Implications of the redissociation phenomenon for mineral-buffered fluids and aqueous species transport at elevated temperatures and pressures
•A 3-species model can describe NaCl(aq) and KCl(aq) behavior at elevated T and P.•This model predicts neutral complex redissociation at certain T, P conditions.•Redissociation impacts mineral solubilities, solution pH, and elemental fluxes.•We focus on feldspar–mica–quartz equilibria, but geologica...
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Published in | Applied geochemistry Vol. 55; no. C; pp. 119 - 127 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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01.04.2015
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Abstract | •A 3-species model can describe NaCl(aq) and KCl(aq) behavior at elevated T and P.•This model predicts neutral complex redissociation at certain T, P conditions.•Redissociation impacts mineral solubilities, solution pH, and elemental fluxes.•We focus on feldspar–mica–quartz equilibria, but geological implications are broad.
Aqueous species equilibrium constants and activity models form the foundation of the complex speciation codes used to model the geochemistry of geothermal energy production, extremophilic ecosystems, ore deposition, and a variety of other processes. Researchers have shown that a simple three species model (i.e., Na+, Cl−, and NaCl(aq)) can accurately describe conductivity measurements of concentrated NaCl and KCl solutions at elevated temperatures and pressures (Sharygin et al., 2002). In this model, activity coefficients of the charged species (e.g., Na+, K+, Cl−) become sufficiently low that the complexes must redisocciate with increasing salt concentration in order to meet equilibrium constant constraints. Redissociation decreases the proportion of the elements bound up as neutral complexes, and thereby increases the true ionic strength of the solution. In this contribution, we explore the consequences of the redissociation phenomenon in albite–paragonite–quartz (APQ) buffered systems. We focus on the implications of the redissociation phenomenon for mineral solubilities, particularly the observation that, at certain temperatures and pressures, calculated activities of charged ions in solution remain practically constant even as element concentrations increase from <1molal to 4.5molal. Finally, we note that redissociation has a similar effect on pH, and therefore aqueous speciation, in APQ-hosted systems. The calculations and discussion presented here are not limited to APQ-hosted systems, but additionally apply to many others in which the dominant cations and anions can form neutral complexes. |
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AbstractList | •A 3-species model can describe NaCl(aq) and KCl(aq) behavior at elevated T and P.•This model predicts neutral complex redissociation at certain T, P conditions.•Redissociation impacts mineral solubilities, solution pH, and elemental fluxes.•We focus on feldspar–mica–quartz equilibria, but geological implications are broad.
Aqueous species equilibrium constants and activity models form the foundation of the complex speciation codes used to model the geochemistry of geothermal energy production, extremophilic ecosystems, ore deposition, and a variety of other processes. Researchers have shown that a simple three species model (i.e., Na+, Cl−, and NaCl(aq)) can accurately describe conductivity measurements of concentrated NaCl and KCl solutions at elevated temperatures and pressures (Sharygin et al., 2002). In this model, activity coefficients of the charged species (e.g., Na+, K+, Cl−) become sufficiently low that the complexes must redisocciate with increasing salt concentration in order to meet equilibrium constant constraints. Redissociation decreases the proportion of the elements bound up as neutral complexes, and thereby increases the true ionic strength of the solution. In this contribution, we explore the consequences of the redissociation phenomenon in albite–paragonite–quartz (APQ) buffered systems. We focus on the implications of the redissociation phenomenon for mineral solubilities, particularly the observation that, at certain temperatures and pressures, calculated activities of charged ions in solution remain practically constant even as element concentrations increase from <1molal to 4.5molal. Finally, we note that redissociation has a similar effect on pH, and therefore aqueous speciation, in APQ-hosted systems. The calculations and discussion presented here are not limited to APQ-hosted systems, but additionally apply to many others in which the dominant cations and anions can form neutral complexes. |
Author | Tutolo, Benjamin M. Schaen, Adam T. Saar, Martin O. Seyfried, William E. |
Author_xml | – sequence: 1 givenname: Benjamin M. surname: Tutolo fullname: Tutolo, Benjamin M. email: tutol001@umn.edu – sequence: 2 givenname: Adam T. surname: Schaen fullname: Schaen, Adam T. – sequence: 3 givenname: Martin O. surname: Saar fullname: Saar, Martin O. – sequence: 4 givenname: William E. surname: Seyfried fullname: Seyfried, William E. |
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CitedBy_id | crossref_primary_10_1007_s11631_016_0130_6 crossref_primary_10_1016_j_gca_2016_12_002 crossref_primary_10_1016_j_geothermics_2015_02_005 crossref_primary_10_1016_j_jseaes_2015_09_010 crossref_primary_10_1016_j_gca_2015_04_002 crossref_primary_10_1016_j_jseaes_2015_10_006 crossref_primary_10_1016_j_ijggc_2015_05_026 crossref_primary_10_1016_j_apenergy_2014_11_043 crossref_primary_10_1016_j_gca_2015_04_040 |
Cites_doi | 10.1021/jp013647u 10.1016/S0009-2541(02)00263-2 10.2113/gselements.8.5.355 10.1016/j.geothermics.2004.11.004 10.1007/BF01166763 10.2174/978160805306311201010141 10.2475/ajs.274.10.1199 10.1016/S0016-7037(97)00070-7 10.1039/FT9928800803 10.7185/geochempersp.3.1 10.2172/919388 10.1021/jp0029818 10.1021/j100621a026 10.2475/ajs.288.1.19 10.1016/0016-7037(79)90114-5 10.1021/je300361j 10.2113/gsecongeo.70.3.577 10.1016/0016-7037(79)90026-7 10.1016/j.geothermics.2006.08.002 10.1021/j100848a050 10.1016/S1364-0321(02)00002-3 10.1016/0016-7037(75)90085-X 10.1016/0098-3004(92)90029-Q 10.1063/1.1461829 10.1016/0016-7037(88)90354-7 10.1016/0016-7037(86)90318-2 10.1016/0016-7037(80)90291-4 10.2475/ajs.267.7.729 10.1007/BF00974100 10.2475/ajs.291.6.541 10.1016/0016-7037(94)90489-8 10.2113/gsecongeo.95.5.971 10.1016/0016-7037(93)90383-8 10.2113/gsecongeo.100.4.613 10.1016/j.epsl.2005.04.041 10.1007/s004100050279 10.1016/S0016-7037(97)00274-3 10.1007/BF00373411 10.1029/2011GL047265 10.2475/ajs.257.4.241 10.1016/S0016-7037(97)00146-4 10.1016/S0016-7037(98)00313-5 10.1063/1.555643 10.1016/0016-7037(84)90098-X 10.1016/S0016-7037(97)00170-1 10.1016/0016-7037(87)90248-1 10.1016/0016-7037(91)90157-Z 10.2138/rmg.2013.76.5 10.1007/s004100050216 10.1016/S0016-7037(97)00009-4 10.1016/0016-7037(91)90303-M 10.1126/science.261.5123.888 10.1063/1.555888 10.2475/ajs.281.10.1249 10.1130/G35079.1 10.1016/0016-7037(93)90086-C 10.2475/ajs.284.6.651 10.1038/nrmicro1745 10.1016/S0016-7037(01)00899-7 10.1063/1.555915 10.1016/0016-7037(92)90297-V 10.2172/138894 10.2113/gsecongeo.59.4.538 10.1016/0016-7037(90)90368-U 10.1016/j.gca.2014.02.036 10.2113/gsecongeo.100.7.1287 10.1016/S0016-7037(98)00207-5 10.1016/0016-7037(88)90143-3 10.1016/0016-7037(87)90295-X |
