Three-Dimensional Honeycomb-Like Carbon as Sulfur Host for Sodium–Sulfur Batteries without the Shuttle Effect
Sodium-sulfur batteries operating at ambient temperature are being extensively studied because of the high theoretical capacity and abundant resources, yet the long-chain polysulfides’ shuttle effect causes poor cycling performance of Na–S batteries. We report an annealing/etching method to converse...
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| Published in | ACS applied materials & interfaces Vol. 14; no. 49; pp. 54662 - 54669 |
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| Main Authors | , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
14.12.2022
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| Subjects | |
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| Abstract | Sodium-sulfur batteries operating at ambient temperature are being extensively studied because of the high theoretical capacity and abundant resources, yet the long-chain polysulfides’ shuttle effect causes poor cycling performance of Na–S batteries. We report an annealing/etching method to converse low-cost wheat bran to a 3D honeycomb-like carbon with abundant micropores (WBMC), which is smaller than S8 molecular size (∼0.7 nm). Thus, the microporous structure could only fill small molecular sulfur (S2–4). The micropores made sulfur a one-step reaction without the shuttle effect due to the formed short-chain polysulfides being insoluble. The WBMC@S exhibits an excellent initial capacity (1413 mAh g–1) at 0.2 C, outstanding cycling performance (822 mAh g–1 after 100 cycles at 0.2 C), and high rate performance (483 mAh g–1 at 3.0 C). The electrochemical performance proves that the steric confinement of micropores effectively terminates the shuttle effect. |
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| AbstractList | Sodium-sulfur batteries operating at ambient temperature are being extensively studied because of the high theoretical capacity and abundant resources, yet the long-chain polysulfides' shuttle effect causes poor cycling performance of Na-S batteries. We report an annealing/etching method to converse low-cost wheat bran to a 3D honeycomb-like carbon with abundant micropores (WBMC), which is smaller than S
molecular size (∼0.7 nm). Thus, the microporous structure could only fill small molecular sulfur (S
). The micropores made sulfur a one-step reaction without the shuttle effect due to the formed short-chain polysulfides being insoluble. The WBMC@S exhibits an excellent initial capacity (1413 mAh g
) at 0.2 C, outstanding cycling performance (822 mAh g
after 100 cycles at 0.2 C), and high rate performance (483 mAh g
at 3.0 C). The electrochemical performance proves that the steric confinement of micropores effectively terminates the shuttle effect. Sodium-sulfur batteries operating at ambient temperature are being extensively studied because of the high theoretical capacity and abundant resources, yet the long-chain polysulfides’ shuttle effect causes poor cycling performance of Na–S batteries. We report an annealing/etching method to converse low-cost wheat bran to a 3D honeycomb-like carbon with abundant micropores (WBMC), which is smaller than S8 molecular size (∼0.7 nm). Thus, the microporous structure could only fill small molecular sulfur (S2–4). The micropores made sulfur a one-step reaction without the shuttle effect due to the formed short-chain polysulfides being insoluble. The WBMC@S exhibits an excellent initial capacity (1413 mAh g–1) at 0.2 C, outstanding cycling performance (822 mAh g–1 after 100 cycles at 0.2 C), and high rate performance (483 mAh g–1 at 3.0 C). The electrochemical performance proves that the steric confinement of micropores effectively terminates the shuttle effect. Sodium-sulfur batteries operating at ambient temperature are being extensively studied because of the high theoretical capacity and abundant resources, yet the long-chain polysulfides' shuttle effect causes poor cycling performance of Na-S batteries. We report