Reticular Synthesis of tbo Topology Covalent Organic Frameworks

• Published in: Journal of the American Chemical Society Vol. 142; no. 38; pp. 16346 - 16356
• Main Authors: Kang, Xing, Han, Xing, Yuan, Chen, Cheng, Cheng, Liu, Yan, Cui, Yong
• Format: Journal Article
• Language: English
• Published: American Chemical Society 23.09.2020
• Subjects: alkenes; coordination polymers; crystallization; hydroxylation; photocatalysts; porphyrins; topology

The metal–organic framework (MOF) HKUST-1 with a tbo topology serves as an archetypal tunable and isoreticular framework platform for targeting desired applications, but the design and synthesis of tbo-covalent organic frameworks (COFs) remains a formidable challenge. Here we demonstrate the success...