Spinel-group minerals as a record of magmatic and metamorphic processes: evidence from the highly altered Morro do Onça ultramafic suite, São Francisco Craton (Brazil)
The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoprot...
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Published in | Contributions to mineralogy and petrology Vol. 177; no. 3 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Berlin/Heidelberg
Springer Berlin Heidelberg
01.03.2022
Springer Springer Nature B.V |
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Abstract | The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoproterozoic ophiolite/accretionary wedge or an Archean komatiite flow(s). In this paper, we utilize spinel-group mineral chemistry—alongside field mapping, petrography, silicate mineral chemistry and bulk-rock geochemistry—to decipher the magmatic and metamorphic evolution of the Morro do Onça suite. A komatiite origin is supported by the identification of spinifex-textured layers, as well as primary spinel-group mineral compositions (mean Cr-number = 79; mean TiO
2
= 0.3 wt%) and chondrite-normalized bulk-rock rare-earth element values ([Sm–Lu]
N
= 1.2–5.1). Metamorphism reached mid/upper amphibolite-facies and was likely responsible for Al mobility on mineral and bulk-rock scales, demonstrating that the bulk-rock Al/Ti proxy commonly used to classify komatiites is susceptible to alteration. Thus, the Morro do Onça komatiites record variable bulk-rock Al/Ti values (17–47) that overlap with both Munro- (Al/Ti = 22) and Weltevreden-type (Al/Ti = 30) komatiites. Based on immobile trace-element ratios ([Gd/Lu]
N
= 0.6–2.0) and primary spinel-group mineral compositions, we classify the Morro do Onça komatiites as Weltevreden-type. Mesoarchean komatiites related to mantle plume-magmatism are now recognized throughout the southern São Francisco Craton, potentially suggesting that its precursor lithosphere was continuous during this Era. |
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AbstractList | The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoproterozoic ophiolite/accretionary wedge or an Archean komatiite flow(s). In this paper, we utilize spinel-group mineral chemistry—alongside field mapping, petrography, silicate mineral chemistry and bulk-rock geochemistry—to decipher the magmatic and metamorphic evolution of the Morro do Onça suite. A komatiite origin is supported by the identification of spinifex-textured layers, as well as primary spinel-group mineral compositions (mean Cr-number = 79; mean TiO
2
= 0.3 wt%) and chondrite-normalized bulk-rock rare-earth element values ([Sm–Lu]
N
= 1.2–5.1). Metamorphism reached mid/upper amphibolite-facies and was likely responsible for Al mobility on mineral and bulk-rock scales, demonstrating that the bulk-rock Al/Ti proxy commonly used to classify komatiites is susceptible to alteration. Thus, the Morro do Onça komatiites record variable bulk-rock Al/Ti values (17–47) that overlap with both Munro- (Al/Ti = 22) and Weltevreden-type (Al/Ti = 30) komatiites. Based on immobile trace-element ratios ([Gd/Lu]
N
= 0.6–2.0) and primary spinel-group mineral compositions, we classify the Morro do Onça komatiites as Weltevreden-type. Mesoarchean komatiites related to mantle plume-magmatism are now recognized throughout the southern São Francisco Craton, potentially suggesting that its precursor lithosphere was continuous during this Era. The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoproterozoic ophiolite/accretionary wedge or an Archean komatiite flow(s). In this paper, we utilize spinel-group mineral chemistry-alongside field mapping, petrography, silicate mineral chemistry and bulk-rock geochemistry-to decipher the magmatic and metamorphic evolution of the Morro do Onça suite. A komatiite origin is supported by the identification of spinifex-textured layers, as well as primary spinel-group mineral compositions (mean Cr-number = 79; mean TiO.sub.2 = 0.3 wt%) and chondrite-normalized bulk-rock rare-earth element values ([Sm-Lu].sub.N = 1.2-5.1). Metamorphism reached mid/upper amphibolite-facies and was likely responsible for Al mobility on mineral and bulk-rock scales, demonstrating that the bulk-rock Al/Ti proxy commonly used to classify komatiites is susceptible to alteration. Thus, the Morro do Onça komatiites record variable bulk-rock Al/Ti values (17-47) that overlap with both Munro- (Al/Ti = 22) and Weltevreden-type (Al/Ti = 30) komatiites. Based on immobile trace-element ratios ([Gd/Lu].sub.N = 0.6-2.0) and primary spinel-group mineral