Synthesis and Effect of Physical Aging on Gas Transport Properties of a Microporous Polyimide Derived from a Novel Spirobifluorene-Based Dianhydride

A novel generic method is reported for the synthesis of a spirobifluorene-based dianhydride (SBFDA). An intrinsically microporous polyimide was obtained by polycondensation reaction with 3,3′-dimethylnaphthidine (DMN). The corresponding polymer (SBFDA-DMN) exhibited good solubility, excellent therma...

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Published inACS macro letters Vol. 4; no. 2; pp. 231 - 235
Main Authors Ma, Xiaohua, Ghanem, Bader, Salines, Octavio, Litwiller, Eric, Pinnau, Ingo
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 17.02.2015
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Abstract A novel generic method is reported for the synthesis of a spirobifluorene-based dianhydride (SBFDA). An intrinsically microporous polyimide was obtained by polycondensation reaction with 3,3′-dimethylnaphthidine (DMN). The corresponding polymer (SBFDA-DMN) exhibited good solubility, excellent thermal stability, as well as significant microporosity with high BET surface area of 686 m2/g. The O2 permeability of a methanol-treated and air-dried membrane was 1193 Barrer with a moderate O2/N2 selectivity of 3.2. The post-treatment history and aging conditions had great effects on the membrane performance. A significant drop in permeability coupled with an increase in selectivity was observed after long-term aging. After storage of 200 days, the gas separation properties of SBFDA-DMN were located slightly above the latest Robeson upper bounds for several gas pairs such as O2/N2 and H2/N2.
AbstractList A novel generic method is reported for the synthesis of a spirobifluorene-based dianhydride (SBFDA). An intrinsically microporous polyimide was obtained by polycondensation reaction with 3,3'-dimethylnaphthidine (DMN). The corresponding polymer (SBFDA-DMN) exhibited good solubility, excellent thermal stability, as well as significant microporosity with high BET surface area of 686 m /g. The O permeability of a methanol-treated and air-dried membrane was 1193 Barrer with a moderate O /N selectivity of 3.2. The post-treatment history and aging conditions had great effects on the membrane performance. A significant drop in permeability coupled with an increase in selectivity was observed after long-term aging. After storage of 200 days, the gas separation properties of SBFDA-DMN were located slightly above the latest Robeson upper bounds for several gas pairs such as O /N and H /N .
A novel generic method is reported for the synthesis of a spirobifluorene-based dianhydride (SBFDA). An intrinsically microporous polyimide was obtained by polycondensation reaction with 3,3′-dimethylnaphthidine (DMN). The corresponding polymer (SBFDA-DMN) exhibited good solubility, excellent thermal stability, as well as significant microporosity with high BET surface area of 686 m2/g. The O2 permeability of a methanol-treated and air-dried membrane was 1193 Barrer with a moderate O2/N2 selectivity of 3.2. The post-treatment history and aging conditions had great effects on the membrane performance. A significant drop in permeability coupled with an increase in selectivity was observed after long-term aging. After storage of 200 days, the gas separation properties of SBFDA-DMN were located slightly above the latest Robeson upper bounds for several gas pairs such as O2/N2 and H2/N2.
A novel generic method is reported for the synthesis of a spirobifluorene-based dianhydride (SBFDA). An intrinsically microporous polyimide was obtained by polycondensation reaction with 3,3'-dimethylnaphthidine (DMN). The corresponding polymer (SBFDA-DMN) exhibited good solubility, excellent thermal stability, as well as significant microporosity with high BET surface area of 686 m2/g. The O2 permeability of a methanol-treated and air-dried membrane was 1193 Barrer with a moderate O2/N2 selectivity of 3.2. The post-treatment history and aging conditions had great effects on the membrane performance. A significant drop in permeability coupled with an increase in selectivity was observed after long-term aging. After storage of 200 days, the gas separation properties of SBFDA-DMN were located slightly above the latest Robeson upper bounds for several gas pairs such as O2/N2 and H2/N2.A novel generic method is reported for the synthesis of a spirobifluorene-based dianhydride (SBFDA). An intrinsically microporous polyimide was obtained by polycondensation reaction with 3,3'-dimethylnaphthidine (DMN). The corresponding polymer (SBFDA-DMN) exhibited good solubility, excellent thermal stability, as well as significant microporosity with high BET surface area of 686 m2/g. The O2 permeability of a methanol-treated and air-dried membrane was 1193 Barrer with a moderate O2/N2 selectivity of 3.2. The post-treatment history and aging conditions had great effects on the membrane performance. A significant drop in permeability coupled with an increase in selectivity was observed after long-term aging. After storage of 200 days, the gas separation properties of SBFDA-DMN were located slightly above the latest Robeson upper bounds for several gas pairs such as O2/N2 and H2/N2.
