Dynamic Figure Eight Loop Structure of meso-Tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0)
3,3′-Diethyl substituents of the 2,2′-bipyrrole components in meso-tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) affect the cavity shape through CH/π interactions and remarkably accelerate syn−anti conformational change of the 2,2′-bipyrrole components leading to helicity change in the figure eight loop...
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| Published in | Journal of organic chemistry Vol. 74; no. 9; pp. 3579 - 3582 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
WASHINGTON
American Chemical Society
01.05.2009
Amer Chemical Soc |
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| Abstract | 3,3′-Diethyl substituents of the 2,2′-bipyrrole components in meso-tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) affect the cavity shape through CH/π interactions and remarkably accelerate syn−anti conformational change of the 2,2′-bipyrrole components leading to helicity change in the figure eight loop of [32]octaphyrins. |
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| AbstractList | 3,3'-Diethyl substituents of the 2,2'-bipyrrole components in meso-tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) affect the cavity shape through CH/pi interactions and remarkably accelerate syn-anti conformational change of the 2,2'-bipyrrole components leading to helicity change in the figure eight loop of [32]octaphyrins. 3,3′-Diethyl substituents of the 2,2′-bipyrrole components in meso-tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) affect the cavity shape through CH/π interactions and remarkably accelerate syn−anti conformational change of the 2,2′-bipyrrole components leading to helicity change in the figure eight loop of [32]octaphyrins. |
| Author | Iizuna, Noriko Mori, Megumi Setsune, Jun-ichiro Okawa, Toshifumi Lintuluoto, Juha M Nakayama, Kana |
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| Keywords | ABSOLUTE-CONFIGURATION CYCLOOCTAPYRROLES MACROCYCLES SUBSTITUTED EXPANDED PORPHYRINS INTERNAL-ROTATION CHEMISTRY METAL-COMPLEX CYCLOPOLYPYRROLES Molecular interaction Molecular structure Nitrogen heterocycle Conformational changes Porphyrin derivatives Helicity |
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| Snippet | 3,3′-Diethyl substituents of the 2,2′-bipyrrole components in meso-tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) affect the cavity shape through CH/π interactions... 3,3'-Diethyl substituents of the 2,2'-bipyrrole components in meso-tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) affect the cavity shape through CH/pi interactions... |
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| SubjectTerms | Chemistry Chemistry, Organic Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Organic chemistry Physical Sciences Preparations and properties Science & Technology |
| Title | Dynamic Figure Eight Loop Structure of meso-Tetraaryl[32]octaphyrins(1.0.1.0.1.0.1.0) |
| URI | http://dx.doi.org/10.1021/jo9001189 http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000265554900054 https://www.ncbi.nlm.nih.gov/pubmed/19326903 https://search.proquest.com/docview/67165476 |
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