Copper-Mediated Direct Aryloxylation of Benzamides Assisted by an N,O‑Bidentate Directing Group
Copper-mediated selective mono- or diaryloxylation of benzamides has been achieved by using 2-aminopyridine 1-oxide as a new and removable N,O-bidentate directing group. The reaction system shows a broad substrate scope and provides a straightforward way for the synthesis of mono- and diaryloxylated...
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| Published in | Organic letters Vol. 16; no. 4; pp. 1104 - 1107 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
WASHINGTON
American Chemical Society
21.02.2014
Amer Chemical Soc |
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| Online Access | Get full text |
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| Abstract | Copper-mediated selective mono- or diaryloxylation of benzamides has been achieved by using 2-aminopyridine 1-oxide as a new and removable N,O-bidentate directing group. The reaction system shows a broad substrate scope and provides a straightforward way for the synthesis of mono- and diaryloxylated benzoic acids. |
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| AbstractList | Copper-mediated selective mono- or diaryloxylation of benzamides has been achieved by using 2-aminopyridine 1-oxide as a new and removable N,O-bidentate directing group. The reaction system shows a broad substrate scope and provides a straightforward way for the synthesis of mono- and diaryloxylated benzoic acids. Copper-mediated selective mono- or diaryloxylation of benzamides has been achieved by using 2-aminopyridine 1-oxide as a new and removable N,O-bidentate directing group. The reaction system shows a broad substrate scope and provides a straightforward way for the synthesis of mono- and diaryloxylated benzoic acids.Copper-mediated selective mono- or diaryloxylation of benzamides has been achieved by using 2-aminopyridine 1-oxide as a new and removable N,O-bidentate directing group. The reaction system shows a broad substrate scope and provides a straightforward way for the synthesis of mono- and diaryloxylated benzoic acids. |
| Author | Hao, Xin-Qi Song, Mao-Ping Ren, Baozeng Li, Liu-Yan Gong, Jun-Fang Niu, Jun-Long Chen, Li-Juan Yang, Xin-Yan |
| AuthorAffiliation | The College of Chemistry and Molecular Engineering, Henan Key Laboratory of Chemical Biology and Organic Chemistry School of Chemical Engineering and Energy Zhengzhou University |
| AuthorAffiliation_xml | – name: The College of Chemistry and Molecular Engineering, Henan Key Laboratory of Chemical Biology and Organic Chemistry – name: Zhengzhou University – name: School of Chemical Engineering and Energy |
| Author_xml | – sequence: 1 givenname: Xin-Qi surname: Hao fullname: Hao, Xin-Qi – sequence: 2 givenname: Li-Juan surname: Chen fullname: Chen, Li-Juan – sequence: 3 givenname: Baozeng surname: Ren fullname: Ren, Baozeng – sequence: 4 givenname: Liu-Yan surname: Li fullname: Li, Liu-Yan – sequence: 5 givenname: Xin-Yan surname: Yang fullname: Yang, Xin-Yan – sequence: 6 givenname: Jun-Fang surname: Gong fullname: Gong, Jun-Fang – sequence: 7 givenname: Jun-Long surname: Niu fullname: Niu, Jun-Long email: niujunlong@zzu.edu.cn – sequence: 8 givenname: Mao-Ping surname: Song fullname: Song, Mao-Ping email: mpsong@zzu.edu.cn |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/24502415$$D View this record in MEDLINE/PubMed |
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| Keywords | BIDENTATE-CHELATION ASSISTANCE FUNCTIONALIZATION ACID DERIVATIVES CROSS-COUPLING REACTIONS ACTIVATION DIRECT ARYLATION AROMATIC AMIDES ARYL DIARYL ETHERS C-H BONDS |
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| Snippet | Copper-mediated selective mono- or diaryloxylation of benzamides has been achieved by using 2-aminopyridine 1-oxide as a new and removable N,O-bidentate... |
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| SubjectTerms | benzamides benzoic acids chemical reactions chemical structure Chemistry Chemistry, Organic Physical Sciences Science & Technology |
| Title | Copper-Mediated Direct Aryloxylation of Benzamides Assisted by an N,O‑Bidentate Directing Group |
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