Surface Curvature Effects in the Aqueous Ionic Solvation of the Chloride Ion
Molecular dynamics simulations of hydrated chloride ions have been performed with a polarizable model for interface geometries of varying curvature, ranging from clusters to planar surfaces. The solvation depth profile of the chloride ion is found to depend dramatically on the curvature of the inter...
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Published in | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 103; no. 49; pp. 10300 - 10307 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
09.12.1999
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Online Access | Get full text |
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Summary: | Molecular dynamics simulations of hydrated chloride ions have been performed with a polarizable model for interface geometries of varying curvature, ranging from clusters to planar surfaces. The solvation depth profile of the chloride ion is found to depend dramatically on the curvature of the interface. This behavior is consistent with the structure-breaking character of the chloride ion, and is successfully analyzed in terms of a simple geometric model. This model is expected to be useful in predicting analogous behavior in other ionic species. |
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Bibliography: | istex:8BB292A13462C66E6CF346BCBF745E475FF3E64C ark:/67375/TPS-Z3PCXPCN-X |
ISSN: | 1089-5639 1520-5215 |
DOI: | 10.1021/jp991671q |