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References | Helgeson, Kirkham, Flowers (b0115) 1981; 281 Manning (b0160) 2013; 76 Popp, Frantz (b0240) 1980; 44 Frantz, Marshall (b0055) 1984; 284 Quist, Marshall (b0250) 1968; 72 Archer (b0025) 1992; 21 Oelkers, Helgeson (b0185) 1990; 54 Tagirov, Schott, Harrichourry, Salvi (b0300) 2002; 66 Frantz, Popp (b0060) 1979; 43 Yardley (b0350) 2005; 100 Xie, Walther (b0345) 1993; 57 Zhang, G., Spycher, N., Xu, T., Sonnenthal, E., Steefel, C., 2006. Reactive Geochemical Transport Modeling of Concentrated Aqueous Solutions: Supplement to TOUGHREACT User’s Guide for the Pitzer Ion-Interaction Model. Duan, Sun (b0050) 2003; 193 Pitzer, Pabalan (b0220) 1986; 50 Aranovich, Newton (b0010) 1996; 125 Johnson, Oelkers, Helgeson (b9000) 1992; 18 Helgeson, Kirkham (b0110) 1974; 274 Hemley (b0120) 1959; 257 Helgeson (b0100) 1969; 267 Giggenbach (b0070) 1988; 52 Ho, Palmer, Gruszkiewicz (b0140) 2001; 105 Oelkers, Helgeson (b0190) 1991; 55 Gunter, Eugster (b0075) 1978; 66 Williams-Jones, Heinrich (b0325) 2005; 100 Bethke, C.M., Yeakel, S., 2012. The Geochemist’s Workbench Release 9.0 Reaction modeling guide. Aqueous Solutions LLC. Shock, Oelkers, Johnson, Sverjensky, Helgeson (b0275) 1992; 88 Sverjensky, Hemley, D’Angelo (b0285) 1991; 55 Tutolo, Kong, Saar, Seyfried (b0310) 2014; 133 Saccocia, Seyfried (b0265) 1994; 58 Reed (b0260) 1997; 3 Møller (b0175) 1988; 52 Yardley, Bodnar (b0355) 2014; 3 Montoya, Hemley (b0180) 1975; 70 Simmons, Browne (b0280) 2000; 95 Popp, Frantz (b0235) 1979; 43 Pitzer (b0215) 1973; 77 Marshall, Franck (b0165) 1981; 10 Jørgensen, Boetius (b0150) 2007; 5 Fridleifsson, Elders (b0065) 2005; 34 Wagner, Pruss (b0315) 2002; 31 Aranovich, Newton (b0015) 1997; 127 Junglas (b0155) 2009; 25 Sharygin, Wood, Zimmerman, Balashov (b0270) 2002; 106 Sverjensky, Shock, Helgeson (b0290) 1997; 61 Archer (b0020) 1991; 20 Woodland, Walther (b0340) 1987; 51 Anderson, Crerar (b0005) 1993 Pokrovskii, Helgeson (b0230) 1997; 61 Hammond, G., Lichtner, P., Lu, C., Mills, R., 2012. PFLOTRAN: reactive flow and transport code for use on laptops to leadership-class supercomputers. In: Zhang, F., Yeh, G.T., Parker, J.C. (Eds.), Ebook: Groundwater Reactive Transport Models, pp. 141–159. Johnson, Norton (b0145) 1991; 291 Oelkers, Helgeson (b0200) 1993; 261 Barbier (b0030) 2002; 6 Harvie, Møller, Weare (b0090) 1984; 48 Tanger, Helgeson (b0305) 1988; 288 Merino (b0170) 1975; 39 Ho, Palmer (b0130) 1997; 61 Williams-Jones, Migdisov, Samson (b0330) 2012; 8 Pokrovskii (b0225) 1999; 63 Tagirov, Zotov, Akinfiev (b0295) 1997; 61 Wolery, T.J., 1992. EQ3/6: A Software Package for Geochemical Modeling of Aqueous Systems: Package Overview and Installation Guide (version 7.0). Lawrence Livermore National Laboratory. Ding, Seyfried, Zhang, Tivey, Von Damm, Bradley (b0040) 2005; 237 Walther (b0320) 1997; 61 Hemley, Jones (b0125) 1964; 59 Pester, Ding, Seyfried (b0210) 2014 Oelkers, Helgeson (b0195) 1993; 57 Driesner, Seward, Tironi (b0045) 1998; 62 Helgeson (b0105) 1992; 56 Pabalan, Pitzer (b0205) 1987; 51 Pruess (b0245) 2006; 35 Gunter, Eugster (b0080) 1980; 75 Zimmerman, Arcis, Tremaine (b0365) 2012; 57 Ho, Palmer, Mesmer (b0135) 1994; 23 Helgeson (b0095) 1964 Randolph, Saar (b0255) 2011; 38 Harvie (10.1016/j.apgeochem.2014.11.002_b0090) 1984; 48 Pabalan (10.1016/j.apgeochem.2014.11.002_b0205) 1987; 51 Pitzer (10.1016/j.apgeochem.2014.11.002_b0220) 1986; 50 Johnson (10.1016/j.apgeochem.2014.11.002_b9000) 1992; 18 Archer (10.1016/j.apgeochem.2014.11.002_b0020) 1991; 20 Xie (10.1016/j.apgeochem.2014.11.002_b0345) 1993; 57 Tanger (10.1016/j.apgeochem.2014.11.002_b0305) 1988; 288 Barbier (10.1016/j.apgeochem.2014.11.002_b0030) 2002; 6 Merino (10.1016/j.apgeochem.2014.11.002_b0170) 1975; 39 Giggenbach (10.1016/j.apgeochem.2014.11.002_b0070) 1988; 52 Johnson (10.1016/j.apgeochem.2014.11.002_b0145) 1991; 291 Helgeson (10.1016/j.apgeochem.2014.11.002_b0110) 1974; 274 Junglas (10.1016/j.apgeochem.2014.11.002_b0155) 2009; 25 Montoya (10.1016/j.apgeochem.2014.11.002_b0180) 1975; 70 Sverjensky (10.1016/j.apgeochem.2014.11.002_b0285) 1991; 55 Jørgensen (10.1016/j.apgeochem.2014.11.002_b0150) 2007; 5 Yardley (10.1016/j.apgeochem.2014.11.002_b0350) 2005; 100 Ho (10.1016/j.apgeochem.2014.11.002_b0130) 1997; 61 Gunter (10.1016/j.apgeochem.2014.11.002_b0075) 1978; 66 Aranovich (10.1016/j.apgeochem.2014.11.002_b0015) 1997; 127 Oelkers (10.1016/j.apgeochem.2014.11.002_b0195) 1993; 57 Helgeson (10.1016/j.apgeochem.2014.11.002_b0105) 1992; 56 Popp (10.1016/j.apgeochem.2014.11.002_b0235) 1979; 43 Pokrovskii (10.1016/j.apgeochem.2014.11.002_b0225) 1999; 63 Driesner (10.1016/j.apgeochem.2014.11.002_b0045) 1998; 62 Zimmerman (10.1016/j.apgeochem.2014.11.002_b0365) 2012; 57 Manning (10.1016/j.apgeochem.2014.11.002_b0160) 2013; 76 Hemley (10.1016/j.apgeochem.2014.11.002_b0125) 1964; 59 Oelkers (10.1016/j.apgeochem.2014.11.002_b0200) 1993; 261 Helgeson (10.1016/j.apgeochem.2014.11.002_b0115) 1981; 281 10.1016/j.apgeochem.2014.11.002_b0335 Shock (10.1016/j.apgeochem.2014.11.002_b0275) 1992; 88 Møller (10.1016/j.apgeochem.2014.11.002_b0175) 1988; 52 Tagirov (10.1016/j.apgeochem.2014.11.002_b0300) 2002; 66 Reed (10.1016/j.apgeochem.2014.11.002_b0260) 1997; 3 Hemley (10.1016/j.apgeochem.2014.11.002_b0120) 1959; 257 Woodland (10.1016/j.apgeochem.2014.11.002_b0340) 1987; 51 Pester (10.1016/j.apgeochem.2014.11.002_b0210) 2014 Pruess (10.1016/j.apgeochem.2014.11.002_b0245) 2006; 35 Tutolo (10.1016/j.apgeochem.2014.11.002_b0310) 2014; 133 Ho (10.1016/j.apgeochem.2014.11.002_b0140) 2001; 105 Tagirov (10.1016/j.apgeochem.2014.11.002_b0295) 1997; 61 Yardley (10.1016/j.apgeochem.2014.11.002_b0355) 2014; 3 10.1016/j.apgeochem.2014.11.002_b0085 Williams-Jones (10.1016/j.apgeochem.2014.11.002_b0330) 2012; 8 10.1016/j.apgeochem.2014.11.002_b0360 Anderson (10.1016/j.apgeochem.2014.11.002_b0005) 1993 Oelkers (10.1016/j.apgeochem.2014.11.002_b0185) 1990; 54 Archer (10.1016/j.apgeochem.2014.11.002_b0025) 1992; 21 Randolph (10.1016/j.apgeochem.2014.11.002_b0255) 2011; 38 Marshall (10.1016/j.apgeochem.2014.11.002_b0165) 1981; 10 Frantz (10.1016/j.apgeochem.2014.11.002_b0060) 1979; 43 Helgeson (10.1016/j.apgeochem.2014.11.002_b0095) 1964 Sharygin (10.1016/j.apgeochem.2014.11.002_b0270) 2002; 106 Pokrovskii (10.1016/j.apgeochem.2014.11.002_b0230) 1997; 61 Simmons (10.1016/j.apgeochem.2014.11.002_b0280) 2000; 95 Ho (10.1016/j.apgeochem.2014.11.002_b0135) 1994; 23 Walther (10.1016/j.apgeochem.2014.11.002_b0320) 1997; 61 Duan (10.1016/j.apgeochem.2014.11.002_b0050) 2003; 193 Pitzer (10.1016/j.apgeochem.2014.11.002_b0215) 1973; 77 Saccocia (10.1016/j.apgeochem.2014.11.002_b0265) 1994; 58 Frantz (10.1016/j.apgeochem.2014.11.002_b0055) 1984; 284 Popp (10.1016/j.apgeochem.2014.11.002_b0240) 1980; 44 Aranovich (10.1016/j.apgeochem.2014.11.002_b0010) 1996; 125 Fridleifsson (10.1016/j.apgeochem.2014.11.002_b0065) 2005; 34 Sverjensky (10.1016/j.apgeochem.2014.11.002_b0290) 1997; 61 Wagner (10.1016/j.apgeochem.2014.11.002_b0315) 2002; 31 10.1016/j.apgeochem.2014.11.002_b0035 Williams-Jones (10.1016/j.apgeochem.2014.11.002_b0325) 2005; 100 Ding (10.1016/j.apgeochem.2014.11.002_b0040) 2005; 237 Gunter (10.1016/j.apgeochem.2014.11.002_b0080) 1980; 75 Helgeson (10.1016/j.apgeochem.2014.11.002_b0100) 1969; 267 Oelkers (10.1016/j.apgeochem.2014.11.002_b0190) 1991; 55 Quist (10.1016/j.apgeochem.2014.11.002_b0250) 1968; 72 |
References_xml | – volume: 23 start-page: 997 year: 1994 end-page: 1018 ident: b0135 article-title: Electrical conductivity measurements of aqueous sodium chloride solutions to 600 publication-title: J. Solution Chem. contributor: fullname: Mesmer – volume: 57 start-page: 2415 year: 2012 end-page: 2429 ident: b0365 article-title: Limiting conductivities and ion association constants of aqueous NaCl under hydrothermal conditions: experimental data and correlations publication-title: J. Chem. Eng. Data contributor: fullname: Tremaine – volume: 100 start-page: 613 year: 2005 end-page: 632 ident: b0350 article-title: 100th anniversary special paper: metal concentrations in crustal fluids and their relationship to ore formation publication-title: Econ. Geol. contributor: fullname: Yardley – volume: 257 start-page: 241 year: 1959 end-page: 270 ident: b0120 article-title: Some mineralogical equilibria in the system K publication-title: Am. J. Sci. contributor: fullname: Hemley – year: 1964 ident: b0095 article-title: Complexing and Hydrothermal Ore Deposition contributor: fullname: Helgeson – volume: 52 start-page: 821 year: 1988 end-page: 837 ident: b0175 article-title: The prediction of mineral solubilities in natural waters: a chemical equilibrium model for the Na–Ca–Cl–SO publication-title: Geochim. Cosmochim. Acta contributor: fullname: Møller – volume: 51 start-page: 2429 year: 1987 end-page: 2443 ident: b0205 article-title: Thermodynamics of concentrated electrolyte mixtures and the prediction of mineral solubilities to high temperatures for mixtures in the system Na–K–Mg–Cl–SO publication-title: Geochim. Cosmochim. Acta contributor: fullname: Pitzer – volume: 105 start-page: 1260 year: 2001 end-page: 1266 ident: b0140 article-title: Conductivity measurements of dilute aqueous HCl solutions to high temperatures and pressures using a flow-through cell publication-title: J. Phys. Chem. B contributor: fullname: Gruszkiewicz – volume: 261 start-page: 888 year: 1993 end-page: 891 ident: b0200 article-title: Multiple ion association in supercritical aqueous solutions of single electrolytes publication-title: Science contributor: fullname: Helgeson – volume: 274 start-page: 1199 year: 1974 end-page: 1261 ident: b0110 article-title: Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures: II. Debye–Hückel parameters for activity coefficients and relative partial molal properties publication-title: Am. J. Sci. contributor: fullname: Kirkham – volume: 284 start-page: 651 year: 1984 end-page: 667 ident: b0055 article-title: Electrical conductances and ionization constants of salts, acids, and bases in supercritical aqueous fluids: I. Hydrochloric acid from 100 to 700 publication-title: Am. J. Sci. contributor: fullname: Marshall – volume: 52 start-page: 2749 year: 1988 end-page: 2765 ident: b0070 article-title: Geothermal solute equilibria. Derivation of Na–K–Mg–Ca geoindicators publication-title: Geochim. Cosmochim. Acta contributor: fullname: Giggenbach – volume: 76 start-page: 135 year: 2013 end-page: 164 ident: b0160 article-title: Thermodynamic modeling of fluid-rock interaction at mid-crustal to upper-mantle conditions publication-title: Rev. Mineral. Geochem. contributor: fullname: Manning – volume: 127 start-page: 261 year: 1997 end-page: 271 ident: b0015 article-title: H publication-title: Contrib. Mineral. Petr. contributor: fullname: Newton – volume: 59 start-page: 538 year: 1964 end-page: 569 ident: b0125 article-title: Chemical aspects of hydrothermal alteration with emphasis on hydrogen metasomatism publication-title: Econ. Geol. contributor: fullname: Jones – volume: 106 start-page: 7121 year: 2002 end-page: 7134 ident: b0270 article-title: Multiple ion association versus redissociation in aqueous NaCl and KCl at high temperatures publication-title: J. Phys. Chem. B contributor: fullname: Balashov – volume: 3 start-page: 303 year: 1997 end-page: 365 ident: b0260 article-title: Hydrothermal alteration and its relationship to ore fluid composition publication-title: Geochem. Hydrothermal ore deposits contributor: fullname: Reed – volume: 61 start-page: 1359 year: 1997 end-page: 1412 ident: b0290 article-title: Prediction of the thermodynamic properties of aqueous metal complexes to 1000 publication-title: Geochim. Cosmochim. Acta contributor: fullname: Helgeson – volume: 10 start-page: 295 year: 1981 end-page: 304 ident: b0165 article-title: Ion product of water substance, 0–1000 publication-title: J. Phys. Chem. Ref. Data contributor: fullname: Franck – volume: 48 start-page: 723 year: 1984 end-page: 751 ident: b0090 article-title: The prediction of mineral solubilities in natural waters: The Na–K–Mg–Ca–H–Cl–SO publication-title: Geochim. Cosmochim. Acta contributor: fullname: Weare – volume: 31 start-page: 387 year: 2002 end-page: 536 ident: b0315 article-title: The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use publication-title: J. Phys. Chem. Ref. Data contributor: fullname: Pruss – volume: 6 start-page: 3 year: 2002 end-page: 65 ident: b0030 article-title: Geothermal energy technology and current status: an overview publication-title: Renew. Sust. Energy Rev. contributor: fullname: Barbier – volume: 66 start-page: 2013 year: 2002 end-page: 2024 ident: b0300 article-title: Experimental study of aluminum