Plasmonic Enhancement of Nanophosphor Upconversion Luminescence in Au Nanohole Arrays
Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)hexagonal phase NaYF4 doped with Yb3+ and Er3+. The dimensions of nanohole Au arrays were designed to...
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Published in | ACS nano Vol. 7; no. 8; pp. 7186 - 7192 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
27.08.2013
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Subjects | |
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Abstract | Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)hexagonal phase NaYF4 doped with Yb3+ and Er3+. The dimensions of nanohole Au arrays were designed to accept only a single UCNP upon particle filling and with a periodicity to be resonant with the excitation wavelength of the upconversion. Frequency-dependent luminescence enhancements of up to 35-fold and a concomitant shortening of the UCNP luminescence rise time were observed, consistent with simulations of plasmonic enhancement of the UCNP absorption. |
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AbstractList | Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)hexagonal phase NaYF4 doped with Yb3+ and Er3+. The dimensions of nanohole Au arrays were designed to accept only a single UCNP upon particle filling and with a periodicity to be resonant with the excitation wavelength of the upconversion. Frequency-dependent luminescence enhancements of up to 35-fold and a concomitant shortening of the UCNP luminescence rise time were observed, consistent with simulations of plasmonic enhancement of the UCNP absorption. Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)--hexagonal phase NaYF4 doped with Yb(3+) and Er(3+). The dimensions of nanohole Au arrays were designed to accept only a single UCNP upon particle filling and with a periodicity to be resonant with the excitation wavelength of the upconversion. Frequency-dependent luminescence enhancements of up to 35-fold and a concomitant shortening of the UCNP luminescence rise time were observed, consistent with simulations of plasmonic enhancement of the UCNP absorption. Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)-hexagonal phase NaYF sub(4) doped with Yb super(3+) and Er super(3+). The dimensions of nanohole Au arrays were designed to accept only a single UCNP upon particle filling and with a periodicity to be resonant with the excitation wavelength of the upconversion. Frequency-dependent luminescence enhancements of up to 35-fold and a concomitant shortening of the UCNP luminescence rise time were observed, consistent with simulations of plasmonic enhancement of the UCNP absorption. |
Author | Kagan, Cherie R Engheta, Nader Murray, Christopher B Ye, Xingchen Saboktakin, Marjan Chettiar, Uday K |
AuthorAffiliation | Department of Chemistry Department of Physics and Astronomy Department of Electrical and Systems Engineering Department of Materials Science and Engineering Department of Bioengineering University of Pennsylvania |
AuthorAffiliation_xml | – name: University of Pennsylvania – name: Department of Bioengineering – name: – name: Department of Electrical and Systems Engineering – name: Department of Chemistry – name: Department of Physics and Astronomy – name: Department of Materials Science and Engineering |
Author_xml | – sequence: 1 givenname: Marjan surname: Saboktakin fullname: Saboktakin, Marjan – sequence: 2 givenname: Xingchen surname: Ye fullname: Ye, Xingchen – sequence: 3 givenname: Uday K surname: Chettiar fullname: Chettiar, Uday K – sequence: 4 givenname: Nader surname: Engheta fullname: Engheta, Nader – sequence: 5 givenname: Christopher B surname: Murray fullname: Murray, Christopher B – sequence: 6 givenname: Cherie R surname: Kagan fullname: Kagan, Cherie R email: kagan@seas.upenn.edu |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/23909608$$D View this record in MEDLINE/PubMed |
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Keywords | lanthanide squeegee method upconversion nanohole array plasmonically enhanced luminescence nanophosphor |
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Snippet | Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence... |
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SubjectTerms | Absorption Arrays Biosensing Techniques Colloids - chemistry Computation Computer Simulation Excitation Finite Element Analysis Luminescence Luminescent Measurements Microscopy, Electron, Scanning Microscopy, Electron, Transmission Nanoparticles - chemistry Nanostructure Nanotechnology - methods Optics and Photonics Plasmonics Silver - chemistry Surface Properties Upconversion Wavelengths |
Title | Plasmonic Enhancement of Nanophosphor Upconversion Luminescence in Au Nanohole Arrays |
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