Probing Interfacial Water on Nanodiamonds in Colloidal Dispersion
The structure of interfacial water layers around nanoparticles dispersed in an aqueous environment may have a significant impact on their reactivity and on their interaction with biological species. Using transmission soft X-ray absorption spectroscopy in liquid, we demonstrate that the unoccupied e...
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Published in | The journal of physical chemistry letters Vol. 6; no. 15; pp. 2909 - 2912 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
06.08.2015
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Abstract | The structure of interfacial water layers around nanoparticles dispersed in an aqueous environment may have a significant impact on their reactivity and on their interaction with biological species. Using transmission soft X-ray absorption spectroscopy in liquid, we demonstrate that the unoccupied electronic states of oxygen atoms from water molecules in aqueous colloidal dispersions of nanodiamonds have a different signature than bulk water. X-ray absorption spectroscopy can thus probe interfacial water molecules in colloidal dispersions. The impacts of nanodiamond surface chemistry and concentration on interfacial water electronic signature are discussed. |
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AbstractList | The structure of interfacial water layers around nanoparticles dispersed in an aqueous environment may have a significant impact on their reactivity and on their interaction with biological species. Using transmission soft X-ray absorption spectroscopy in liquid, we demonstrate that the unoccupied electronic states of oxygen atoms from water molecules in aqueous colloidal dispersions of nanodiamonds have a different signature than bulk water. X-ray absorption spectroscopy can thus probe interfacial water molecules in colloidal dispersions. The impacts of nanodiamond surface chemistry and concentration on interfacial water electronic signature are discussed. |
Author | Aziz, Emad F Petit, Tristan Yamanoi, Ryoko Yuzawa, Hayato Kosugi, Nobuhiro Osawa, Eiji Nagasaka, Masanari |
AuthorAffiliation | Shinshu University Institute for Molecular Science Nanocarbon Research Institute Freie Universität Berlin Helmholtz-Zentrum Berlin Institute of Methods for Materials Development |
AuthorAffiliation_xml | – name: Freie Universität Berlin – name: Institute of Methods for Materials Development – name: Helmholtz-Zentrum Berlin – name: Nanocarbon Research Institute – name: Institute for Molecular Science – name: Shinshu University |
Author_xml | – sequence: 1 givenname: Tristan surname: Petit fullname: Petit, Tristan email: tristan.petit@helmholtz-berlin.de – sequence: 2 givenname: Hayato surname: Yuzawa fullname: Yuzawa, Hayato – sequence: 3 givenname: Masanari surname: Nagasaka fullname: Nagasaka, Masanari – sequence: 4 givenname: Ryoko surname: Yamanoi fullname: Yamanoi, Ryoko – sequence: 5 givenname: Eiji surname: Osawa fullname: Osawa, Eiji – sequence: 6 givenname: Nobuhiro surname: Kosugi fullname: Kosugi, Nobuhiro – sequence: 7 givenname: Emad F surname: Aziz fullname: Aziz, Emad F |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26267179$$D View this record in MEDLINE/PubMed |
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SubjectTerms | Colloids - chemistry Nanodiamonds - chemistry Surface Properties Water - chemistry X-Ray Absorption Spectroscopy |
Title | Probing Interfacial Water on Nanodiamonds in Colloidal Dispersion |
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