Relationship of polycyclic aromatic sulfur compounds and gold enrichment in the Kupferschiefer from Poland and Germany
The contents of polycyclic aromatic sulfur compounds （PASCs） in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the Kupferschiefer from Poland and Germany, Gold enrichment was only observed in samples with higher PASC contents. At the same time, all the samples with...
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| Published in | Acta geochimica Vol. 25; no. 1; pp. 16 - 22 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
Dordrecht
Springer Nature B.V
2006
Hebei University of Engineering, Handan 056038, China Key Laboratory of Resource Exploration Research of Hebei Province, Handan 056038, China%Hebei University of Engineering, Handan 056038, China%Key Laboratory for Petroleum Geochemistry, CNPC, Beijing 100083, China |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1000-9426 2096-0956 1993-0364 2365-7499 |
| DOI | 10.1007/BF02894792 |
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| Abstract | The contents of polycyclic aromatic sulfur compounds （PASCs） in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the Kupferschiefer from Poland and Germany, Gold enrichment was only observed in samples with higher PASC contents. At the same time, all the samples with gold enrichment originated from areas close to tile redox boundary （ the front section of Rote Faule） that was formed by oxidizing brines in contact with the reducing Kupferschiefer. It is proposed that the gold-bearing solutions encountered PASCs in the Kupferschiefer. PASCs could easily displace chloride ions from aurous chloride complexes to form stable gold S-chelates. Subsequent oxidation of these gold organic compounds could destroy the organic components atld lead to the formation of metallic gold, |
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| AbstractList | The contents of polycyclic aromatic sulfur compounds (PASCs) in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the Kupferschiefer from Poland and Germany. Gold enrichment was only observed in samples with higher PASC contents. At the same time, all the samples with gold enrichment originated from areas close to the redox boundary (the front section ofRote Fäule) that was formed by oxidizing brines in contact with the reducing Kupferschiefer. It is proposed that the gold-bearing solutions encountered PASCs in the Kupferschiefer. PASCs could easily displace chloride ions from aurous chloride complexes to form stable gold S-chelates. Subsequent oxidation of these gold organic compounds could destroy the organic components and lead to the formation of metallic gold.[PUBLICATION ABSTRACT] P59; The contents of polycyclic aromatic sulfur compounds (PASCs) in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the Kupferschiefer from Poland and Germany. Gold enrichment was only observed in samples with higher PASC contents. At the same time, all the samples with gold enrichment originated from areas close to the redox boundary (the front section of Rote Faule) that was formed by oxidizing brines in contact with the reducing Kupferschiefer. It is proposed that the gold-bearing solutions encountered PASCs in the Kupferschiefer. PASCs could easily displace chloride ions from aurous chloride complexes to form stable gold S-chelates. Subsequent oxidation of these gold organic compounds could destroy the organic components and lead to the formation of metallic gold. The contents of polycyclic aromatic sulfur compounds (PASCs) in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the Kupferschiefer from Poland and Germany. Gold enrichment was only observed in samples with higher PASC contents. At the same time, all the samples with gold enrichment originated from areas close to the redox boundary (the front section ofRote Faeule) that was formed by oxidizing brines in contact with the reducing Kupferschiefer. It is proposed that the gold-bearing solutions encountered PASCs in the Kupferschiefer. PASCs could easily displace chloride ions from aurous chloride complexes to form stable gold S-chelates. Subsequent oxidation of these gold organic compounds could destroy the organic components and lead to the formation of metallic gold. The contents of polycyclic aromatic sulfur compounds （PASCs） in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the Kupferschiefer from Poland and Germany, Gold enrichment was only observed in samples with higher PASC contents. At the same time, all the samples with gold enrichment originated from areas close to tile redox boundary （ the front section of Rote Faule） that was formed by oxidizing brines in contact with the reducing Kupferschiefer. It is proposed that the gold-bearing solutions encountered PASCs in the Kupferschiefer. PASCs could easily displace chloride ions from aurous chloride complexes to form stable gold S-chelates. Subsequent oxidation of these gold organic compounds could destroy the organic components atld lead to the formation of metallic gold, The contents of polycyclic aromatic sulfur compounds (PASCs) in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the Kupferschiefer from Poland and Germany. Gold enrichment was only observed in samples with higher PASC contents. At the same time, all the samples with gold enrichment originated from areas close to the redox boundary (the front section ofRote Fäule) that was formed by oxidizing brines in contact with the reducing Kupferschiefer. It is proposed that the gold-bearing solutions encountered PASCs in the Kupferschiefer. PASCs could easily displace chloride ions from aurous chloride complexes to form stable gold S-chelates. Subsequent oxidation of these gold organic compounds could destroy the organic components and lead to the formation of metallic gold. |
| Author | 孙玉壮 王萍 陈建平 |
| AuthorAffiliation | Hebei University of Engineering, Handan 056038, China Key Laboratory of Resource Exploration, Research of Hebei Province, Handan 056038, China Key Laboratory for Petroleum Geochemistry, CNPC, Beijing 100083, China |
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| CitedBy_id | crossref_primary_10_1016_j_marpetgeo_2014_07_009 crossref_primary_10_1260_0144_5987_29_5_617 crossref_primary_10_1260_0144_5987_29_6_711 crossref_primary_10_1260_0144_5987_32_2_301 crossref_primary_10_1260_0144_5987_28_6_451 crossref_primary_10_1007_s11631_007_0235_z crossref_primary_10_1260_0144_5987_30_6_957 crossref_primary_10_1260_0144_5987_27_2_133 crossref_primary_10_1108_WJE_07_2017_0179 |
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| Snippet | The contents of polycyclic aromatic sulfur compounds （PASCs） in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the... The contents of polycyclic aromatic sulfur compounds (PASCs) in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the... P59; The contents of polycyclic aromatic sulfur compounds (PASCs) in the Kupferschiefer varied from sample to sample. Twenty PASCs were determined in the... |
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| SubjectTerms | Aromatic compounds Boundaries Brines Chelates Chloride ions Chlorides Contact Enrichment Geochemistry Gold Organic compounds Oxidation Polycyclic aromatic hydrocarbons Sulfur Sulfur compounds Sulphur Sulphur compounds 富集规律 芳香族化合物 |
| Title | Relationship of polycyclic aromatic sulfur compounds and gold enrichment in the Kupferschiefer from Poland and Germany |
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