High-Entropy Oxide Derived from Metal–Organic Framework as a Bifunctional Electrocatalyst for Efficient Urea Oxidation and Oxygen Evolution Reactions

High-entropy oxides (HEOs) offer unique features through a combination of incompatible metal cations to a single crystalline lattice. Owing to their special characteristics such as abundant cation compositions, high entropy stabilization, chemical and thermal stability, and lattice distortion effect...

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Published inACS applied materials & interfaces Vol. 14; no. 34; pp. 38727 - 38738
Main Authors Fereja, Shemsu Ligani, Zhang, Ziwei, Fang, Zhongying, Guo, Jinhan, Zhang, Xiaohui, Liu, Kaifan, Li, Zongjun, Chen, Wei
Format Journal Article
LanguageEnglish
Published American Chemical Society 31.08.2022
Subjects
catalytic activity
cations
coordination polymers
Energy, Environmental, and Catalysis Applications
entropy
infancy
oxidation
oxygen
oxygen production
surface area
thermal stability
urea
oxygen evolution reaction
high-entropy oxide
electrocatalysis
oxygen vacancy
urea oxidation reaction
metal−organic framework
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Abstract High-entropy oxides (HEOs) offer unique features through a combination of incompatible metal cations to a single crystalline lattice. Owing to their special characteristics such as abundant cation compositions, high entropy stabilization, chemical and thermal stability, and lattice distortion effect, they have drawn ever-increasing attention for various applications. However, very few studies have been reported for catalytic application, and developing HEOs with large surface areas for efficient catalytic application is still in infancy. Herein, we design nanostructured HEO of (FeNiCoCrCu)3O4 using metal–organic frameworks (MOFs) as sacrificial templates to achieve a large surface area, high density of exposed active sites, and more oxygen vacancies. Single-crystalline phase HEOs with surface area as large as 206 m2 g–1 are produced and further applied as bifunctional electrocatalysts for the urea oxidation reaction (UOR) and oxygen evolution reaction (OER). Benefiting from enhanced oxygen vacancies and a large surface area with abundant exposed active sites, the optimized HEO exhibited excellent electrocatalytic activity toward UOR with a very low potential of 1.35 V at the current density of 10 mA cm–2 and showed long-term stability for 36 h operation, making a significant catalytic performance over previously reported HEOs. Moreover, the HEO demonstrated an efficient catalytic performance toward OER with a low overpotential of 270 mV at 10 mA cm–2 and low Tafel slope of 49 mV dec–1. The excellent catalytic activity is ascribed to the starting MOF precursor and favorable high-entropy effect.
AbstractList High-entropy oxides (HEOs) offer unique features through a combination of incompatible metal cations to a single crystalline lattice. Owing to their special characteristics such as abundant cation compositions, high entropy stabilization, chemical and thermal stability, and lattice distortion effect, they have drawn ever-increasing attention for various applications. However, very few studies have been reported for catalytic application, and developing HEOs with large surface areas for efficient catalytic application is still in infancy. Herein, we design nanostructured HEO of (FeNiCoCrCu)₃O₄ using metal–organic frameworks (MOFs) as sacrificial templates to achieve a large surface area, high density of exposed active sites, and more oxygen vacancies. Single-crystalline phase HEOs with surface area as large as 206 m² g–¹ are produced and further applied as bifunctional electrocatalysts for the urea oxidation reaction (UOR) and oxygen evolution reaction (OER). Benefiting from enhanced oxygen vacancies and a large surface area with abundant exposed active sites, the optimized HEO exhibited excellent electrocatalytic activity toward UOR with a very low potential of 1.35 V at the current density of 10 mA cm–² and showed long-term stability for 36 h operation, making a significant catalytic performance over previously reported HEOs. Moreover, the HEO demonstrated an efficient catalytic performance toward OER with a low overpotential of 270 mV at 10 mA cm–² and low Tafel slope of 49 mV dec–¹. The excellent catalytic activity is ascribed to the starting MOF precursor and favorable high-entropy effect.