speciation in fluoride-rich supercritical fluids publication-title: Geochim. Cosmochim. Acta contributor: fullname: Salvi – volume: 61 start-page: 2175 year: 1997 end-page: 2183 ident: b0230 article-title: Calculation of the standard partial molal thermodynamic properties of KCl° and activity coefficients of aqueous KCl at temperatures and pressures to 1000 publication-title: Geochim. Cosmochim. Acta contributor: fullname: Helgeson – year: 1993 ident: b0005 article-title: Thermodynamics in Geochemistry: The Equilibrium Model contributor: fullname: Crerar – volume: 75 start-page: 235 year: 1980 end-page: 250 ident: b0080 article-title: Mica-feldspar equilibria in supercritical alkali chloride solutions publication-title: Contrib. Mineral. Petr. contributor: fullname: Eugster – volume: 5 start-page: 770 year: 2007 end-page: 781 ident: b0150 article-title: Feast and famine–microbial life in the deep-sea bed publication-title: Nat. Rev. Microbiol. contributor: fullname: Boetius – volume: 63 start-page: 1107 year: 1999 end-page: 1115 ident: b0225 article-title: Calculation of the standard partial molal thermodynamic properties and dissociation constants of aqueous HCl° and HBr° at temperatures to 1000 publication-title: Geochim. Cosmochim. Acta contributor: fullname: Pokrovskii – volume: 61 start-page: 3311 year: 1997 end-page: 3318 ident: b0320 article-title: Determination of activity coefficients of neutral species in supercritical H publication-title: Geochim. Cosmochim. Acta contributor: fullname: Walther – volume: 281 start-page: 1249 year: 1981 end-page: 1516 ident: b0115 article-title: Theoretical prediction of the thermodynamic behavior of aqueous electrolytes by high pressures and temperatures: IV. Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600 publication-title: Am. J. Sci. contributor: fullname: Flowers – volume: 95 start-page: 971 year: 2000 end-page: 999 ident: b0280 article-title: Hydrothermal minerals and precious metals in the broadlands–ohaaki geothermal system: Implications for understanding low-sulfidation epithermal environments publication-title: Econ. Geol. contributor: fullname: Browne – volume: 72 start-page: 684 year: 1968 end-page: 703 ident: b0250 article-title: Electrical conductances of aqueous sodium chloride solutions from 0° to 800° and at pressures to 4000 publication-title: J. Phys. Chem. contributor: fullname: Marshall – volume: 100 start-page: 1287 year: 2005 end-page: 1312 ident: b0325 article-title: 100th anniversary special paper: vapor transport of metals and the formation of magmatic–hydrothermal ore deposits publication-title: Econ. Geol. contributor: fullname: Heinrich – volume: 54 start-page: 727 year: 1990 end-page: 738 ident: b0185 article-title: Triple-ion anions and polynuclear complexing in supercritical electrolyte solutions publication-title: Geochim. Cosmochim. Acta contributor: fullname: Helgeson – volume: 57 start-page: 2673 year: 1993 end-page: 2697 ident: b0195 article-title: Calculation of dissociation constants and the relative stabilities of polynuclear clusters of 1:1 electrolytes in hydrothermal solutions at supercritical pressures and temperatures publication-title: Geochim. Cosmochim. Acta contributor: fullname: Helgeson – volume: 61 start-page: 4267 year: 1997 end-page: 4280 ident: b0295 article-title: Experimental study of dissociation of HCl from 350 to 500 publication-title: Geochim. Cosmochim. Acta contributor: fullname: Akinfiev – volume: 57 start-page: 1947 year: 1993 end-page: 1955 ident: b0345 article-title: Quartz solubilities in NaCl solutions with and without wollastonite at elevated temperatures and pressures publication-title: Geochim. Cosmochim. Acta contributor: fullname: Walther – volume: 66 start-page: 271 year: 1978 end-page: 281 ident: b0075 article-title: Wollastonite solubility and free energy of supercritical aqueous CaCl publication-title: Contrib. Mineral. Petr. contributor: fullname: Eugster – year: 2014 ident: b0210 article-title: Magmatic eruptions and iron volatility in deep-sea hydrothermal fluids publication-title: Geology contributor: fullname: Seyfried – volume: 25 start-page: 3 year: 2009 end-page: 10 ident: b0155 article-title: Water95: a Matlab implementation of the IAPWS-95 standard for use in thermodynamics lectures publication-title: Int. J. Eng. Educ. contributor: fullname: Junglas – volume: 193 start-page: 257 year: 2003 end-page: 271 ident: b0050 article-title: An improved model calculating CO publication-title: Chem. Geol. contributor: fullname: Sun – volume: 56 start-page: 3191 year: 1992 end-page: 3207 ident: b0105 article-title: Effects of complex formation in flowing fluids on the hydrothermal solubilities of minerals as a function of fluid pressure and temperature in the critical and supercritical regions of the system H publication-title: Geochim. Cosmochim. Acta contributor: fullname: Helgeson – volume: 39 start-page: 1629 year: 1975 end-page: 1645 ident: b0170 article-title: Diagenesis in Tertiary sandstones from Kettleman North Dome, California–II. Interstitial solutions: distribution of aqueous species at 100 publication-title: Geochim. Cosmochim. Acta contributor: fullname: Merino – volume: 237 start-page: 167 year: 2005 end-page: 174 ident: b0040 article-title: The in situ pH of hydrothermal fluids at mid-ocean ridges publication-title: Earth Planet. Sci. Lett. contributor: fullname: Bradley – volume: 88 start-page: 803 year: 1992 end-page: 826 ident: b0275 article-title: Calculation of the thermodynamic properties of aqueous species at high pressures and temperatures. Effective electrostatic radii, dissociation constants and standard partial molal properties to 1000 publication-title: J. Chem. Soc. Faraday Trans. contributor: fullname: Helgeson – volume: 34 start-page: 269 year: 2005 end-page: 285 ident: b0065 article-title: The iceland deep drilling project: a search for deep unconventional geothermal resources publication-title: Geothermics contributor: fullname: Elders – volume: 288 start-page: 19 year: 1988 end-page: 98 ident: b0305 article-title: Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures; revised equations of state for the standard partial molal properties of ions and electrolytes publication-title: Am. J. Sci. contributor: fullname: Helgeson – volume: 125 start-page: 200 year: 1996 end-page: 212 ident: b0010 article-title: H publication-title: Contrib. Mineral. Petr. contributor: fullname: Newton – volume: 55 start-page: 1235 year: 1991 end-page: 1251 ident: b0190 article-title: Calculation of activity coefficients and degrees of formation of neutral ion pairs in supercritical electrolyte solutions publication-title: Geochim. Cosmochim. Acta