Energy Flow and Fragmentation Dynamics of N,N-Dimethylisopropylamine
The energy flow and fragmentation dynamics of N,N-dimethylisopropylamine (DMIPA) upon excitation to the 3p Rydberg states has been investigated with use of time-resolved photoelectron and mass spectrometry. The 3p states are short-lived, with a lifetime of 701 ± 45 fs. From the time dependence of th...
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Published in | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 110; no. 12; pp. 4251 - 4255 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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United States
American Chemical Society
30.03.2006
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Abstract | The energy flow and fragmentation dynamics of N,N-dimethylisopropylamine (DMIPA) upon excitation to the 3p Rydberg states has been investigated with use of time-resolved photoelectron and mass spectrometry. The 3p states are short-lived, with a lifetime of 701 ± 45 fs. From the time dependence of the photoelectron spectra, we infer that the primary reaction channel leads to the 3s level, which itself decays to the ground state with a decay time of 87.9 ± 10.2 ps. The mass spectrum reveals fragmentation with cleavage at the α C−C bond, indicating that the energy deposited in vibrations during the internal conversion from 3p to 3s exceeds the bond energy. A thorough examination of the binding energies and temporal dynamics of the Rydberg states, as well as a comparison to the related fragmentation of N,N-dimethyl-2-butanamine (DM2BA), suggests that the fragments are formed on the ion surfaces, i.e., after ionization and on a time scale much slower than the fluorescence decay from 3s to the ground state. |
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AbstractList | The energy flow and fragmentation dynamics of N,N-dimethylisopropylamine (DMIPA) upon excitation to the 3p Rydberg states has been investigated with use of time-resolved photoelectron and mass spectrometry. The 3p states are short-lived, with a lifetime of 701 +/- 45 fs. From the time dependence of the photoelectron spectra, we infer that the primary reaction channel leads to the 3s level, which itself decays to the ground state with a decay time of 87.9 +/- 10.2 ps. The mass spectrum reveals fragmentation with cleavage at the alpha C-C bond, indicating that the energy deposited in vibrations during the internal conversion from 3p to 3s exceeds the bond energy. A thorough examination of the binding energies and temporal dynamics of the Rydberg states, as well as a comparison to the related fragmentation of N,N-dimethyl-2-butanamine (DM2BA), suggests that the fragments are formed on the ion surfaces, i.e., after ionization and on a time scale much slower than the fluorescence decay from 3s to the ground state. The energy flow and fragmentation dynamics of N,N-dimethylisopropylamine (DMIPA) upon excitation to the 3p Rydberg states has been investigated with use of time-resolved photoelectron and mass spectrometry. The 3p states are short-lived, with a lifetime of 701 ± 45 fs. From the time dependence of the photoelectron spectra, we infer that the primary reaction channel leads to the 3s level, which itself decays to the ground state with a decay time of 87.9 ± 10.2 ps. The mass spectrum reveals fragmentation with cleavage at the α C−C bond, indicating that the energy deposited in vibrations during the internal conversion from 3p to 3s exceeds the bond energy. A thorough examination of the binding energies and temporal dynamics of the Rydberg states, as well as a comparison to the related fragmentation of N,N-dimethyl-2-butanamine (DM2BA), suggests that the fragments are formed on the ion surfaces, i.e., after ionization and on a time scale much slower than the fluorescence decay from 3s to the ground state. |
Author | Sølling, Theis I. Gosselin, Jaimie L. Weber, Peter M. Rudakov, Fedor M. Minitti, Michael P. |
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Cites_doi | 10.1063/1.439098 10.1139/p61-051 10.1021/jp030797r 10.1016/0301-0104(81)80306-0 10.1021/ja00812a021 10.1063/1.463798 10.1063/1.1749715 10.1021/ja01338a041 10.1063/1.443602 10.1063/1.473448 10.1063/1.469895 10.1016/j.cplett.2003.08.002 10.1063/1.1698878 10.1016/0009-2614(71)80580-8 10.1021/jp003303o 10.1021/jp0503866 10.1063/1.476082 10.1021/jp046400g |