High-entropy oxides (HEOs) offer unique features through a combination of incompatible metal cations to a single crystalline lattice. Owing to their special characteristics such as abundant cation compositions, high entropy stabilization, chemical and thermal stability, and lattice distortion effect, they have drawn ever-increasing attention for various applications. However, very few studies have been reported for catalytic application, and developing HEOs with large surface areas for efficient catalytic application is still in infancy. Herein, we design nanostructured HEO of (FeNiCoCrCu)3O4 using metal–organic frameworks (MOFs) as sacrificial templates to achieve a large surface area, high density of exposed active sites, and more oxygen vacancies. Single-crystalline phase HEOs with surface area as large as 206 m2 g–1 are produced and further applied as bifunctional electrocatalysts for the urea oxidation reaction (UOR) and oxygen evolution reaction (OER). Benefiting from enhanced oxygen vacancies and a large surface area with abundant exposed active sites, the optimized HEO exhibited excellent electrocatalytic activity toward UOR with a very low potential of 1.35 V at the current density of 10 mA cm–2 and showed long-term stability for 36 h operation, making a significant catalytic performance over previously reported HEOs. Moreover, the HEO demonstrated an efficient catalytic performance toward OER with a low overpotential of 270 mV at 10 mA cm–2 and low Tafel slope of 49 mV dec–1. The excellent catalytic activity is ascribed to the starting MOF precursor and favorable high-entropy effect.
High-entropy oxides (HEOs) offer unique features through a combination of incompatible metal cations to a single crystalline lattice. Owing to their special characteristics such as abundant cation compositions, high entropy stabilization, chemical and thermal stability, and lattice distortion effect, they have drawn ever-increasing attention for various applications. However, very few studies have been reported for catalytic application, and developing HEOs with large surface areas for efficient catalytic application is still in infancy. Herein, we design nanostructured HEO of (FeNiCoCrCu)3O4 using metal-organic frameworks (MOFs) as sacrificial templates to achieve a large surface area, high density of exposed active sites, and more oxygen vacancies. Single-crystalline phase HEOs with surface area as large as 206 m2 g-1 are produced and further applied as bifunctional electrocatalysts for the urea oxidation reaction (UOR) and oxygen evolution reaction (OER). Benefiting from enhanced oxygen vacancies and a large surface area with abundant exposed active sites, the optimized HEO exhibited excellent electrocatalytic activity toward UOR with a very low potential of 1.35 V at the current density of 10 mA cm-2 and showed long-term stability for 36 h operation, making a significant catalytic performance over previously reported HEOs. Moreover, the HEO demonstrated an efficient catalytic performance toward OER with a low overpotential of 270 mV at 10 mA cm-2 and low Tafel slope of 49 mV dec-1. The excellent catalytic activity is ascribed to the starting MOF precursor and favorable high-entropy effect.High-entropy oxides (HEOs) offer unique features through a combination of incompatible metal cations to a single crystalline lattice. Owing to their special characteristics such as abundant cation compositions, high entropy stabilization, chemical and thermal stability, and lattice distortion effect, they have drawn ever-increasing attention for various applications. However, very few studies have been reported for catalytic application, and developing HEOs with large surface areas for efficient catalytic application is still in infancy. Herein, we design nanostructured HEO of (FeNiCoCrCu)3O4 using metal-organic frameworks (MOFs) as sacrificial templates to achieve a large surface area, high density of exposed active sites, and more oxygen vacancies. Single-crystalline phase HEOs with surface area as large as 206 m2 g-1 are produced and further applied as bifunctional electrocatalysts for the urea oxidation reaction (UOR) and oxygen evolution reaction (OER). Benefiting from enhanced oxygen vacancies and a large surface area with abundant exposed active sites, the optimized HEO exhibited excellent electrocatalytic activity toward UOR with a very low potential of 1.35 V at the current density of 10 mA cm-2 and showed long-term stability for 36 h operation, making a significant catalytic performance over previously reported HEOs. Moreover, the HEO demonstrated an efficient catalytic performance toward OER with a low overpotential of 270 mV at 10 mA cm-2 and low Tafel slope of 49 mV dec-1. The excellent catalytic activity is ascribed to the starting MOF precursor and favorable high-entropy effect.
