High-Performance Germanium Nanowire-Based Lithium-Ion Battery Anodes Extending over 1000 Cycles Through in Situ Formation of a Continuous Porous Network
Here we report the formation of high-performance and high-capacity lithium-ion battery anodes from high-density germanium nanowire arrays grown directly from the current collector. The anodes retain capacities of ∼900 mAh/g after 1100 cycles with excellent rate performance characteristics, even at v...
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Published in | Nano letters Vol. 14; no. 2; pp. 716 - 723 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
12.02.2014
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Subjects | |
Online Access | Get full text |
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Abstract | Here we report the formation of high-performance and high-capacity lithium-ion battery anodes from high-density germanium nanowire arrays grown directly from the current collector. The anodes retain capacities of ∼900 mAh/g after 1100 cycles with excellent rate performance characteristics, even at very high discharge rates of 20–100C. We show by an ex situ high-resolution transmission electron microscopy and high-resolution scanning electron microscopy study that this performance can be attributed to the complete restructuring of the nanowires that occurs within the first 100 cycles to form a continuous porous network that is mechanically robust. Once formed, this restructured anode retains a remarkably stable capacity with a drop of only 0.01% per cycle thereafter. As this approach encompasses a low energy processing method where all the material is electrochemically active and binder free, the extended cycle life and rate performance characteristics demonstrated makes these anodes highly attractive for the most demanding lithium-ion applications such as long-range battery electric vehicles. |
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AbstractList | Here we report the formation of high-performance and high-capacity lithium-ion battery anodes from high-density germanium nanowire arrays grown directly from the current collector. The anodes retain capacities of 900 mAh/g after 1100 cycles with excellent rate performance characteristics, even at very high discharge rates of 20-100C. We show by an ex situ high-resolution transmission electron microscopy and high-resolution scanning electron microscopy study that this performance can be attributed to the complete restructuring of the nanowires that occurs within the first 100 cycles to form a continuous porous network that is mechanically robust. Once formed, this restructured anode retains a remarkably stable capacity with a drop of only 0.01% per cycle thereafter. As this approach encompasses a low energy processing method where all the material is electrochemically active and binder free, the extended cycle life and rate performance characteristics demonstrated makes these anodes highly attractive for the most demanding lithium-ion applications such as long-range battery electric vehicles. Here we report the formation of high-performance and high-capacity lithium-ion battery anodes from high-density germanium nanowire arrays grown directly from the current collector. The anodes retain capacities of ∼ 900 mAh/g after 1100 cycles with excellent rate performance characteristics, even at very high discharge rates of 20-100C. We show by an ex situ high-resolution transmission electron microscopy and high-resolution scanning electron microscopy study that this performance can be attributed to the complete restructuring of the nanowires that occurs within the first 100 cycles to form a continuous porous network that is mechanically robust. Once formed, this restructured anode retains a remarkably stable capacity with a drop of only 0.01% per cycle thereafter. As this approach encompasses a low energy processing method where all the material is electrochemically active and binder free, the extended cycle life and rate performance characteristics demonstrated makes these anodes highly attractive for the most demanding lithium-ion applications such as long-range battery electric vehicles. Here we report the formation of high-performance and high-capacity lithium-ion battery anodes from high-density germanium nanowire arrays grown directly from the current collector. The anodes retain capacities of ∼900 mAh/g after 1100 cycles with excellent rate performance characteristics, even at very high discharge rates of 20–100C. We show by an ex situ high-resolution transmission electron microscopy and high-resolution scanning electron microscopy study that this performance can be attributed to the complete restructuring of the nanowires that occurs within the first 100 cycles to form a continuous porous network that is mechanically robust. Once formed, this restructured anode retains a remarkably stable capacity with a drop of only 0.01% per cycle thereafter. As this approach encompasses a low energy processing method where all the material is electrochemically active and binder free, the extended cycle life and rate performance characteristics demonstrated makes these anodes highly attractive for the most demanding lithium-ion applications such as long-range battery electric vehicles. |
Author | Kennedy, Tadhg Osiak, Michal Ryan, Kevin M Mullane, Emma O’Dwyer, Colm Geaney, Hugh |
AuthorAffiliation | University of Limerick Department of Chemistry Lee Maltings Materials and Surface Science Institute and the Department of Chemical and Environmental Sciences University College Cork Tyndall National Institute |
AuthorAffiliation_xml | – name: University College Cork – name: Department of Chemistry – name: Lee Maltings – name: Tyndall National Institute – name: Materials and Surface Science Institute and the Department of Chemical and Environmental Sciences – name: University of Limerick |
Author_xml | – sequence: 1 givenname: Tadhg surname: Kennedy fullname: Kennedy, Tadhg – sequence: 2 givenname: Emma surname: Mullane fullname: Mullane, Emma – sequence: 3 givenname: Hugh surname: Geaney fullname: Geaney, Hugh – sequence: 4 givenname: Michal surname: Osiak fullname: Osiak, Michal – sequence: 5 givenname: Colm surname: O’Dwyer fullname: O’Dwyer, Colm – sequence: 6 givenname: Kevin M surname: Ryan fullname: Ryan, Kevin M email: Kevin.M.Ryan@ul.ie |
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Keywords | porous tin seed rate capability lithium-ion battery Germanium nanowires network Lithium battery Scanning electron microscopy Transmission electron microscopy High density Porous materials Germanium Nanowires Arrays Nanostructured materials Nanomaterial synthesis |
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Snippet | Here we report the formation of high-performance and high-capacity lithium-ion battery anodes from high-density germanium nanowire arrays grown directly from... |
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SubjectTerms | Anodes Applied sciences Arrays Cross-disciplinary physics: materials science; rheology Direct energy conversion and energy accumulation Electric vehicles Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology Formations Lithium-ion batteries Materials science Methods of nanofabrication Nanocrystalline materials Nanoscale materials and structures: fabrication and characterization Nanowires Networks Physics Quantum wires Scanning electron microscopy |
Title | High-Performance Germanium Nanowire-Based Lithium-Ion Battery Anodes Extending over 1000 Cycles Through in Situ Formation of a Continuous Porous Network |
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