contributor: fullname: Helgeson – volume: 267 start-page: 729 year: 1969 end-page: 804 ident: b0100 article-title: Thermodynamics of hydrothermal systems at elevated temperatures and pressures publication-title: Am. J. Sci. contributor: fullname: Helgeson – volume: 3 start-page: 1 year: 2014 end-page: 123 ident: b0355 article-title: Fluids in the continental crust publication-title: Geochem. Perspec. contributor: fullname: Bodnar – volume: 51 start-page: 365 year: 1987 end-page: 372 ident: b0340 article-title: Experimental determination of the solubility of the assemblage paragonite, albite, and quartz in supercritical H publication-title: Geochim. Cosmochim. Acta contributor: fullname: Walther – volume: 35 start-page: 351 year: 2006 end-page: 367 ident: b0245 article-title: Enhanced geothermal systems (EGS) using CO publication-title: Geothermics contributor: fullname: Pruess – volume: 70 start-page: 577 year: 1975 end-page: 583 ident: b0180 article-title: Activity relations and stabilities in alkali feldspar and mica alteration reactions publication-title: Econ. Geol. contributor: fullname: Hemley – volume: 8 start-page: 355 year: 2012 end-page: 360 ident: b0330 article-title: Hydrothermal mobilisation of the rare earth elements – a tale of ceria and yttria publication-title: Elements contributor: fullname: Samson – volume: 43 start-page: 1223 year: 1979 end-page: 1239 ident: b0060 article-title: Mineral-solution equilibria–I. An experimental study of complexing and thermodynamic properties of aqueous MgCl publication-title: Geochim. Cosmochim. Acta contributor: fullname: Popp – volume: 61 start-page: 3027 year: 1997 end-page: 3040 ident: b0130 article-title: Ion association of dilute aqueous potassium chloride and potassium hydroxide solutions to 600 publication-title: Geochim. Cosmochim. Acta contributor: fullname: Palmer – volume: 62 start-page: 3095 year: 1998 end-page: 3107 ident: b0045 article-title: Molecular dynamics simulation study of ionic hydration and ion association in dilute and 1 publication-title: Geochim. et Cosmochim. Acta contributor: fullname: Tironi – volume: 77 start-page: 268 year: 1973 end-page: 277 ident: b0215 article-title: Thermodynamics of electrolytes. I. Theoretical basis and general equations publication-title: J. Phys. Chem. contributor: fullname: Pitzer – volume: 38 start-page: L10401 year: 2011 ident: b0255 article-title: Combining geothermal energy capture with geologic carbon dioxide sequestration publication-title: Geophys. Res. Lett. contributor: fullname: Saar – volume: 133 start-page: 216 year: 2014 end-page: 234 ident: b0310 article-title: Internal consistency in aqueous geochemical data revisited: applications to the aluminum system publication-title: Geochim. Cosmochim. Acta contributor: fullname: Seyfried – volume: 291 start-page: 541 year: 1991 end-page: 648 ident: b0145 article-title: Critical phenomena in hydrothermal systems; state, thermodynamic, electrostatic, and transport properties of H publication-title: Am. J. Sci. contributor: fullname: Norton – volume: 18 start-page: 899 year: 1992 end-page: 947 ident: b9000 article-title: SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000 C publication-title: Comput. Geosci. contributor: fullname: Helgeson – volume: 43 start-page: 1777 year: 1979 end-page: 1790 ident: b0235 article-title: Mineral solution equilibria-II. An experimental study of mineral solubilities and the thermodynamic properties of aqueous CaCl publication-title: Geochim. Cosmochim. Acta contributor: fullname: Frantz – volume: 44 start-page: 1029 year: 1980 end-page: 1037 ident: b0240 article-title: Mineral-solution equilibria-III. The system Na publication-title: Geochim. Cosmochim. Acta contributor: fullname: Frantz – volume: 58 start-page: 567 year: 1994 end-page: 585 ident: b0265 article-title: The solubility of chlorite solid solutions in 3.2 publication-title: Geochim. Cosmochim. Acta contributor: fullname: Seyfried – volume: 20 start-page: 509 year: 1991 end-page: 555 ident: b0020 article-title: Thermodynamic properties of the NaBr publication-title: J. Phys. Chem. Ref. Data contributor: fullname: Archer – volume: 21 start-page: 793 year: 1992 end-page: 829 ident: b0025 article-title: Thermodynamic properties of the NaCl publication-title: J. Phys. Chem. Ref. Data contributor: fullname: Archer – volume: 50 start-page: 1445 year: 1986 end-page: 1454 ident: b0220 article-title: Thermodynamics of NaCl in steam publication-title: Geochim. Cosmochim. Acta contributor: fullname: Pabalan – volume: 55 start-page: 989 year: 1991 end-page: 1004 ident: b0285 article-title: Thermodynamic assessment of hydrothermal alkali feldspar–mica–aluminosilicate equilibria publication-title: Geochim. Cosmochim. Acta contributor: fullname: D’Angelo – volume: 106 start-page: 7121 issue: 28 year: 2002 ident: 10.1016/j.apgeochem.2014.11.002_b0270 article-title: Multiple ion association versus redissociation in aqueous NaCl and KCl at high temperatures publication-title: J. Phys. Chem. B doi: 10.1021/jp013647u contributor: fullname: Sharygin – volume: 193 start-page: 257 issue: 3 year: 2003 ident: 10.1016/j.apgeochem.2014.11.002_b0050 article-title: An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533K and from 0 to 2000bar publication-title: Chem. Geol. doi: 10.1016/S0009-2541(02)00263-2 contributor: fullname: Duan – volume: 8 start-page: 355 issue: 5 year: 2012 ident: 10.1016/j.apgeochem.2014.11.002_b0330 article-title: Hydrothermal mobilisation of the rare earth elements – a tale of ceria and yttria publication-title: Elements doi: 10.2113/gselements.8.5.355 contributor: fullname: Williams-Jones – volume: 34 start-page: 269 issue: 3 year: 2005 ident: 10.1016/j.apgeochem.2014.11.002_b0065 article-title: The iceland deep drilling project: a search for deep unconventional geothermal resources publication-title: Geothermics doi: 10.1016/j.geothermics.2004.11.004 contributor: fullname: Fridleifsson – volume: 75 start-page: 235 issue: 3 year: 1980 ident: 10.1016/j.apgeochem.2014.11.002_b0080 article-title: Mica-feldspar equilibria in supercritical alkali chloride solutions publication-title: Contrib. Mineral. Petr. doi: 10.1007/BF01166763 contributor: fullname: Gunter – ident: 10.1016/j.apgeochem.2014.11.002_b0085 doi: 10.2174/978160805306311201010141 – volume: 274 start-page: 1199 issue: 10 year: 1974 ident: 10.1016/j.apgeochem.2014.11.002_b0110 article-title: Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures: II. Debye–Hückel parameters for activity coefficients and relative partial molal properties publication-title: Am. J. Sci. doi: 10.2475/ajs.274.10.1199 contributor: fullname: Helgeson – volume: 61 start-page: 