Crystalline Liquid-like Behavior: Surface-Induced Secondary Grain Growth of Photovoltaic Perovskite Thin Film
Surface effects usually become negligible on the micrometer or sub-micrometer scale due to lower surface-to-bulk ratio compared to nanomaterials. In lead halide perovskites, however, their “soft” nature renders them highly responsive to the external field, allowing for extended depth scale affected...
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| Published in | Journal of the American Chemical Society Vol. 141; no. 35; pp. 13948 - 13953 |
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| Main Authors | , , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
04.09.2019
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Surface effects usually become negligible on the micrometer or sub-micrometer scale due to lower surface-to-bulk ratio compared to nanomaterials. In lead halide perovskites, however, their “soft” nature renders them highly responsive to the external field, allowing for extended depth scale affected by the surface. Herein, by taking advantage of this unique feature of perovskites we demonstrate a methodology for property manipulation of perovskite thin films based on secondary grain growth, where tuning of the surface induces the internal property evolution of the entire perovskite film. While in conventional microelectronic techniques secondary grain growth generally involves harsh conditions such as high temperature and straining, it is easily triggered in a perovskite thin film by a simple surface post-treatment, producing enlarged grain sizes of up to 4 μm. The resulting photovoltaic devices exhibit significantly enhanced power conversion efficiency and operational stability over a course of 1000 h and an ambient shelf stability of over 4000 h while maintaining over 90% of its original efficiency. |
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| AbstractList | Surface effects usually become negligible on the micrometer or sub-micrometer scale due to lower surface-to-bulk ratio compared to nanomaterials. In lead halide perovskites, however, their "soft" nature renders them highly responsive to the external field, allowing for extended depth scale affected by the surface. Herein, by taking advantage of this unique feature of perovskites we demonstrate a methodology for property manipulation of perovskite thin films based on secondary grain growth, where tuning of the surface induces the internal property evolution of the entire perovskite film. While in conventional microelectronic techniques secondary grain growth generally involves harsh conditions such as high temperature and straining, it is easily triggered in a perovskite thin film by a simple surface post-treatment, producing enlarged grain sizes of up to 4 μm. The resulting photovoltaic devices exhibit significantly enhanced power conversion efficiency and operational stability over a course of 1000 h and an ambient shelf stability of over 4000 h while maintaining over 90% of its original efficiency.Surface effects usually become negligible on the micrometer or sub-micrometer scale due to lower surface-to-bulk ratio compared to nanomaterials. In lead halide perovskites, however, their "soft" nature renders them highly responsive to the external field, allowing for extended depth scale affected by the surface. Herein, by taking advantage of this unique feature of perovskites we demonstrate a methodology for property manipulation of perovskite thin films based on secondary grain growth, where tuning of the surface induces the internal property evolution of the entire perovskite film. While in conventional microelectronic techniques secondary grain growth generally involves harsh conditions such as high temperature and straining, it is easily triggered in a perovskite thin film by a simple surface post-treatment, producing enlarged grain sizes of up to 4 μm. The resulting photovoltaic devices exhibit significantly enhanced power conversion efficiency and operational stability over a course of 1000 h and an ambient shelf stability of over 4000 h while maintaining over 90% of its original efficiency. Surface effects usually become negligible on the micrometer or sub-micrometer scale due to lower surface-to-bulk ratio compared to nanomaterials. In lead halide perovskites, however, their “soft” nature renders them highly responsive to the external field, allowing for extended depth scale affected by the surface. Herein, by taking advantage of this unique feature of perovskites we demonstrate a methodology for property manipulation of perovskite thin films based on secondary grain growth, where tuning of the surface induces the internal property evolution of the entire perovskite film. While in conventional microelectronic techniques secondary grain growth generally involves harsh conditions such as high temperature and straining, it is easily triggered in a perovskite thin film by a simple surface post-treatment, producing enlarged grain sizes of up to 4 μm. The resulting photovoltaic devices exhibit significantly enhanced power conversion efficiency and operational stability over a course of 1000 h