Author Chen, Wei
Li, Zongjun
Zhang, Xiaohui
Liu, Kaifan
Fereja, Shemsu Ligani
Zhang, Ziwei
Fang, Zhongying
Guo, Jinhan
AuthorAffiliation University of Science and Technology of China
Wolkite University College of Natural and Computational Science
Chinese Academy of Sciences
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry
AuthorAffiliation_xml – name: University of Science and Technology of China
– name: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry
– name: Chinese Academy of Sciences
– name: Wolkite University College of Natural and Computational Science
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  organization: Wolkite University College of Natural and Computational Science
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  fullname: Zhang, Ziwei
  organization: University of Science and Technology of China
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  organization: University of Science and Technology of China
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  givenname: Wei
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  fullname: Chen, Wei
  email: weichen@ciac.ac.cn
  organization: University of Science and Technology of China
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Cites_doi 10.1021/acsaem.8b01186
10.1016/j.matpr.2020.04.521
10.1016/j.molstruc.2017.08.041
10.1039/d1nr05747b
10.1016/j.cej.2021.129686
10.1039/c9cc02507c
10.1021/acssuschemeng.7b04808
10.1002/aenm.201700518
10.1021/acs.iecr.0c05565
10.1021/acsami.1c04325
10.1039/c9an02481f
10.1016/j.apcatb.2021.120196
10.1002/anie.201600687
10.1021/acs.inorgchem.7b02848
10.1002/anie.202004892
10.1038/ncomms8345
10.1038/s41467-021-21401-2
10.1038/s41467-018-05774-5
10.1038/s41467-018-07160-7
10.1039/c9ta09975a
10.1016/j.electacta.2021.139793
10.1016/j.jece.2021.106932
10.1016/j.jechem.2019.04.013
10.1016/j.est.2021.103004
10.1039/d0qi00929f
10.1039/d1nj04509a
10.1038/s41598-021-95844-4
10.1016/j.cej.2020.125507
10.1021/acsami.0c06716
10.1016/j.cej.2020.127831
10.1021/acsami.0c17446
10.1038/s41524-022-00780-0
10.1007/s10853-018-2168-9
10.1039/c9ta08740k
10.1016/j.matlet.2017.12.148
10.1007/s10853-021-05805-5
10.3390/nano11030657
10.1016/j.apcatb.2020.119436
10.1016/j.mattod.2018.10.038
10.1002/cssc.202001185
10.1016/j.jcis.2019.12.044
10.1021/acs.chemmater.9b00624
10.1021/jacs.9b12377
10.1002/adfm.202101632
10.1039/d1ta04755h
10.1016/j.elecom.2019.02.001
10.1002/smll.202104761
10.1002/anie.202107390
10.1039/d1dt01952j
10.1002/adma.201806236
10.1016/j.cej.2020.127630
10.1021/acs.langmuir.1c01105
10.1039/c9ra10300g
10.1021/acs.analchem.1c00568
10.1002/adma.201805004
10.1021/acsami.1c01188
10.1002/celc.202100443
10.1038/srep37946
10.1002/adma.202101342
10.1038/ncomms9485
10.1016/j.jeurceramsoc.2016.09.018
10.1002/aenm.202002887
10.1016/j.jallcom.2021.162640