Author Salines, Octavio
Pinnau, Ingo
Ghanem, Bader
Litwiller, Eric
Ma, Xiaohua
AuthorAffiliation King Abdullah University of Science and Technology (KAUST)
Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering
AuthorAffiliation_xml – name: Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering
– name: King Abdullah University of Science and Technology (KAUST)
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  fullname: Ma, Xiaohua
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  givenname: Ingo
  surname: Pinnau
  fullname: Pinnau, Ingo
  email: ingo.pinnau@kaust.edu.sa
BackLink https://www.ncbi.nlm.nih.gov/pubmed/35596413$$D View this record in MEDLINE/PubMed
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Cites_doi 10.1126/science.1228032
10.1021/ie8019032
10.1002/adma.201202393
10.1021/ma071846r
10.1016/0376-7388(91)80060-J
10.1002/adma.200702400
10.1021/ie0108088
10.1021/ma900898m
10.1002/marc.201000775
10.1002/adma.201470264
10.1021/ma9009017
10.1039/b311764b
10.1039/C4TA00564C
10.1021/ma5009226
10.1021/ma101930x
10.1021/ma402033z
10.1021/ma300549m
10.1021/ma501488s
10.1038/nmat2989
10.1039/c3py00451a
10.1021/ma9814548
10.1021/ma901430q
10.1002/adma.201306229
10.1002/adma.200306053
10.1016/j.memsci.2008.09.010
10.1021/ol800573m
10.1016/j.memsci.2009.02.003
10.1016/j.polymer.2013.07.035
10.1002/macp.201100089
10.1016/j.memsci.2005.01.009
10.1016/j.tetlet.2009.08.032
10.1021/ie071083w
10.1039/c1cc11717c
10.1016/j.memsci.2008.04.030
10.1021/ma801858d
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References Du N. (ref14/cit14) 2009; 42
Du N. (ref18/cit18) 2011; 10
Ghanem B. S. (ref26/cit26) 2008; 41
Robeson L. M. (ref6/cit6) 2008; 320
Short R. (ref23/cit23) 2011; 47
Budd P. (ref11/cit11) 2008; 325
Thomas S. (ref12/cit12) 2009; 333
Rogan Y. (ref31/cit31) 2013; 4
Carta M. (ref27/cit27) 2013; 339
Ma X. (ref35/cit35) 2013; 46
Du N. (ref19/cit19) 2011; 32
Robeson L. M. (ref5/cit5) 1991; 62
Rogan Y. (ref32/cit32) 2014; 2
Du N. (ref13/cit13) 2008; 41
Fritsch D. (ref22/cit22) 2011; 212
Swaidan R. (ref34/cit34) 2014; 47
Baker R. W. (ref4/cit4) 2002; 41
Carta M. (ref20/cit20) 2008; 10
Budd P. M. (ref9/cit9) 2004
Ma X. (ref15/cit15) 2012; 45
Du N. (ref16/cit16) 2009; 42
Ghanem B. S. (ref29/cit29) 2008; 20
Budd P. (ref10/cit10) 2005; 251
Budd P. M. (ref8/cit8) 2004; 16
Bernardo P. (ref1/cit1) 2009; 48
Iqbal Z. (ref36/cit36) 2008
Ghanem B. S. (ref28/cit28) 2014; 26
Baker R. W. (ref2/cit2) 2008; 47
Freeman B. D. (ref7/cit7) 1999; 32
Carta M. (ref21/cit21) 2009; 50
Vile J. (ref25/cit25) 2014; 55
Du N. (ref17/cit17) 2010; 43
Ghanem B. S. (ref33/cit33) 2014; 22
Baker R. W. (ref3/cit3) 2014; 47
Bezzu C. G. (ref24/cit24) 2012; 24
Ghanem B. S. (ref30/cit30) 2009; 42
References_xml – volume: 339
  start-page: 303
  year: 2013
  ident: ref27/cit27
  publication-title: Science
  doi: 10.1126/science.1228032
– volume: 48
  start-page: 4638
  year: 2009
  ident: ref1/cit1
  publication-title: Ind. Eng. Chem. Res.
  doi: 10.1021/ie8019032
– volume: 24
  start-page: 5930
  year: 2012
  ident: ref24/cit24
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201202393
– volume: 41
  start-page: 1640
  year: 2008
  ident: ref26/cit26
  publication-title: Macromolecules
  doi: 10.1021/ma071846r
– volume: 62
  start-page: 165
  year: 1991
  ident: ref5/cit5
  publication-title: J. Membr. Sci.
  doi: 10.1016/0376-7388(91)80060-J
– volume: 20
  start-page: 2766
  year: 2008
  ident: ref29/cit29
  publication-title: Adv. Mater.
  doi: 10.1002/adma.200702400
– volume: 41
  start-page: 1393
  year: 2002
  ident: ref4/cit4
  publication-title: Ind. Eng. Chem. Res.
  doi: 10.1021/ie0108088
– volume: 42
  start-page: 6023
  year: 2009
  ident: ref14/cit14
  publication-title: Macromolecules
  doi: 10.1021/ma900898m
– volume: 32
  start-page: 631
  year: 2011
  ident: ref19/cit19
  publication-title: Macromol. Rapid Commun.
