 2.3960106 |
| Snippet | MCM-22(P), the precursor to zeolite MCM-22, consists of stacks of layers that can be swollen and exfoliated to produce catalytically active materials. However,... |
| SourceID | proquest pubmed crossref istex acs |
| SourceType | Aggregation Database Index Database Enrichment Source Publisher |
| StartPage | 1507 |
| Title | Layer Structure Preservation during Swelling, Pillaring, and Exfoliation of a Zeolite Precursor |
| URI | http://dx.doi.org/10.1021/ja077711i https://api.istex.fr/ark:/67375/TPS-8D698HNK-R/fulltext.pdf https://www.ncbi.nlm.nih.gov/pubmed/18179218 https://www.proquest.com/docview/70227744 |
| Volume | 130 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwhV1LS8QwEB50PejF92N9BhXxYMWkaZI9yqosKiKugngJSZOCKF3ZB4i_3km7XRVftxymbZqZZL6ZzANgV8SCC5aJyElvIu5oHFlU1JFHaC15KoVwRZTvlWjd8fP75H4Mdn65wWehPtCRlJLSx3GYYELJYGEdN9sfyY9M0QrjSiXiqnzQ50eD6kl7X1TPRFjF199xZaFfzmbgpMrSKcNKng4HfXuYvn0v2vjX1GdheogvyXEpEHMw5vN5mGxWbd0WQF8aRNmkXdSNHXQ9CUEYlWeWlFmLpB1cejg4INehK1G3GJrckdPXrPNccpN0MmLIgw8BdMVb0gGC9-4i3J2d3jZb0bDLQmQ4lf3IxLit0erBGXsnMyuMTWKXMmYS7nziqbCptbhxVUOiveOZTZhMHBJnHg96Gy9BLe_kfgVIw6eZZ0aFZFxuOTXKUsQngjnq0czjddhENujhLunp4gKcoQFSrVMd9isO6XRYozy0ynj-iXR7RPpSFub4iWivYPOIwnSfQiSbTPTtdVurE9FQrasLfVOHrUoONPIjXJqY3HcGPS1DjUXJce7LpXh8fE3hYYYIafW_v1qDqTLKJHj61qGGDPYbCGX6drMQ5Xe3X-t6 |
| linkProvider | American Chemical Society |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1LSwMxEA4-Dnrx_ajPICIe3GKy2WR7lKpUrUVsBfESkk0WRNlKtwXx1zvJ7loVRW85zGaTTB7fJDPfILTPQ844TXlghFUBMyQMNBzUgQVoLVgiODfey7fDW3fs8j66L2lyXCwMNCKHmnL_iD9mF3A0QcdCCEIeJ9E0gBDqDK2TZnccA0ljUkFdEfOwYhH6_Kk7gZL8ywk07Qbz9Xd46Y-Z8_kiX5FvoPcueaqPhrqevH3jbvxfDxbQXIk28UkxPRbRhM2W0EyzSvK2jGRbAebGXc8iOxpY7FwyqntaXMQw4q674IPCEb5xOYoGvqgyg89e0_5zoVvcT7HCD9a50_lakhFA-cEKujs_6zVbQZlzIVCMiGGgQljkYANBi60RqeZKR6FJKFURMzayhOtEa1jGcUOA9WOpBlVEBoRTC9u-DlfRVNbP7DrCDZuklqrYheYyzYiKNQG0wqkhFow-VkM7MEyyXDO59M_hFMyRapxq6LBSlExKxnKXOOP5J9G9D9GXgqbjJ6EDr-0PCTV4cn5tIpK9m66MT3kjbnWu5G0N7VbTQYI-3BOKymx_lEvhGBcFg7avFbNk_LcYtjbASxt_9WoXzbR6123ZvuhcbaLZwv_E3QFuoSlQtt0GkDPUO352vwOR1PPb |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV3db9MwED_BJgEvG19jhbFZCCEeyIQdx04fp25VYVOp6CZNvFh27EhoUzo1rTTx13PnJN2YhuDNDxfH9t3Zv_N9GOC9SpVUolSJ18Em0vM0cXhQJwGhtZaFVsrHKN-xGp3Jr-fZeWsoUi4MDqLGnuroxCetvvJlW2GASgV91lpz_vMhrJO7joytg8H0Jg9S5LyDuzpXaVdJ6PandAoV9R-n0Dot6PXfIWY8aoab8G01yBhhcrG_XLj94ted-o3_P4unsNGiTnbQiMkzeBCq5_B40D329gLMiUXszaaxmuxyHhiFZnT3tazJZWRTuujDxic2obeK5rFpK8-OrsvZZcNjNiuZZT8ChdXFXoolQvr5SzgbHp0ORkn79kJiJdeLxKao7GgL4YiD16VT1mWpL4SwmfQhC1y5wjlU57yv0QoKwmVCZx6Jy4Dbv0u3YK2aVWEbWD8UZRA2pxRd6SS3ueOIWpTwPKDxJ3uwi0tlWt2pTXSLCzRLunXqwceOWaZoK5fTAxqX95G-W5FeNeU67iP6EDm-orDzC4pv05k5nUxNfqj6-Wh8bL73YK8TCYP8IFeKrcJsWRtNlRe1xLG_aiTl5m85bnGIm17_a1Z78GhyODQnX8bHb-BJE4ZCV4E7sIa8Dm8R6yzcbhTw35WE9l4 |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Layer+structure+preservation+during+swelling%2C+pillaring%2C+and+exfoliation+of+a+zeolite+precursor&rft.jtitle=Journal+of+the+American+Chemical+Society&rft.au=Maheshwari%2C+Sudeep&rft.au=Jordan%2C+Edgar&rft.au=Kumar%2C+Sandeep&rft.au=Bates%2C+Frank+S&rft.date=2008-01-30&rft.eissn=1520-5126&rft.volume=130&rft.issue=4&rft.spage=1507&rft_id=info:doi/10.1021%2Fja077711i&rft_id=info%3Apmid%2F18179218&rft.externalDocID=18179218 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0002-7863&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0002-7863&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0002-7863&client=summon |