an annealing/etching method to converse low-cost wheat bran to a 3D honeycomb-like carbon with abundant micropores (WBMC), which is smaller than S8 molecular size (∼0.7 nm). Thus, the microporous structure could only fill small molecular sulfur (S2-4). The micropores made sulfur a one-step reaction without the shuttle effect due to the formed short-chain polysulfides being insoluble. The WBMC@S exhibits an excellent initial capacity (1413 mAh g-1) at 0.2 C, outstanding cycling performance (822 mAh g-1 after 100 cycles at 0.2 C), and high rate performance (483 mAh g-1 at 3.0 C). The electrochemical performance proves that the steric confinement of micropores effectively terminates the shuttle effect.Sodium-sulfur batteries operating at ambient temperature are being extensively studied because of the high theoretical capacity and abundant resources, yet the long-chain polysulfides' shuttle effect causes poor cycling performance of Na-S batteries. We report an annealing/etching method to converse low-cost wheat bran to a 3D honeycomb-like carbon with abundant micropores (WBMC), which is smaller than S8 molecular size (∼0.7 nm). Thus, the microporous structure could only fill small molecular sulfur (S2-4). The micropores made sulfur a one-step reaction without the shuttle effect due to the formed short-chain polysulfides being insoluble. The WBMC@S exhibits an excellent initial capacity (1413 mAh g-1) at 0.2 C, outstanding cycling performance (822 mAh g-1 after 100 cycles at 0.2 C), and high rate performance (483 mAh g-1 at 3.0 C). The electrochemical performance proves that the steric confinement of micropores effectively terminates the shuttle effect. |
| Author | Zhao, Decheng Zhou, Jian Liu, Xiang Xu, Xiangyu Ge-Zhang, Shangjie Zhang, Zhen Zhang, Yi Tang, Hao Wang, Zhoulu Xu, Yuanyuan Gao, Fei Liu, Shupei Wu, Yutong |
| AuthorAffiliation | College of Science Northeast Forestry University School of Energy Sciences and Engineering |
| AuthorAffiliation_xml | – name: College of Science – name: Northeast Forestry University – name: School of Energy Sciences and Engineering |
| Author_xml | – sequence: 1 givenname: Decheng surname: Zhao fullname: Zhao, Decheng organization: School of Energy Sciences and Engineering – sequence: 2 givenname: Shangjie surname: Ge-Zhang fullname: Ge-Zhang, Shangjie organization: Northeast Forestry University – sequence: 3 givenname: Zhen surname: Zhang fullname: Zhang, Zhen organization: School of Energy Sciences and Engineering – sequence: 4 givenname: Hao surname: Tang fullname: Tang, Hao organization: School of Energy Sciences and Engineering – sequence: 5 givenname: Yuanyuan surname: Xu fullname: Xu, Yuanyuan organization: School of Energy Sciences and Engineering – sequence: 6 givenname: Fei surname: Gao fullname: Gao, Fei organization: School of Energy Sciences and Engineering – sequence: 7 givenname: Xiangyu surname: Xu fullname: Xu, Xiangyu organization: School of Energy Sciences and Engineering – sequence: 8 givenname: Shupei surname: Liu fullname: Liu, Shupei organization: School of Energy Sciences and Engineering – sequence: 9 givenname: Jian surname: Zhou fullname: Zhou, Jian organization: School of Energy Sciences and Engineering – sequence: 10 givenname: Zhoulu surname: Wang fullname: Wang, Zhoulu organization: School of Energy Sciences and Engineering – sequence: 11 givenname: Yutong orcidid: 0000-0003-1214-9147 surname: Wu fullname: Wu, Yutong organization: School of Energy Sciences and Engineering – sequence: 12 givenname: Xiang surname: Liu fullname: Liu, Xiang email: iamxliu@njtech.edu.cn organization: School of Energy Sciences and Engineering – sequence: 13 givenname: Yi orcidid: 0000-0002-1603-8623 surname: Zhang fullname: Zhang, Yi email: zhangy@njtech.edu.cn organization: School of Energy Sciences and Engineering |
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| Title | Three-Dimensional Honeycomb-Like Carbon as Sulfur Host for Sodium–Sulfur Batteries without the Shuttle Effect |
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