Plasmonic Enhancement of Nanophosphor Upconversion Luminescence in Au Nanohole Arrays

Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)hexagonal phase NaYF4 doped with Yb3+ and Er3+. The dimensions of nanohole Au arrays were designed to...

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Published inACS nano Vol. 7; no. 8; pp. 7186 - 7192
Main Authors Saboktakin, Marjan, Ye, Xingchen, Chettiar, Uday K, Engheta, Nader, Murray, Christopher B, Kagan, Cherie R
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 27.08.2013
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Abstract Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)hexagonal phase NaYF4 doped with Yb3+ and Er3+. The dimensions of nanohole Au arrays were designed to accept only a single UCNP upon particle filling and with a periodicity to be resonant with the excitation wavelength of the upconversion. Frequency-dependent luminescence enhancements of up to 35-fold and a concomitant shortening of the UCNP luminescence rise time were observed, consistent with simulations of plasmonic enhancement of the UCNP absorption.
AbstractList Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)hexagonal phase NaYF4 doped with Yb3+ and Er3+. The dimensions of nanohole Au arrays were designed to accept only a single UCNP upon particle filling and with a periodicity to be resonant with the excitation wavelength of the upconversion. Frequency-dependent luminescence enhancements of up to 35-fold and a concomitant shortening of the UCNP luminescence rise time were observed, consistent with simulations of plasmonic enhancement of the UCNP absorption.
Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)--hexagonal phase NaYF4 doped with Yb(3+) and Er(3+). The dimensions of nanohole Au arrays were designed to accept only a single UCNP upon particle filling and with a periodicity to be resonant with the excitation wavelength of the upconversion. Frequency-dependent luminescence enhancements of up to 35-fold and a concomitant shortening of the UCNP luminescence rise time were observed, consistent with simulations of plasmonic enhancement of the UCNP absorption.
Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence of upconversion nanophosphors (UCNPs)-hexagonal phase NaYF sub(4) doped with Yb super(3+) and Er super(3+). The dimensions of nanohole Au arrays were designed to accept only a single UCNP upon particle filling and with a periodicity to be resonant with the excitation wavelength of the upconversion. Frequency-dependent luminescence enhancements of up to 35-fold and a concomitant shortening of the UCNP luminescence rise time were observed, consistent with simulations of plasmonic enhancement of the UCNP absorption.
Author Kagan, Cherie R
Engheta, Nader
Murray, Christopher B
Ye, Xingchen
Saboktakin, Marjan
Chettiar, Uday K
AuthorAffiliation Department of Chemistry
Department of Physics and Astronomy
Department of Electrical and Systems Engineering
Department of Materials Science and Engineering
Department of Bioengineering
University of Pennsylvania
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  givenname: Xingchen
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  givenname: Uday K
  surname: Chettiar
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  surname: Kagan
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  email: kagan@seas.upenn.edu
BackLink https://www.ncbi.nlm.nih.gov/pubmed/23909608$$D View this record in MEDLINE/PubMed
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Keywords lanthanide
squeegee method
upconversion
nanohole array
plasmonically enhanced luminescence
nanophosphor
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Snippet Arrays of subwavelength holes (nanoholes) in Au films were computationally designed, fabricated, and used as templates to localize and enhance the luminescence...
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SubjectTerms Absorption
Arrays
Biosensing Techniques
Colloids - chemistry
Computation
Computer Simulation
Excitation
Finite Element Analysis
Luminescence
Luminescent Measurements
Microscopy, Electron, Scanning
Microscopy, Electron, Transmission
Nanoparticles - chemistry
Nanostructure
Nanotechnology - methods
Optics and Photonics
Plasmonics
Silver - chemistry
Surface Properties
Upconversion
Wavelengths
Title Plasmonic Enhancement of Nanophosphor Upconversion Luminescence in Au Nanohole Arrays
URI http://dx.doi.org/10.1021/nn402598e
https://www.ncbi.nlm.nih.gov/pubmed/23909608
https://search.proquest.com/docview/1428519541
https://search.proquest.com/docview/1762059389
Volume 7
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