Inherent Proton Conduction in a 2D Coordination Framework
We synthesized a coordination polymer consisting of Zn2+, 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton conduction by a coordination network. The compound has a two-dimensional layered structure with extended hydrogen bonds between the layers. It shows int...
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| Published in | Journal of the American Chemical Society Vol. 134; no. 30; pp. 12780 - 12785 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
01.08.2012
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| Subjects | |
| Online Access | Get full text |
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| Abstract | We synthesized a coordination polymer consisting of Zn2+, 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton conduction by a coordination network. The compound has a two-dimensional layered structure with extended hydrogen bonds between the layers. It shows intrinsic proton conductivity along the direction parallel to the layers, as elucidated by impedance studies of powder and single crystals. From the low activation energy for proton hopping, the conduction mechanism was found to be of the Grotthuss fashion. The hopping is promoted by rotation of phosphate ligands, which are aligned on the layers at appropriate intervals. |
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| AbstractList | We synthesized a coordination polymer consisting of Zn(2+), 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton conduction by a coordination network. The compound has a two-dimensional layered structure with extended hydrogen bonds between the layers. It shows intrinsic proton conductivity along the direction parallel to the layers, as elucidated by impedance studies of powder and single crystals. From the low activation energy for proton hopping, the conduction mechanism was found to be of the Grotthuss fashion. The hopping is promoted by rotation of phosphate ligands, which are aligned on the layers at appropriate intervals.We synthesized a coordination polymer consisting of Zn(2+), 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton conduction by a coordination network. The compound has a two-dimensional layered structure with extended hydrogen bonds between the layers. It shows intrinsic proton conductivity along the direction parallel to the layers, as elucidated by impedance studies of powder and single crystals. From the low activation energy for proton hopping, the conduction mechanism was found to be of the Grotthuss fashion. The hopping is promoted by rotation of phosphate ligands, which are aligned on the layers at appropriate intervals. We synthesized a coordination polymer consisting of Zn(2+), 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton conduction by a coordination network. The compound has a two-dimensional layered structure with extended hydrogen bonds between the layers. It shows intrinsic proton conductivity along the direction parallel to the layers, as elucidated by impedance studies of powder and single crystals. From the low activation energy for proton hopping, the conduction mechanism was found to be of the Grotthuss fashion. The hopping is promoted by rotation of phosphate ligands, which are aligned on the layers at appropriate intervals. We synthesized a coordination polymer consisting of Zn²⁺, 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton conduction by a coordination network. The compound has a two-dimensional layered structure with extended hydrogen bonds between the layers. It shows intrinsic proton conductivity along the direction parallel to the layers, as elucidated by impedance studies of powder and single crystals. From the low activation energy for proton hopping, the conduction mechanism was found to be of the Grotthuss fashion. The hopping is promoted by rotation of phosphate ligands, which are aligned on the layers at appropriate intervals. We synthesized a coordination polymer consisting of Zn2+, 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton conduction by a coordination network. The compound has a two-dimensional layered structure with extended hydrogen bonds between the layers. It shows intrinsic proton conductivity along the direction parallel to the layers, as elucidated by impedance studies of powder and single crystals. From the low activation energy for proton hopping, the conduction mechanism was found to be of the Grotthuss fashion. The hopping is promoted by rotation of phosphate ligands, which are aligned on the layers at appropriate intervals. |
| Author | Kitagawa, Susumu Umeyama, Daiki Horike, Satoshi Inukai, Munehiro Itakura, Tomoya |
| AuthorAffiliation | Kyoto University Japan Science and Technology Agency DENSO Corporation |
| AuthorAffiliation_xml | – name: DENSO Corporation – name: Japan Science and Technology Agency – name: Kyoto University |
| Author_xml | – sequence: 1 givenname: Daiki surname: Umeyama fullname: Umeyama, Daiki – sequence: 2 givenname: Satoshi surname: Horike fullname: Horike, Satoshi email: horike@sbchem.kyoto-u.ac.jp, kitagawa@icems.kyoto-u.ac.jp – sequence: 3 givenname: Munehiro surname: Inukai fullname: Inukai, Munehiro – sequence: 4 givenname: Tomoya surname: Itakura fullname: Itakura, Tomoya – sequence: 5 givenname: Susumu surname: Kitagawa fullname: Kitagawa, Susumu email: horike@sbchem.kyoto-u.ac.jp, kitagawa@icems.kyoto-u.ac.jp |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/22783808$$D View this record in MEDLINE/PubMed |
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| Snippet | We synthesized a coordination polymer consisting of Zn2+, 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton conduction... We synthesized a coordination polymer consisting of Zn(2+), 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton... We synthesized a coordination polymer consisting of Zn²⁺, 1,2,4-triazole, and orthophosphates, and demonstrated for the first time intrinsic proton conduction... |
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| SubjectTerms | activation energy coordination polymers crystals hydrogen bonding ligands orthophosphates zinc |
| Title | Inherent Proton Conduction in a 2D Coordination Framework |
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