10.1016/j.jcis.2022.03.063
10.1021/acssuschemeng.1c03353
10.1007/s10853-021-06391-2
10.1021/acsami.0c05916
10.1016/j.cej.2021.134274
10.1016/j.jcis.2021.07.124
10.1016/j.jallcom.2021.159064
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high-entropy oxide
electrocatalysis
oxygen vacancy
urea oxidation reaction
metal−organic framework
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References ref9/cit9
ref45/cit45
ref3/cit3
ref27/cit27
ref63/cit63
ref56/cit56
ref16/cit16
ref52/cit52
ref23/cit23
ref8/cit8
ref31/cit31
ref59/cit59
ref2/cit2
ref34/cit34
ref37/cit37
ref20/cit20
ref48/cit48
ref60/cit60
ref17/cit17
ref10/cit10
ref35/cit35
ref53/cit53
ref19/cit19
ref21/cit21
ref42/cit42
ref46/cit46
ref49/cit49
ref13/cit13
ref61/cit61
ref67/cit67
ref24/cit24
ref38/cit38
ref50/cit50
ref64/cit64
ref54/cit54
ref6/cit6
ref36/cit36
ref18/cit18
ref65/cit65
ref11/cit11
ref25/cit25
ref29/cit29
ref32/cit32
ref39/cit39
ref14/cit14
ref57/cit57
ref5/cit5
ref51/cit51
ref43/cit43
ref28/cit28
ref40/cit40
ref68/cit68
ref26/cit26
ref55/cit55
ref69/cit69
ref12/cit12
ref15/cit15
ref62/cit62
ref66/cit66
ref41/cit41
ref58/cit58
ref22/cit22
ref33/cit33
ref4/cit4
ref30/cit30
ref47/cit47
ref1/cit1
ref44/cit44
ref70/cit70
ref7/cit7
References_xml – ident: ref49/cit49
  doi: 10.1021/acsaem.8b01186
– ident: ref42/cit42
  doi: 10.1016/j.matpr.2020.04.521
– ident: ref44/cit44
  doi: 10.1016/j.molstruc.2017.08.041
– ident: ref33/cit33
  doi: 10.1039/d1nr05747b
– ident: ref54/cit54
  doi: 10.1016/j.cej.2021.129686
– ident: ref66/cit66
  doi: 10.1039/c9cc02507c
– ident: ref57/cit57
  doi: 10.1021/acssuschemeng.7b04808
– ident: ref35/cit35
  doi: 10.1002/aenm.201700518
– ident: ref64/cit64
  doi: 10.1021/acs.iecr.0c05565
– ident: ref69/cit69
  doi: 10.1021/acsami.1c04325
– ident: ref40/cit40
  doi: 10.1039/c9an02481f
– ident: ref55/cit55
  doi: 10.1016/j.apcatb.2021.120196
– ident: ref56/cit56
  doi: 10.1002/anie.201600687
– ident: ref50/cit50
  doi: 10.1021/acs.inorgchem.7b02848
– ident: ref18/cit18
  doi: 10.1002/anie.202004892
– ident: ref51/cit51
  doi: 10.1038/ncomms8345
– ident: ref37/cit37
  doi: 10.1038/s41467-021-21401-2
– ident: ref8/cit8
  doi: 10.1038/s41467-018-05774-5
– ident: ref12/cit12
  doi: 10.1038/s41467-018-07160-7
– ident: ref39/cit39
  doi: 10.1039/c9ta09975a
– ident: ref1/cit1
  doi: 10.1016/j.electacta.2021.139793
– ident: ref21/cit21
  doi: 10.1016/j.jece.2021.106932
– ident: ref36/cit36
  doi: 10.1016/j.jechem.2019.04.013
– ident: ref26/cit26
  doi: 10.1016/j.est.2021.103004
– ident: ref38/cit38
  doi: 10.1039/d0qi00929f
– ident: ref14/cit14
  doi: 10.1039/d1nj04509a
– ident: ref41/cit41
  doi: 10.1038/s41598-021-95844-4
– ident: ref2/cit2
  doi: 10.1016/j.cej.2020.125507
– ident: ref3/cit3
  doi: 10.1021/acsami.0c06716
– ident: ref34/cit34
  doi: 10.1016/j.cej.2020.127831
– ident: ref47/cit47
