Modelling of bentonite–granite solutes transfer from an in situ full-scale experiment to simulate a deep geological repository (Grimsel Test Site, Switzerland)

• Published in: Applied geochemistry Vol. 25; no. 12; pp. 1797 - 1804
• Main Authors: Buil, B., Gómez, P., Peña, J., Garralón, A., Turrero, M.J., Escribano, A., Sánchez, L., Durán, J.M.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.12.2010; Elsevier
• Subjects: Earth sciences; Earth, ocean, space; Engineering and environment geology. Geothermics; Exact sciences and technology; Geochemistry; Pollution, environment geology; Central Europe; Switzerland; Europe; experimental studies; diffusion; underground laboratories; simulation; ground water; bentonite; boreholes; aquifers; granites; ions; clastic rocks; models; interfaces; solutes; tracers; sampling; crystalline rocks; concentration; igneous rocks; transport; high-level waste; in situ; sedimentary rocks; plutonic rocks; migration
• ISSN: 0883-2927; 1872-9134
• DOI: 10.1016/j.apgeochem.2010.09.003

► The FEBEX experiment is a 1:1 simulation of a high level waste disposal facility in crystalline rock according to the Spanish radwaste disposal concept. ► Solute transfer processes occurrs at the bentonite–granite interface. ► An increase of Cl and Na is observed in granitic water of the surrounding of the experiment. ► Solute transfer does not affect the sealing and thermo-hydromechanical properties of the engineered barriers. ► A diffusive transport of Cl and Na simulated by 1D transport modeling with an effective diffusion coefficient of D e ≅ 5.0 E-11 m 2/s. The FEBEX experiment is a 1:1 simulation of a high level waste disposal facility in crystalline rock according to the Spanish radwaste disposal concept. This experiment has been performed in a gallery drilled in the underground laboratory Grimsel Test Site (Switzerland). Two boreholes parallel to the FEBEX drift were drilled 20 and 60 cm away from the granite–bentonite interface to provide data on potential bentonite–granite solutes transfer. Periodic sampling and analysis of the major ions showed: (a) the existence of solutes transfer from the bentonite porewater towards the granite groundwater, explaining the Cl − and Na + contents of the latter; (b) that the concentration of the natural tracers coming into the granite groundwater from the bentonite porewater increased over time. This bentonite–granite solutes transfer was modelled in order to predict the increase in the Cl − and Na + concentrations of the granite groundwater. The modelled results seem to confirm that the mechanism of solute migration in this scenario is that of diffusive transport. An effective diffusion coefficient of D e = 5 × 10 −11 m 2/s was that which best fitted the data obtained.