Switching of the Electronic Communication between Two {Ru(trpy)(bpy)} (trpy = 2,2‘:6‘,2‘ ‘-Terpyridine and bpy = 2,2‘-Bipyridine) Centers by Protonation on the Bridging Dimercaptothiadiazolato Ligand
A stable Ru(II)/Ru(III) mixed-valence state was observed in acetonitrile for the ruthenium binuclear complex bridged by dimercaptothiadiazolate (ΔE 1/2 = 220 mV for Ru2(II,II)/Ru2(II,III) and Ru2(II,III)/Ru2(III,III) processes; K com = 5.3 × 103). Upon protonation of the bridging ligand by the addit...
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| Published in | Inorganic chemistry Vol. 44; no. 15; pp. 5206 - 5208 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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American Chemical Society
25.07.2005
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| Abstract | A stable Ru(II)/Ru(III) mixed-valence state was observed in acetonitrile for the ruthenium binuclear complex bridged by dimercaptothiadiazolate (ΔE 1/2 = 220 mV for Ru2(II,II)/Ru2(II,III) and Ru2(II,III)/Ru2(III,III) processes; K com = 5.3 × 103). Upon protonation of the bridging ligand by the addition of equimolar p-toluenesulfonic acid, however, the mixed-valence state diminished (ΔE 1/2 = 0 mV). The bridging ligand operates as a proton-induced switch of the electronic communication in the dimeric complex. |
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| AbstractList | A stable Ru(II)/Ru(III) mixed-valence state was observed in acetonitrile for the ruthenium binuclear complex bridged by dimercaptothiadiazolate (ΔE 1/2 = 220 mV for Ru2(II,II)/Ru2(II,III) and Ru2(II,III)/Ru2(III,III) processes; K com = 5.3 × 103). Upon protonation of the bridging ligand by the addition of equimolar p-toluenesulfonic acid, however, the mixed-valence state diminished (ΔE 1/2 = 0 mV). The bridging ligand operates as a proton-induced switch of the electronic communication in the dimeric complex. A stable Ru(II)/Ru(III) mixed-valence state was observed in acetonitrile for the ruthenium binuclear complex bridged by dimercaptothiadiazolate (DeltaE(1/2) = 220 mV for Ru(2)(II,II)/Ru(2)(II,III) and Ru(2)(II,III)/Ru(2)(III,III) processes; K(com) = 5.3 x 10(3)). Upon protonation of the bridging ligand by the addition of equimolar p-toluenesulfonic acid, however, the mixed-valence state diminished (DeltaE(1/2) = 0 mV). The bridging ligand operates as a proton-induced switch of the electronic communication in the dimeric complex. |
| Author | Sasaki, Yoichi Tannai, Hidenori Tsuge, Kiyoshi |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/16022516$$D View this record in MEDLINE/PubMed |
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| Snippet | A stable Ru(II)/Ru(III) mixed-valence state was observed in acetonitrile for the ruthenium binuclear complex bridged by dimercaptothiadiazolate (ΔE 1/2 = 220... A stable Ru(II)/Ru(III) mixed-valence state was observed in acetonitrile for the ruthenium binuclear complex bridged by dimercaptothiadiazolate (DeltaE(1/2) =... |
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| SubjectTerms | Bridged-Ring Compounds - chemistry Crystallography, X-Ray Dimercaprol - chemistry Electrons Ligands Models, Molecular Organometallic Compounds - chemistry Protons Ruthenium - chemistry Thiadiazoles - chemistry |
| Title | Switching of the Electronic Communication between Two {Ru(trpy)(bpy)} (trpy = 2,2‘:6‘,2‘ ‘-Terpyridine and bpy = 2,2‘-Bipyridine) Centers by Protonation on the Bridging Dimercaptothiadiazolato Ligand |
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