compositions, we classify the Morro do Onça komatiites as Weltevreden-type. Mesoarchean komatiites related to mantle plume-magmatism are now recognized throughout the southern São Francisco Craton, potentially suggesting that its precursor lithosphere was continuous during this Era. The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate minerals, the Morro do Onça suite has been the subject of diverging interpretations, including: part of a retrogressed eclogite-facies Paleoproterozoic ophiolite/accretionary wedge or an Archean komatiite flow(s). In this paper, we utilize spinel-group mineral chemistry—alongside field mapping, petrography, silicate mineral chemistry and bulk-rock geochemistry—to decipher the magmatic and metamorphic evolution of the Morro do Onça suite. A komatiite origin is supported by the identification of spinifex-textured layers, as well as primary spinel-group mineral compositions (mean Cr-number = 79; mean TiO2 = 0.3 wt%) and chondrite-normalized bulk-rock rare-earth element values ([Sm–Lu]N = 1.2–5.1). Metamorphism reached mid/upper amphibolite-facies and was likely responsible for Al mobility on mineral and bulk-rock scales, demonstrating that the bulk-rock Al/Ti proxy commonly used to classify komatiites is susceptible to alteration. Thus, the Morro do Onça komatiites record variable bulk-rock Al/Ti values (17–47) that overlap with both Munro- (Al/Ti = 22) and Weltevreden-type (Al/Ti = 30) komatiites. Based on immobile trace-element ratios ([Gd/Lu]N = 0.6–2.0) and primary spinel-group mineral compositions, we classify the Morro do Onça komatiites as Weltevreden-type. Mesoarchean komatiites related to mantle plume-magmatism are now recognized throughout the southern São Francisco Craton, potentially suggesting that its precursor lithosphere was continuous during this Era. |
ArticleNumber | 34 |
Audience | Academic |
Author | Pinheiro, Marco Aurélio Piacentini Ferreira, Raianny Carolini Ramos Ackerson, Michael R. Melo-Silva, Paola Guice, George L. Magalhães, Joana Reis Meira, Vinícius Tieppo |
Author_xml | – sequence: 1 givenname: George L. orcidid: 0000-0003-0599-0907 surname: Guice fullname: Guice, George L. email: GuiceG@si.edu organization: Department of Mineral Sciences, National Museum of Natural History, Smithsonian Institution – sequence: 2 givenname: Joana Reis surname: Magalhães fullname: Magalhães, Joana Reis organization: Geological Survey of Brazil-CPRM – sequence: 3 givenname: Marco Aurélio Piacentini surname: Pinheiro fullname: Pinheiro, Marco Aurélio Piacentini organization: Geological Survey of Brazil-CPRM – sequence: 4 givenname: Raianny Carolini Ramos surname: Ferreira fullname: Ferreira, Raianny Carolini Ramos organization: Geological Survey of Brazil-CPRM – sequence: 5 givenname: Vinícius Tieppo surname: Meira fullname: Meira, Vinícius Tieppo organization: Department of Geology and Natural Resources, Institute of Geosciences, UNICAMP – sequence: 6 givenname: Paola surname: Melo-Silva fullname: Melo-Silva, Paola organization: Institute of Geosciences, University of São Paulo – sequence: 7 givenname: Michael R. surname: Ackerson fullname: Ackerson, Michael R. organization: Department of Mineral Sciences, National Museum of Natural History, Smithsonian Institution |
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Keywords | Chromite Geochemical fingerprinting Weltevreden Alteration Early Earth tectonics Element mobility Komatiites |
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Snippet | The Morro do Onça suite is a package of ultramafic rocks in the southern São Francisco Craton, Brazil. Owing to the complete alteration of primary silicate... |
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SubjectTerms | Accretion Aluminum Amphibolites Classification Composition Cratons Earth Earth and Environmental Science Earth Sciences Eclogite Gadolinium Geochemistry Geology Isotopes Komatiites Lava Lithosphere Magma Magmatism Mantle Mantle plumes Metamorphism Metamorphism (Geology) Meteorites Mineral composition Mineral Resources Mineralogy Minerals Original Paper Petrography Petrology Rare earth elements Rocks Rocks, Metamorphic Samarium Silicate minerals Silicates Spinel Spinel group Titanium Titanium dioxide Trace elements Ultramafic materials Ultramafic rocks |
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Title | Spinel-group minerals as a record of magmatic and metamorphic processes: evidence from the highly altered Morro do Onça ultramafic suite, São Francisco Craton (Brazil) |
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