  doi: 10.1002/marc.201000775
– volume: 26
  start-page: 6661
  year: 2014
  ident: ref28/cit28
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201470264
– volume: 42
  start-page: 6038
  year: 2009
  ident: ref16/cit16
  publication-title: Macromolecules
  doi: 10.1021/ma9009017
– start-page: 230
  year: 2004
  ident: ref9/cit9
  publication-title: Chem. Commun.
  doi: 10.1039/b311764b
– start-page: 2287
  year: 2008
  ident: ref36/cit36
  publication-title: Synlett
– volume: 2
  start-page: 4874
  year: 2014
  ident: ref32/cit32
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C4TA00564C
– volume: 47
  start-page: 5104
  year: 2014
  ident: ref34/cit34
  publication-title: Macromolecules
  doi: 10.1021/ma5009226
– volume: 43
  start-page: 8580
  year: 2010
  ident: ref17/cit17
  publication-title: Macromolecules
  doi: 10.1021/ma101930x
– volume: 46
  start-page: 9618
  year: 2013
  ident: ref35/cit35
  publication-title: Macromolecules
  doi: 10.1021/ma402033z
– volume: 45
  start-page: 3841
  year: 2012
  ident: ref15/cit15
  publication-title: Macromolecules
  doi: 10.1021/ma300549m
– volume: 47
  start-page: 6999
  year: 2014
  ident: ref3/cit3
  publication-title: Macromolecules
  doi: 10.1021/ma501488s
– volume: 10
  start-page: 372
  year: 2011
  ident: ref18/cit18
  publication-title: Nat. Mater.
  doi: 10.1038/nmat2989
– volume: 4
  start-page: 3813
  year: 2013
  ident: ref31/cit31
  publication-title: Polym. Chem.
  doi: 10.1039/c3py00451a
– volume: 32
  start-page: 375
  year: 1999
  ident: ref7/cit7
  publication-title: Macromolecules
  doi: 10.1021/ma9814548
– volume: 42
  start-page: 7881
  year: 2009
  ident: ref30/cit30
  publication-title: Macromolecules
  doi: 10.1021/ma901430q
– volume: 22
  start-page: 3688
  year: 2014
  ident: ref33/cit33
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201306229
– volume: 16
  start-page: 456
  year: 2004
  ident: ref8/cit8
  publication-title: Adv. Mater.
  doi: 10.1002/adma.200306053
– volume: 325
  start-page: 851
  year: 2008
  ident: ref11/cit11
  publication-title: J. Membr. Sci.
  doi: 10.1016/j.memsci.2008.09.010
– volume: 10
  start-page: 2641
  year: 2008
  ident: ref20/cit20
  publication-title: Org. Lett.
  doi: 10.1021/ol800573m
– volume: 333
  start-page: 125
  year: 2009
  ident: ref12/cit12
  publication-title: J. Membr. Sci.
  doi: 10.1016/j.memsci.2009.02.003
– volume: 55
  start-page: 326
  year: 2014
  ident: ref25/cit25
  publication-title: Polymer
  doi: 10.1016/j.polymer.2013.07.035
– volume: 212
  start-page: 1137
  year: 2011
  ident: ref22/cit22
  publication-title: Macromol. Chem. Phys.
  doi: 10.1002/macp.201100089
– volume: 251
  start-page: 263
  year: 2005
  ident: ref10/cit10
  publication-title: J. Membr. Sci.
  doi: 10.1016/j.memsci.2005.01.009
– volume: 50
  start-page: 5954
  year: 2009
  ident: ref21/cit21
  publication-title: Tetrahedron Lett.
  doi: 10.1016/j.tetlet.2009.08.032
– volume: 47
  start-page: 2109
  year: 2008
  ident: ref2/cit2
  publication-title: Ind. Eng. Chem. Res.
  doi: 10.1021/ie071083w
– volume: 47
  start-page: 6822
  year: 2011
  ident: ref23/cit23
  publication-title: Chem. Commun.
  doi: 10.1039/c1cc11717c
– volume: 320
  start-page: 390
  year: 2008
  ident: ref6/cit6
  publication-title: J. Membr. Sci.
  doi: 10.1016/j.memsci.2008.04.030
– volume: 41
  start-page: 9656
  year: 2008
  ident: ref13/cit13
  publication-title: Macromolecules
  doi: 10.1021/ma801858d
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Snippet A novel generic method is reported for the synthesis of a spirobifluorene-based dianhydride (SBFDA). An intrinsically microporous polyimide was obtained by...
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Title Synthesis and Effect of Physical Aging on Gas Transport Properties of a Microporous Polyimide Derived from a Novel Spirobifluorene-Based Dianhydride
URI http://dx.doi.org/10.1021/acsmacrolett.5b00009
https://www.ncbi.nlm.nih.gov/pubmed/35596413
https://www.proquest.com/docview/2667789085
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