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References | Gosselin J. L. (jp0574706b00013/jp0574706b00013_1) 2005; 109 Mulliken R. S. (jp0574706b00006/jp0574706b00006_1) 1935; 3 Cureton C. G. (jp0574706b00009/jp0574706b00009_1) 1981; 63 Taylor D. P. (jp0574706b00018/jp0574706b00018_1) 1997; 106 Taylor D. P. (jp0574706b00019/jp0574706b00019_1) 1995; 103 Robin M. B. (jp0574706b00015/jp0574706b00015_1) 1974; 1 Langford S. R. (jp0574706b00004/jp0574706b00004_1) 1998; 108 Sølling T. I. (jp0574706b00010/jp0574706b00010_1) 2003; 107 Halpern A. M. (jp0574706b00022/jp0574706b00022_1) 1974; 96 Glownia J. H. (jp0574706b00003/jp0574706b00003_1) 1982; 77 Clarke H. T. (jp0574706b00020/jp0574706b00020_1) 1933; 55 Cureton C. G. (jp0574706b00021/jp0574706b00021_1) 1981; 63 Herzberg G. (jp0574706b00005/jp0574706b00005_1) 1933; 39 Schick C. P. (jp0574706b00017/jp0574706b00017_1) 2001; 105 Glownia J. H. (jp0574706b00002/jp0574706b00002_1) 1980; 72 Tannenbaum E. (jp0574706b00007/jp0574706b00007_1) 1953; 21 Taylor D. P. (jp0574706b00008/jp0574706b00008_1) 1995; 103 Cheng W. (jp0574706b00014/jp0574706b00014_1) 2005; 109 Freeman C. G. (jp0574706b00023/jp0574706b00023_1) 1971; 8 Douglas A. E. (jp0574706b00001/jp0574706b00001_1) 1962; 39 Kuthirummal N. (jp0574706b00011/jp0574706b00011_1) 2003; 378 Kim B. (jp0574706b00016/jp0574706b00016_1) 1992; 97 |
References_xml | – volume: 72 start-page: 5998 year: 1980 ident: jp0574706b00002/jp0574706b00002_1 publication-title: J. Chem. Phys. doi: 10.1063/1.439098 contributor: fullname: Glownia J. H. – volume: 39 start-page: 479 year: 1962 ident: jp0574706b00001/jp0574706b00001_1 publication-title: Can. J. Phys. doi: 10.1139/p61-051 contributor: fullname: Douglas A. E. – volume: 107 start-page: 10872 year: 2003 ident: jp0574706b00010/jp0574706b00010_1 publication-title: J. Phys. Chem. A doi: 10.1021/jp030797r contributor: fullname: Sølling T. I. – volume: 63 start-page: 31 year: 1981 ident: jp0574706b00021/jp0574706b00021_1 publication-title: Chem. Phys. doi: 10.1016/0301-0104(81)80306-0 contributor: fullname: Cureton C. G. – volume: 96 start-page: 1393 year: 1974 ident: jp0574706b00022/jp0574706b00022_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00812a021 contributor: fullname: Halpern A. M. – volume: 97 start-page: 5384 year: 1992 ident: jp0574706b00016/jp0574706b00016_1 publication-title: J. Chem. Phys. doi: 10.1063/1.463798 contributor: fullname: Kim B. – volume: 3 start-page: 506 year: 1935 ident: jp0574706b00006/jp0574706b00006_1 publication-title: J. Chem. Phys. doi: 10.1063/1.1749715 contributor: fullname: Mulliken R. S. – volume: 55 start-page: 4571 year: 1933 ident: jp0574706b00020/jp0574706b00020_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01338a041 contributor: fullname: Clarke H. T. – volume: 77 start-page: 68 year: 1982 ident: jp0574706b00003/jp0574706b00003_1 publication-title: J. Chem. Phys. doi: 10.1063/1.443602 contributor: fullname: Glownia J. H. – volume: 106 start-page: 3512 year: 1997 ident: jp0574706b00018/jp0574706b00018_1 publication-title: J. Chem. Phys. doi: 10.1063/1.473448 contributor: fullname: Taylor D. P. – volume: 103 start-page: 10453 year: 1995 ident: jp0574706b00019/jp0574706b00019_1 publication-title: J. Chem. Phys. doi: 10.1063/1.469895 contributor: fullname: Taylor D. P. – volume: 378 start-page: 647 year: 2003 ident: jp0574706b00011/jp0574706b00011_1 publication-title: Chem. Phys. Lett. doi: 10.1016/j.cplett.2003.08.002 contributor: fullname: Kuthirummal N. – volume: 21 start-page: 311 year: 1953 ident: jp0574706b00007/jp0574706b00007_1 publication-title: J. Chem. Phys. doi: 10.1063/1.1698878 contributor: fullname: Tannenbaum E. – volume: 63 start-page: 31 year: 1981 ident: jp0574706b00009/jp0574706b00009_1 publication-title: Chem. Phys. doi: 10.1016/0301-0104(81)80306-0 contributor: fullname: Cureton C. G. – volume: 39 start-page: 572 year: 1933 ident: jp0574706b00005/jp0574706b00005_1 publication-title: Electrochemistry contributor: fullname: Herzberg G. – volume: 8 start-page: 77 year: 1971 ident: jp0574706b00023/jp0574706b00023_1 publication-title: Chem. Phys. Lett. doi: 10.1016/0009-2614(71)80580-8 contributor: fullname: Freeman C. G. – volume: 105 start-page: 3725 year: 2001 ident: jp0574706b00017/jp0574706b00017_1 publication-title: J. Phys. Chem. A doi: 10.1021/jp003303o contributor: fullname: Schick C. P. – volume: 109 start-page: 4899 year: 2005 ident: jp0574706b00013/jp0574706b00013_1 publication-title: J. Phys. Chem. A doi: 10.1021/jp0503866 contributor: fullname: Gosselin J. L. – volume: 103 start-page: 10453 year: 1995 ident: jp0574706b00008/jp0574706b00008_1 publication-title: J. Chem. Phys. doi: 10.1063/1.469895 contributor: fullname: Taylor D. P. – volume: 108 start-page: 6667 year: 1998 ident: jp0574706b00004/jp0574706b00004_1 publication-title: J. Chem. Phys. doi: 10.1063/1.476082 contributor: fullname: Langford S. R. – volume: 109 start-page: 1920 year: 2005 ident: jp0574706b00014/jp0574706b00014_1 publication-title: J. Phys. Chem. A doi: 10.1021/jp046400g contributor: fullname: Cheng W. – volume: 1 volume-title: Higher Excited States of Polyatomic Molecules year: 1974 ident: jp0574706b00015/jp0574706b00015_1 contributor: fullname: Robin M. B. |
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Title | Energy Flow and Fragmentation Dynamics of N,N-Dimethylisopropylamine |
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