Structures and Reactivities of Palladium−Ruthenium Mixed-Metal Sulfido Clusters Derived from Disulfido- or Hydrosulfido-Bridged Diruthenium Complexes

• Published in: Organometallics Vol. 21; no. 24; pp. 5401 - 5407
• Main Authors: Kuwata, Shigeki, Hashizume, Kohjiro, Mizobe, Yasushi, Hidai, Masanobu
• Format: Journal Article
• Language: English
• Published: American Chemical Society 25.11.2002

The reaction of the disulfido-bridged diruthenium complex [Cp*Ru(μ2-S2)(μ2-SPri)2RuCp*] (1; Cp* = η5-C5Me5) with 2 equiv of [Pd(PPh3)4] in boiling toluene resulted in the formation of the palladium−ruthenium mixed-metal sulfido cluster [(Cp*Ru)2(μ3-S)2Pd2(μ2-SPri)(SPri)(PPh3)] (2). Upon treatment wi...