and an ambient shelf stability of over 4000 h while maintaining over 90% of its original efficiency. Surface effects usually become negligible on the micron or submicron scale due to lower surface-to-bulk ratio compared to nano-materials. In lead halide perovskites, however, their "soft" nature renders them highly responsive to the external field allowing for extended depth scale affected by the surface. Herein, by taking advantage of this unique feature of perovskites we demonstrate a methodology for property manipulation of perovskite thin films based on secondary grain growth, where tuning of the surface induces the internal property evolution of the entire perovskite film. While in conventional microelectronic techniques secondary grain growth generally involves harsh conditions such as high temperature and straining, it is easily triggered in perovskite thin film by a simple surface post-treatment, producing enlarged grain sizes of up to 4 μm. The resulting photovoltaic devices exhibit significantly enhanced power conversion efficiency and operational stability over a course of 1000 h and an ambient shelf stability of over 4000 h while maintaining over 90% of its original efficiency. |
| Author | Gao, Xingyu Huang, Tianyi Kaner, Richard Nuryyeva, Selbi Yang, Yang Wang, Rui Yang, Yingguo Wang, Zhao-Kui Wang, Yang Liao, Liang-Sheng Wang, Kai-Li Lee, Jin-Wook Yavuz, Ilhan Xue, Jingjing Duan, Yu |
| AuthorAffiliation | Chinese Academy of Sciences Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices Yangzhou University Shanghai Synchrotron Radiation Facility (SSRF), Zhangjiang Lab, Shanghai Advanced Research Institute Department of Materials Science and Engineering and California NanoSystems Institute School of Chemistry and Chemical Engineering Department of Physics |
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| Author_xml | – sequence: 1 givenname: Jingjing surname: Xue fullname: Xue, Jingjing organization: Department of Materials Science and Engineering and California NanoSystems Institute – sequence: 2 givenname: Rui surname: Wang fullname: Wang, Rui organization: Department of Materials Science and Engineering and California NanoSystems Institute – sequence: 3 givenname: Kai-Li surname: Wang fullname: Wang, Kai-Li organization: Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices – sequence: 4 givenname: Zhao-Kui orcidid: 0000-0003-1707-499X surname: Wang fullname: Wang, Zhao-Kui email: zkwang@suda.edu.cn organization: Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices – sequence: 5 givenname: Ilhan orcidid: 0000-0002-3268-6268 surname: Yavuz fullname: Yavuz, Ilhan organization: Department of Physics – sequence: 6 givenname: Yang orcidid: 0000-0003-2540-2199 surname: Wang fullname: Wang, Yang organization: Yangzhou University – sequence: 7 givenname: Yingguo orcidid: 0000-0002-1749-2799 surname: Yang fullname: Yang, Yingguo organization: Chinese Academy of Sciences – sequence: 8 givenname: Xingyu orcidid: 0000-0003-1477-0092 surname: Gao fullname: Gao, Xingyu organization: Chinese Academy of Sciences – sequence: 9 givenname: Tianyi surname: Huang fullname: Huang, Tianyi organization: Department of Materials Science and Engineering and California NanoSystems Institute – sequence: 10 givenname: Selbi surname: Nuryyeva fullname: Nuryyeva, Selbi organization: Department of Materials Science and Engineering and California NanoSystems Institute – sequence: 11 givenname: Jin-Wook surname: Lee fullname: Lee, Jin-Wook organization: Department of Materials Science and Engineering and California NanoSystems Institute – sequence: 12 givenname: Yu orcidid: 0000-0002-2155-7188 surname: Duan fullname: Duan, Yu organization: Department of Materials Science and Engineering and California NanoSystems Institute – sequence: 13 givenname: Liang-Sheng orcidid: 0000-0002-2352-9666 surname: Liao fullname: Liao, Liang-Sheng email: lsliao@suda.edu.cn organization: Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices – sequence: 14 givenname: Richard orcidid: 0000-0003-0345-4924 surname: Kaner fullname: Kaner, Richard organization: Department of Materials Science and Engineering and California NanoSystems Institute – sequence: 15 givenname: Yang orcidid: 0000-0001-8833-7641 surname: Yang fullname: Yang, Yang email: yangy@ucla.edu organization: Department of Materials Science and Engineering and California NanoSystems Institute |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31403287$$D View this record in MEDLINE/PubMed |
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| Snippet | Surface effects usually become negligible on the micrometer or sub-micrometer scale due to lower surface-to-bulk ratio compared to nanomaterials. In lead... Surface effects usually become negligible on the micron or submicron scale due to lower surface-to-bulk ratio compared to nano-materials. In lead halide... |
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| SubjectTerms | lead nanomaterials photovoltaic cells temperature |
| Title | Crystalline Liquid-like Behavior: Surface-Induced Secondary Grain Growth of Photovoltaic Perovskite Thin Film |
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