Shape-Controlled Synthesis of Pt Nanocrystals: The Role of Metal Carbonyls

Well-controlled synthesis of nanocrystals is necessary to unambiguously correlate the structural properties of nanocrystals with the catalytic properties. The most common low-index surfaces are (111) and (100). Therefore, model materials with {111} and {100} facets are highly desirable, in order to...

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Published inACS nano Vol. 7; no. 1; pp. 645 - 653
Main Authors Kang, Yijin, Pyo, Jun Beom, Ye, Xingchen, Diaz, Rosa E, Gordon, Thomas R, Stach, Eric A, Murray, Christopher B
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 22.01.2013
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Abstract Well-controlled synthesis of nanocrystals is necessary to unambiguously correlate the structural properties of nanocrystals with the catalytic properties. The most common low-index surfaces are (111) and (100). Therefore, model materials with {111} and {100} facets are highly desirable, in order to understand the catalytic properties of (111) and (100) surfaces for various structure-sensitive reactions. We report a solution-phase synthesis using metal carbonyls as additives. This synthetic method produces highly monodisperse Pt octahedra and icosahedra as the model of Pt{111}, Pt cubes as the model of Pt{100}, respectively. Several other morphologies, such as truncated cubes, cuboctahedra, spheres, tetrapods, star-shaped octapods, multipods, and hyper-branched structure, are produced, as well. A bifunctional role of metal carbonyl in the synthesis is identified: zerovalent transition metal decomposed from metal carbonyl acts as a shape-directing agent, while CO provides the reducing power. These high-quality shape-controlled Pt nanocrystals are suitable for model catalyst studies.
AbstractList Well-controlled synthesis of nanocrystals is necessary to unambiguously correlate the structural properties of nanocrystals with the catalytic properties. The most common low-index surfaces are (111) and (100). Therefore, model materials with {111} and {100} facets are highly desirable, in order to understand the catalytic properties of (111) and (100) surfaces for various structure-sensitive reactions. We report a solution-phase synthesis using metal carbonyls as additives. This synthetic method produces highly monodisperse Pt octahedra and icosahedra as the model of Pt{111}, Pt cubes as the model of Pt{100}, respectively. Several other morphologies, such as truncated cubes, cuboctahedra, spheres, tetrapods, star-shaped octapods, multipods, and hyper-branched structure, are produced, as well. A bifunctional role of metal carbonyl in the synthesis is identified: zerovalent transition metal decomposed from metal carbonyl acts as a shape-directing agent, while CO provides the reducing power. These high-quality shape-controlled Pt nanocrystals are suitable for model catalyst studies.
Author Kang, Yijin
Gordon, Thomas R
Ye, Xingchen
Stach, Eric A
Murray, Christopher B
Diaz, Rosa E
Pyo, Jun Beom
AuthorAffiliation Department of Chemistry
Department of Materials Science and Engineering
University of Pennsylvania
Brookhaven National Laboratory
AuthorAffiliation_xml – name: University of Pennsylvania
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– name: Department of Chemistry
– name: Brookhaven National Laboratory
– name: Department of Materials Science and Engineering
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  givenname: Yijin
  surname: Kang
  fullname: Kang, Yijin
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  givenname: Jun Beom
  surname: Pyo
  fullname: Pyo, Jun Beom
– sequence: 3
  givenname: Xingchen
  surname: Ye
  fullname: Ye, Xingchen
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  givenname: Rosa E
  surname: Diaz
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  givenname: Thomas R
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  givenname: Eric A
  surname: Stach
  fullname: Stach, Eric A
– sequence: 7
  givenname: Christopher B
  surname: Murray
  fullname: Murray, Christopher B
  email: cbmurray@sas.upenn.edu
BackLink https://www.ncbi.nlm.nih.gov/pubmed/23211025$$D View this record in MEDLINE/PubMed
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Keywords nanocrystal
platinum
shape control
morphology
CO oxidation
catalysis
electrocatalysis
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Snippet Well-controlled synthesis of nanocrystals is necessary to unambiguously correlate the structural properties of nanocrystals with the catalytic properties. The...
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SubjectTerms Catalysis
Catalysts
Crystallization - methods
Cubes
Macromolecular Substances - chemistry
Materials Testing
Metal carbonyls
Metal Nanoparticles - chemistry
Metal Nanoparticles - ultrastructure
Molecular Conformation
Nanocrystals
Nanostructure
Particle Size
Platinum
Platinum - chemistry
Surface Properties
Synthesis
Transition metals
Title Shape-Controlled Synthesis of Pt Nanocrystals: The Role of Metal Carbonyls
URI http://dx.doi.org/10.1021/nn3048439
https://www.ncbi.nlm.nih.gov/pubmed/23211025
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