  doi: 10.1021/acsami.0c17446
– ident: ref60/cit60
  doi: 10.1038/s41524-022-00780-0
– ident: ref24/cit24
  doi: 10.1007/s10853-018-2168-9
– ident: ref32/cit32
  doi: 10.1039/c9ta08740k
– ident: ref27/cit27
  doi: 10.1016/j.matlet.2017.12.148
– ident: ref29/cit29
  doi: 10.1007/s10853-021-05805-5
– ident: ref53/cit53
  doi: 10.3390/nano11030657
– ident: ref68/cit68
  doi: 10.1016/j.apcatb.2020.119436
– ident: ref46/cit46
  doi: 10.1016/j.mattod.2018.10.038
– ident: ref62/cit62
  doi: 10.1002/cssc.202001185
– ident: ref48/cit48
  doi: 10.1016/j.jcis.2019.12.044
– ident: ref16/cit16
  doi: 10.1021/acs.chemmater.9b00624
– ident: ref9/cit9
  doi: 10.1021/jacs.9b12377
– ident: ref23/cit23
  doi: 10.1002/adfm.202101632
– ident: ref15/cit15
  doi: 10.1039/d1ta04755h
– ident: ref20/cit20
  doi: 10.1016/j.elecom.2019.02.001
– ident: ref28/cit28
  doi: 10.1002/smll.202104761
– ident: ref30/cit30
  doi: 10.1002/anie.202107390
– ident: ref4/cit4
  doi: 10.1039/d1dt01952j
– ident: ref17/cit17
  doi: 10.1002/adma.201806236
– ident: ref7/cit7
  doi: 10.1016/j.cej.2020.127630
– ident: ref25/cit25
  doi: 10.1021/acs.langmuir.1c01105
– ident: ref43/cit43
  doi: 10.1039/c9ra10300g
– ident: ref59/cit59
  doi: 10.1021/acs.analchem.1c00568
– ident: ref19/cit19
  doi: 10.1002/adma.201805004
– ident: ref63/cit63
  doi: 10.1021/acsami.1c01188
– ident: ref67/cit67
  doi: 10.1002/celc.202100443
– ident: ref13/cit13
  doi: 10.1038/srep37946
– ident: ref31/cit31
  doi: 10.1002/adma.202101342
– ident: ref11/cit11
  doi: 10.1038/ncomms9485
– ident: ref52/cit52
  doi: 10.1016/j.jeurceramsoc.2016.09.018
– ident: ref10/cit10
  doi: 10.1002/aenm.202002887
– ident: ref45/cit45
  doi: 10.1016/j.jallcom.2021.162640
– ident: ref6/cit6
  doi: 10.1016/j.jcis.2022.03.063
– ident: ref58/cit58
  doi: 10.1021/acssuschemeng.1c03353
– ident: ref65/cit65
  doi: 10.1007/s10853-021-06391-2
– ident: ref61/cit61
  doi: 10.1021/acsami.0c05916
– ident: ref5/cit5
  doi: 10.1016/j.cej.2021.134274
– ident: ref70/cit70
  doi: 10.1016/j.jcis.2021.07.124
– ident: ref22/cit22
  doi: 10.1016/j.jallcom.2021.159064
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Snippet High-entropy oxides (HEOs) offer unique features through a combination of incompatible metal cations to a single crystalline lattice. Owing to their special...
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SubjectTerms catalytic activity
cations
coordination polymers
Energy, Environmental, and Catalysis Applications
entropy
infancy
oxidation
oxygen
oxygen production
surface area
thermal stability
urea
Title High-Entropy Oxide Derived from Metal–Organic Framework as a Bifunctional Electrocatalyst for Efficient Urea Oxidation and Oxygen Evolution Reactions
URI http://dx.doi.org/10.1021/acsami.2c09161
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