Spinel-group minerals as a record of magmatic and metamorphic processes: evidence from the highly altered Morro do Onça ultramafic suite, São Francisco Craton (Brazil)

The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoprot...

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Published inContributions to mineralogy and petrology Vol. 177; no. 3
Main Authors Guice, George L., Magalhães, Joana Reis, Pinheiro, Marco Aurélio Piacentini, Ferreira, Raianny Carolini Ramos, Meira, Vinícius Tieppo, Melo-Silva, Paola, Ackerson, Michael R.
Format Journal Article
LanguageEnglish
Published Berlin/Heidelberg Springer Berlin Heidelberg 01.03.2022
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Abstract The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoproterozoic ophiolite/accretionary wedge or an Archean komatiite flow(s). In this paper, we utilize spinel-group mineral chemistry—alongside field mapping, petrography, silicate mineral chemistry and bulk-rock geochemistry—to decipher the magmatic and metamorphic evolution of the Morro do Onça suite. A komatiite origin is supported by the identification of spinifex-textured layers, as well as primary spinel-group mineral compositions (mean Cr-number = 79; mean TiO 2  = 0.3 wt%) and chondrite-normalized bulk-rock rare-earth element values ([Sm–Lu] N  = 1.2–5.1). Metamorphism reached mid/upper amphibolite-facies and was likely responsible for Al mobility on mineral and bulk-rock scales, demonstrating that the bulk-rock Al/Ti proxy commonly used to classify komatiites is susceptible to alteration. Thus, the Morro do Onça komatiites record variable bulk-rock Al/Ti values (17–47) that overlap with both Munro- (Al/Ti = 22) and Weltevreden-type (Al/Ti = 30) komatiites. Based on immobile trace-element ratios ([Gd/Lu] N  = 0.6–2.0) and primary spinel-group mineral compositions, we classify the Morro do Onça komatiites as Weltevreden-type. Mesoarchean komatiites related to mantle plume-magmatism are now recognized throughout the southern São Francisco Craton, potentially suggesting that its precursor lithosphere was continuous during this Era.
AbstractList The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoproterozoic ophiolite/accretionary wedge or an Archean komatiite flow(s). In this paper, we utilize spinel-group mineral chemistry—alongside field mapping, petrography, silicate mineral chemistry and bulk-rock geochemistry—to decipher the magmatic and metamorphic evolution of the Morro do Onça suite. A komatiite origin is supported by the identification of spinifex-textured layers, as well as primary spinel-group mineral compositions (mean Cr-number = 79; mean TiO 2  = 0.3 wt%) and chondrite-normalized bulk-rock rare-earth element values ([Sm–Lu] N  = 1.2–5.1). Metamorphism reached mid/upper amphibolite-facies and was likely responsible for Al mobility on mineral and bulk-rock scales, demonstrating that the bulk-rock Al/Ti proxy commonly used to classify komatiites is susceptible to alteration. Thus, the Morro do Onça komatiites record variable bulk-rock Al/Ti values (17–47) that overlap with both Munro- (Al/Ti = 22) and Weltevreden-type (Al/Ti = 30) komatiites. Based on immobile trace-element ratios ([Gd/Lu] N  = 0.6–2.0) and primary spinel-group mineral compositions, we classify the Morro do Onça komatiites as Weltevreden-type. Mesoarchean komatiites related to mantle plume-magmatism are now recognized throughout the southern São Francisco Craton, potentially suggesting that its precursor lithosphere was continuous during this Era.
The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoproterozoic ophiolite/accretionary wedge or an Archean komatiite flow(s). In this paper, we utilize spinel-group mineral chemistry-alongside field mapping, petrography, silicate mineral chemistry and bulk-rock geochemistry-to decipher the magmatic and metamorphic evolution of the Morro do Onça suite. A komatiite origin is supported by the identification of spinifex-textured layers, as well as primary spinel-group mineral compositions (mean Cr-number = 79; mean TiO.sub.2 = 0.3 wt%) and chondrite-normalized bulk-rock rare-earth element values ([Sm-Lu].sub.N = 1.2-5.1). Metamorphism reached mid/upper amphibolite-facies and was likely responsible for Al mobility on mineral and bulk-rock scales, demonstrating that the bulk-rock Al/Ti proxy commonly used to classify komatiites is susceptible to alteration. Thus, the Morro do Onça komatiites record variable bulk-rock Al/Ti values (17-47) that overlap with both Munro- (Al/Ti = 22) and Weltevreden-type (Al/Ti = 30) komatiites. Based on immobile trace-element ratios ([Gd/Lu].sub.N = 0.6-2.0) and primary spinel-group mineral compositions, we classify the Morro do Onça komatiites as Weltevreden-type. Mesoarchean komatiites related to mantle plume-magmatism are now recognized throughout the southern São Francisco Craton, potentially suggesting that its precursor lithosphere was continuous during this Era.