2175 issue: 11 year: 1997 ident: 10.1016/j.apgeochem.2014.11.002_b0230 article-title: Calculation of the standard partial molal thermodynamic properties of KCl° and activity coefficients of aqueous KCl at temperatures and pressures to 1000°C and 5kbar publication-title: Geochim. Cosmochim. Acta doi: 10.1016/S0016-7037(97)00070-7 contributor: fullname: Pokrovskii – volume: 88 start-page: 803 issue: 6 year: 1992 ident: 10.1016/j.apgeochem.2014.11.002_b0275 article-title: Calculation of the thermodynamic properties of aqueous species at high pressures and temperatures. Effective electrostatic radii, dissociation constants and standard partial molal properties to 1000°C and 5kbar publication-title: J. Chem. Soc. Faraday Trans. doi: 10.1039/FT9928800803 contributor: fullname: Shock – volume: 3 start-page: 1 issue: 1 year: 2014 ident: 10.1016/j.apgeochem.2014.11.002_b0355 article-title: Fluids in the continental crust publication-title: Geochem. Perspec. doi: 10.7185/geochempersp.3.1 contributor: fullname: Yardley – ident: 10.1016/j.apgeochem.2014.11.002_b0360 doi: 10.2172/919388 – volume: 105 start-page: 1260 issue: 6 year: 2001 ident: 10.1016/j.apgeochem.2014.11.002_b0140 article-title: Conductivity measurements of dilute aqueous HCl solutions to high temperatures and pressures using a flow-through cell publication-title: J. Phys. Chem. B doi: 10.1021/jp0029818 contributor: fullname: Ho – volume: 77 start-page: 268 issue: 2 year: 1973 ident: 10.1016/j.apgeochem.2014.11.002_b0215 article-title: Thermodynamics of electrolytes. I. Theoretical basis and general equations publication-title: J. Phys. Chem. doi: 10.1021/j100621a026 contributor: fullname: Pitzer – volume: 288 start-page: 19 issue: 1 year: 1988 ident: 10.1016/j.apgeochem.2014.11.002_b0305 article-title: Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures; revised equations of state for the standard partial molal properties of ions and electrolytes publication-title: Am. J. Sci. doi: 10.2475/ajs.288.1.19 contributor: fullname: Tanger – volume: 43 start-page: 1223 issue: 8 year: 1979 ident: 10.1016/j.apgeochem.2014.11.002_b0060 article-title: Mineral-solution equilibria–I. An experimental study of complexing and thermodynamic properties of aqueous MgCl2 in the system MgO–SiO2–H2O–HCl publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(79)90114-5 contributor: fullname: Frantz – volume: 57 start-page: 2415 issue: 9 year: 2012 ident: 10.1016/j.apgeochem.2014.11.002_b0365 article-title: Limiting conductivities and ion association constants of aqueous NaCl under hydrothermal conditions: experimental data and correlations publication-title: J. Chem. Eng. Data doi: 10.1021/je300361j contributor: fullname: Zimmerman – volume: 70 start-page: 577 issue: 3 year: 1975 ident: 10.1016/j.apgeochem.2014.11.002_b0180 article-title: Activity relations and stabilities in alkali feldspar and mica alteration reactions publication-title: Econ. Geol. doi: 10.2113/gsecongeo.70.3.577 contributor: fullname: Montoya – volume: 43 start-page: 1777 issue: 11 year: 1979 ident: 10.1016/j.apgeochem.2014.11.002_b0235 article-title: Mineral solution equilibria-II. An experimental study of mineral solubilities and the thermodynamic properties of aqueous CaCl2 in the system CaO–SiO2–H2O–HCl publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(79)90026-7 contributor: fullname: Popp – volume: 35 start-page: 351 issue: 4 year: 2006 ident: 10.1016/j.apgeochem.2014.11.002_b0245 article-title: Enhanced geothermal systems (EGS) using CO2 as working fluid – a novel approach for generating renewable energy with simultaneous sequestration of carbon publication-title: Geothermics doi: 10.1016/j.geothermics.2006.08.002 contributor: fullname: Pruess – volume: 25 start-page: 3 issue: 1 year: 2009 ident: 10.1016/j.apgeochem.2014.11.002_b0155 article-title: Water95: a Matlab implementation of the IAPWS-95 standard for use in thermodynamics lectures publication-title: Int. J. Eng. Educ. contributor: fullname: Junglas – volume: 72 start-page: 684 issue: 2 year: 1968 ident: 10.1016/j.apgeochem.2014.11.002_b0250 article-title: Electrical conductances of aqueous sodium chloride solutions from 0° to 800° and at pressures to 4000bars publication-title: J. Phys. Chem. doi: 10.1021/j100848a050 contributor: fullname: Quist – volume: 6 start-page: 3 issue: 1 year: 2002 ident: 10.1016/j.apgeochem.2014.11.002_b0030 article-title: Geothermal energy technology and current status: an overview publication-title: Renew. Sust. Energy Rev. doi: 10.1016/S1364-0321(02)00002-3 contributor: fullname: Barbier – volume: 39 start-page: 1629 issue: 12 year: 1975 ident: 10.1016/j.apgeochem.2014.11.002_b0170 article-title: Diagenesis in Tertiary sandstones from Kettleman North Dome, California–II. Interstitial solutions: distribution of aqueous species at 100°C and chemical relation to the diagenetic mineralogy publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(75)90085-X contributor: fullname: Merino – year: 1964 ident: 10.1016/j.apgeochem.2014.11.002_b0095 contributor: fullname: Helgeson – volume: 3 start-page: 303 year: 1997 ident: 10.1016/j.apgeochem.2014.11.002_b0260 article-title: Hydrothermal alteration and its relationship to ore fluid composition publication-title: Geochem. Hydrothermal ore deposits contributor: fullname: Reed – volume: 18 start-page: 899 issue: 7 year: 1992 ident: 10.1016/j.apgeochem.2014.11.002_b9000 article-title: SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000 C publication-title: Comput. Geosci. doi: 10.1016/0098-3004(92)90029-Q contributor: fullname: Johnson – volume: 31 start-page: 387 issue: 2 year: 2002 ident: 10.1016/j.apgeochem.2014.11.002_b0315 article-title: The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use publication-title: J. Phys. Chem. Ref. Data doi: 10.1063/1.1461829 contributor: fullname: Wagner – volume: 52 start-page: 821 issue: 4 year: 1988 ident: 10.1016/j.apgeochem.2014.11.002_b0175 article-title: The prediction of mineral solubilities in natural waters: a chemical equilibrium model for the Na–Ca–Cl–SO4–H2O system, to high temperature and concentration publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(88)90354-7 contributor: fullname: Møller – volume: 50 start-page: 1445 issue: 7 year: 1986 ident: 10.1016/j.apgeochem.2014.11.002_b0220 article-title: Thermodynamics of NaCl in steam publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(86)90318-2 contributor: fullname: Pitzer – volume: 44 start-page: 1029 issue: 7 year: 1980 ident: 10.1016/j.apgeochem.2014.11.002_b0240 article-title: Mineral-solution equilibria-III. The system Na2O–Al2O3–SiO2–H2O–HCl publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(80)90291-4 