Structural Characterization of Complexes between Iminodiacetate Blocked on Styrene−Divinylbenzene Matrix (Chelex 100 Resin) and Fe(III), Cr(III), and Zn(II) in Solid Phase by Energy-Dispersive X-ray Diffraction
Local structure of Fe(III), Cr(III), and Zn(II) cations has been determined on the amorphous sample by means of the difference method used for liquid systems. We recorded energy-dispersive X-ray diffraction spectra of a chelating resin (Chelex 100), containing paired iminodiacetate ions coupled to a...
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Published in | Journal of the American Chemical Society Vol. 123; no. 11; pp. 2552 - 2558 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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American Chemical Society
21.03.2001
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Abstract | Local structure of Fe(III), Cr(III), and Zn(II) cations has been determined on the amorphous sample by means of the difference method used for liquid systems. We recorded energy-dispersive X-ray diffraction spectra of a chelating resin (Chelex 100), containing paired iminodiacetate ions coupled to a styrene-divinylbenzene support, in several ionic forms. Coordination geometry of Fe(III), Cr(III), and Zn(II) metal cations with Chelex 100 resin ligand sites, and conformation of the ligand groups have been determined. |
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AbstractList | Local structure of Fe(III), Cr(III), and Zn(II) cations has been determined on the amorphous sample by means of the difference method used for liquid systems. We recorded energy-dispersive X-ray diffraction spectra of a chelating resin (Chelex 100), containing paired iminodiacetate ions coupled to a styrene-divinylbenzene support, in several ionic forms. Coordination geometry of Fe(III), Cr(III), and Zn(II) metal cations with Chelex 100 resin ligand sites, and conformation of the ligand groups have been determined. |
Author | Ferri, T Sangiorgio, P Atzei, D Sadun, C Caminiti, R |
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Title | Structural Characterization of Complexes between Iminodiacetate Blocked on Styrene−Divinylbenzene Matrix (Chelex 100 Resin) and Fe(III), Cr(III), and Zn(II) in Solid Phase by Energy-Dispersive X-ray Diffraction |
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