The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoproterozoic ophiolite/accretionary wedge or an Archean komatiite flow(s). In this paper, we utilize spinel-group mineral chemistry—alongside field mapping, petrography, silicate mineral chemistry and bulk-rock geochemistry—to decipher the magmatic and metamorphic evolution of the Morro do Onça suite. A komatiite origin is supported by the identification of spinifex-textured layers, as well as primary spinel-group mineral compositions (mean Cr-number = 79; mean TiO2 = 0.3 wt%) and chondrite-normalized bulk-rock rare-earth element values ([Sm–Lu]N = 1.2–5.1). Metamorphism reached mid/upper amphibolite-facies and was likely responsible for Al mobility on mineral and bulk-rock scales, demonstrating that the bulk-rock Al/Ti proxy commonly used to classify komatiites is susceptible to alteration. Thus, the Morro do Onça komatiites record variable bulk-rock Al/Ti values (17–47) that overlap with both Munro- (Al/Ti = 22) and Weltevreden-type (Al/Ti = 30) komatiites. Based on immobile trace-element ratios ([Gd/Lu]N = 0.6–2.0) and primary spinel-group mineral compositions, we classify the Morro do Onça komatiites as Weltevreden-type. Mesoarchean komatiites related to mantle plume-magmatism are now recognized throughout the southern São Francisco Craton, potentially suggesting that its precursor lithosphere was continuous during this Era.
ArticleNumber 34
Audience Academic
Author Pinheiro, Marco Aurélio Piacentini
Ferreira, Raianny Carolini Ramos
Ackerson, Michael R.
Melo-Silva, Paola
Guice, George L.
Magalhães, Joana Reis
Meira, Vinícius Tieppo
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  organization: Department of Mineral Sciences, National Museum of Natural History, Smithsonian Institution
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  surname: Magalhães
  fullname: Magalhães, Joana Reis
  organization: Geological Survey of Brazil-CPRM
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  givenname: Marco Aurélio Piacentini
  surname: Pinheiro
  fullname: Pinheiro, Marco Aurélio Piacentini
  organization: Geological Survey of Brazil-CPRM
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  givenname: Raianny Carolini Ramos
  surname: Ferreira
  fullname: Ferreira, Raianny Carolini Ramos
  organization: Geological Survey of Brazil-CPRM
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  organization: Institute of Geosciences, University of São Paulo
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  givenname: Michael R.
  surname: Ackerson
  fullname: Ackerson, Michael R.
  organization: Department of Mineral Sciences, National Museum of Natural History, Smithsonian Institution
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IsPeerReviewed true
IsScholarly true
Issue 3
Keywords Chromite
Geochemical fingerprinting
Weltevreden
Alteration
Early Earth tectonics
Element mobility
Komatiites
Language English
LinkModel DirectLink
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Notes ObjectType-Article-1
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content type line 14
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PQPubID 48463
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crossref_primary_10_1007_s00410_022_01901_0
springer_journals_10_1007_s00410_022_01901_0
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PublicationCentury 2000
PublicationDate 20220300
2022-03-00
20220301
PublicationDateYYYYMMDD 2022-03-01
PublicationDate_xml – month: 3
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PublicationDecade 2020
PublicationPlace Berlin/Heidelberg
PublicationPlace_xml – name: Berlin/Heidelberg
– name: Heidelberg
PublicationTitle Contributions to mineralogy and petrology
PublicationTitleAbbrev Contrib Mineral Petrol
PublicationYear 2022
Publisher Springer Berlin Heidelberg
Springer
Springer Nature B.V
Publisher_xml – name: Springer Berlin Heidelberg
– name: Springer
– name: Springer Nature B.V
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Snippet The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate...
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springer
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SubjectTerms Accretion
Aluminum
Amphibolites
Classification
Composition
Cratons
Earth
Earth and Environmental Science
Earth Sciences
Eclogite
Gadolinium
Geochemistry
Geology
Isotopes
Komatiites
Lava
Lithosphere
Magma
Magmatism
Mantle
Mantle plumes
Metamorphism
Metamorphism (Geology)
Meteorites
Mineral composition
Mineral Resources
Mineralogy
Minerals
Original Paper
Petrography
Petrology
Rare earth elements
Rocks
Rocks, Metamorphic
Samarium
Silicate minerals
Silicates
Spinel
Spinel group
Titanium
Titanium dioxide
Trace elements
Ultramafic materials
Ultramafic rocks
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Title Spinel-group minerals as a record of magmatic and metamorphic processes: evidence from the highly altered Morro do Onça ultramafic suite, São Francisco Craton (Brazil)
URI https://link.springer.com/article/10.1007/s00410-022-01901-0
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