contributor: fullname: Popp – volume: 267 start-page: 729 issue: 7 year: 1969 ident: 10.1016/j.apgeochem.2014.11.002_b0100 article-title: Thermodynamics of hydrothermal systems at elevated temperatures and pressures publication-title: Am. J. Sci. doi: 10.2475/ajs.267.7.729 contributor: fullname: Helgeson – volume: 23 start-page: 997 issue: 9 year: 1994 ident: 10.1016/j.apgeochem.2014.11.002_b0135 article-title: Electrical conductivity measurements of aqueous sodium chloride solutions to 600°C and 300MPa publication-title: J. Solution Chem. doi: 10.1007/BF00974100 contributor: fullname: Ho – volume: 291 start-page: 541 issue: 6 year: 1991 ident: 10.1016/j.apgeochem.2014.11.002_b0145 article-title: Critical phenomena in hydrothermal systems; state, thermodynamic, electrostatic, and transport properties of H2O in the critical region publication-title: Am. J. Sci. doi: 10.2475/ajs.291.6.541 contributor: fullname: Johnson – volume: 58 start-page: 567 issue: 2 year: 1994 ident: 10.1016/j.apgeochem.2014.11.002_b0265 article-title: The solubility of chlorite solid solutions in 3.2wt% NaCl fluids from 300 to 400C, 500bars publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(94)90489-8 contributor: fullname: Saccocia – volume: 95 start-page: 971 issue: 5 year: 2000 ident: 10.1016/j.apgeochem.2014.11.002_b0280 article-title: Hydrothermal minerals and precious metals in the broadlands–ohaaki geothermal system: Implications for understanding low-sulfidation epithermal environments publication-title: Econ. Geol. doi: 10.2113/gsecongeo.95.5.971 contributor: fullname: Simmons – volume: 57 start-page: 2673 issue: 12 year: 1993 ident: 10.1016/j.apgeochem.2014.11.002_b0195 article-title: Calculation of dissociation constants and the relative stabilities of polynuclear clusters of 1:1 electrolytes in hydrothermal solutions at supercritical pressures and temperatures publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(93)90383-8 contributor: fullname: Oelkers – volume: 100 start-page: 613 issue: 4 year: 2005 ident: 10.1016/j.apgeochem.2014.11.002_b0350 article-title: 100th anniversary special paper: metal concentrations in crustal fluids and their relationship to ore formation publication-title: Econ. Geol. doi: 10.2113/gsecongeo.100.4.613 contributor: fullname: Yardley – volume: 237 start-page: 167 issue: 1 year: 2005 ident: 10.1016/j.apgeochem.2014.11.002_b0040 article-title: The in situ pH of hydrothermal fluids at mid-ocean ridges publication-title: Earth Planet. Sci. Lett. doi: 10.1016/j.epsl.2005.04.041 contributor: fullname: Ding – volume: 127 start-page: 261 issue: 3 year: 1997 ident: 10.1016/j.apgeochem.2014.11.002_b0015 article-title: H2O activity in concentrated KCl and KCl–NaCl solutions at high temperatures and pressures measured by the brucite-periclase equilibrium publication-title: Contrib. Mineral. Petr. doi: 10.1007/s004100050279 contributor: fullname: Aranovich – volume: 61 start-page: 4267 issue: 20 year: 1997 ident: 10.1016/j.apgeochem.2014.11.002_b0295 article-title: Experimental study of dissociation of HCl from 350 to 500°C and from 500 to 2500bars: thermodynamic properties of HCl(aq)° publication-title: Geochim. Cosmochim. Acta doi: 10.1016/S0016-7037(97)00274-3 contributor: fullname: Tagirov – ident: 10.1016/j.apgeochem.2014.11.002_b0035 – volume: 66 start-page: 271 issue: 3 year: 1978 ident: 10.1016/j.apgeochem.2014.11.002_b0075 article-title: Wollastonite solubility and free energy of supercritical aqueous CaCl2 publication-title: Contrib. Mineral. Petr. doi: 10.1007/BF00373411 contributor: fullname: Gunter – volume: 38 start-page: L10401 issue: 10 year: 2011 ident: 10.1016/j.apgeochem.2014.11.002_b0255 article-title: Combining geothermal energy capture with geologic carbon dioxide sequestration publication-title: Geophys. Res. Lett. doi: 10.1029/2011GL047265 contributor: fullname: Randolph – year: 1993 ident: 10.1016/j.apgeochem.2014.11.002_b0005 contributor: fullname: Anderson – volume: 257 start-page: 241 issue: 4 year: 1959 ident: 10.1016/j.apgeochem.2014.11.002_b0120 article-title: Some mineralogical equilibria in the system K2O–Al2O3–SiO2–H2O publication-title: Am. J. Sci. doi: 10.2475/ajs.257.4.241 contributor: fullname: Hemley – volume: 61 start-page: 3027 issue: 15 year: 1997 ident: 10.1016/j.apgeochem.2014.11.002_b0130 article-title: Ion association of dilute aqueous potassium chloride and potassium hydroxide solutions to 600°C and 300MPa determined by electrical conductance measurements publication-title: Geochim. Cosmochim. Acta doi: 10.1016/S0016-7037(97)00146-4 contributor: fullname: Ho – volume: 63 start-page: 1107 issue: 7 year: 1999 ident: 10.1016/j.apgeochem.2014.11.002_b0225 article-title: Calculation of the standard partial molal thermodynamic properties and dissociation constants of aqueous HCl° and HBr° at temperatures to 1000°C and pressures to 5kbar publication-title: Geochim. Cosmochim. Acta doi: 10.1016/S0016-7037(98)00313-5 contributor: fullname: Pokrovskii – volume: 10 start-page: 295 issue: 2 year: 1981 ident: 10.1016/j.apgeochem.2014.11.002_b0165 article-title: Ion product of water substance, 0–1000°C, 1–10,000bars new international formulation and its background publication-title: J. Phys. Chem. Ref. Data doi: 10.1063/1.555643 contributor: fullname: Marshall – volume: 48 start-page: 723 year: 1984 ident: 10.1016/j.apgeochem.2014.11.002_b0090 article-title: The prediction of mineral solubilities in natural waters: The Na–K–Mg–Ca–H–Cl–SO4–OH–HCO3–CO3–CO2–H2O system to high ionic strengths at 25°C publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(84)90098-X contributor: fullname: Harvie – volume: 61 start-page: 3311 issue: 16 year: 1997 ident: 10.1016/j.apgeochem.2014.11.002_b0320 article-title: Determination of activity coefficients of neutral species in supercritical H2O solutions publication-title: Geochim. Cosmochim. Acta doi: 10.1016/S0016-7037(97)00170-1 contributor: fullname: Walther – volume: 51 start-page: 365 issue: 2 year: 1987 ident: 10.1016/j.apgeochem.2014.11.002_b0340 article-title: Experimental determination of the solubility of the assemblage paragonite, albite, and quartz in supercritical H2O publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(87)90248-1 contributor: fullname: Woodland – volume: 55 start-page: 989 issue: 4 year: 1991 ident: 10.1016/j.apgeochem.2014.11.002_b0285 article-title: Thermodynamic assessment of hydrothermal alkali feldspar–mica–aluminosilicate equilibria publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(91)90157-Z contributor: fullname: Sverjensky – volume: 76 start-page: 135 issue: 1 year: 2013 ident: 10.1016/j.apgeochem.2014.11.002_b0160 article-title: Thermodynamic modeling of fluid-rock interaction at mid-crustal to upper-mantle conditions publication-title: Rev. Mineral. Geochem. doi: 10.2138/rmg.2013.76.5 contributor: fullname: Manning – volume: 125 start-page: 200 issue: 2–3 year: 1996 ident: 10.1016/j.apgeochem.2014.11.002_b0010 article-title: H2O activity in concentrated NaCl solutions at high pressures and temperatures measured by the brucite-periclase equilibrium publication-title: Contrib. Mineral. Petr. doi: 10.1007/s004100050216 contributor: fullname: Aranovich – volume: 61 start-page: 1359 issue: 7 year: 1997 ident: 10.1016/j.apgeochem.2014.11.002_b0290 article-title: Prediction of the thermodynamic properties of aqueous metal complexes to 1000°C and 5kbar publication-title: Geochim. Cosmochim. Acta doi: 10.1016/S0016-7037(97)00009-4 contributor: fullname: Sverjensky – volume: 55 start-page: 1235 issue: 5 year: 1991 ident: 10.1016/j.apgeochem.2014.11.002_b0190 article-title: Calculation of activity coefficients and degrees of formation of neutral ion pairs in supercritical electrolyte solutions publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(91)90303-M contributor: fullname: Oelkers – volume: 261 start-page: 888 issue: 5123 year: 1993 ident: 10.1016/j.apgeochem.2014.11.002_b0200 article-title: Multiple ion association in supercritical aqueous solutions of single electrolytes publication-title: Science doi: 10.1126/science.261.5123.888 contributor: fullname: Oelkers – volume: 20 start-page: 509 issue: 3 year: 1991 ident: 10.1016/j.apgeochem.2014.11.002_b0020 article-title: Thermodynamic properties of the NaBr+H2O system publication-title: J. Phys. Chem. Ref. Data doi: 10.1063/1.555888 contributor: fullname: Archer – volume: 281 start-page: 1249 issue: 10 year: 1981 ident: 10.1016/j.apgeochem.2014.11.002_b0115 publication-title: Am. J. Sci. doi: 10.2475/ajs.281.10.1249 contributor: fullname: Helgeson – year: 2014 ident: 10.1016/j.apgeochem.2014.11.002_b0210 article-title: Magmatic eruptions and iron volatility in deep-sea hydrothermal fluids publication-title: Geology doi: 10.1130/G35079.1 contributor: fullname: Pester – volume: 57 start-page: 1947 issue: 9 year: 1993 ident: 10.1016/j.apgeochem.2014.11.002_b0345 article-title: Quartz solubilities in NaCl solutions with and without wollastonite at elevated temperatures and pressures publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(93)90086-C contributor: fullname: Xie – volume: 284 start-page: 651 issue: 6 year: 1984 ident: 10.1016/j.apgeochem.2014.11.002_b0055 article-title: Electrical conductances and ionization constants of salts, acids, and bases in supercritical aqueous fluids: I. Hydrochloric acid from 100 to 700°C and at pressures to 4000bars publication-title: Am. J. Sci. doi: 10.2475/ajs.284.6.651 contributor: fullname: Frantz – volume: 5 start-page: 770 issue: 10 year: 2007 ident: 10.1016/j.apgeochem.2014.11.002_b0150 article-title: Feast and famine–microbial life in the deep-sea bed publication-title: Nat. Rev. Microbiol. doi: 10.1038/nrmicro1745 contributor: fullname: Jørgensen – volume: 66 start-page: 2013 issue: 11 year: 2002 ident: 10.1016/j.apgeochem.2014.11.002_b0300 article-title: Experimental study of aluminum speciation in fluoride-rich supercritical fluids publication-title: Geochim. Cosmochim. Acta doi: 10.1016/S0016-7037(01)00899-7 contributor: fullname: Tagirov – volume: 21 start-page: 793 issue: 4 year: 1992 ident: 10.1016/j.apgeochem.2014.11.002_b0025 article-title: Thermodynamic properties of the NaCl+H2O system. II. Thermodynamic properties of NaCl (aq), NaCl·2H2O(cr), and phase equilibria publication-title: J. Phys. Chem. Ref. Data doi: 10.1063/1.555915 contributor: fullname: Archer – volume: 56 start-page: 3191 issue: 8 year: 1992 ident: 10.1016/j.apgeochem.2014.11.002_b0105 article-title: Effects of complex formation in flowing fluids on the hydrothermal solubilities of minerals as a function of fluid pressure and temperature in the critical and supercritical regions of the system H2O publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(92)90297-V contributor: fullname: Helgeson – ident: 10.1016/j.apgeochem.2014.11.002_b0335 doi: 10.2172/138894 – volume: 59 start-page: 538 issue: 4 year: 1964 ident: 10.1016/j.apgeochem.2014.11.002_b0125 article-title: Chemical aspects of hydrothermal alteration with emphasis on hydrogen metasomatism publication-title: Econ. Geol. doi: 10.2113/gsecongeo.59.4.538 contributor: fullname: Hemley – volume: 54 start-page: 727 issue: 3 year: 1990 ident: 10.1016/j.apgeochem.2014.11.002_b0185 article-title: Triple-ion anions and polynuclear complexing in supercritical electrolyte solutions publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(90)90368-U contributor: fullname: Oelkers – volume: 133 start-page: 216 year: 2014 ident: 10.1016/j.apgeochem.2014.11.002_b0310 article-title: Internal consistency in aqueous geochemical data revisited: applications to the aluminum system publication-title: Geochim. Cosmochim. Acta doi: 10.1016/j.gca.2014.02.036 contributor: fullname: Tutolo – volume: 100 start-page: 1287 issue: 7 year: 2005 ident: 10.1016/j.apgeochem.2014.11.002_b0325 article-title: 100th anniversary special paper: vapor transport of metals and the formation of magmatic–hydrothermal ore deposits publication-title: Econ. Geol. doi: 10.2113/gsecongeo.100.7.1287 contributor: fullname: Williams-Jones – volume: 62 start-page: 3095 issue: 18 year: 1998 ident: 10.1016/j.apgeochem.2014.11.002_b0045 article-title: Molecular dynamics simulation study of ionic hydration and ion association in dilute and 1molal aqueous sodium chloride solutions from ambient to supercritical conditions publication-title: Geochim. et Cosmochim. Acta doi: 10.1016/S0016-7037(98)00207-5 contributor: fullname: Driesner – volume: 52 start-page: 2749 issue: 12 year: 1988 ident: 10.1016/j.apgeochem.2014.11.002_b0070 article-title: Geothermal solute equilibria. Derivation of Na–K–Mg–Ca geoindicators publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(88)90143-3 contributor: fullname: Giggenbach – volume: 51 start-page: 2429 issue: 9 year: 1987 ident: 10.1016/j.apgeochem.2014.11.002_b0205 article-title: Thermodynamics of concentrated electrolyte mixtures and the prediction of mineral solubilities to high temperatures for mixtures in the system Na–K–Mg–Cl–SO4–OH–H2O publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(87)90295-X contributor: fullname: Pabalan |
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Title | Implications of the redissociation phenomenon for mineral-buffered fluids and aqueous species transport at elevated temperatures and pressures |
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