Coupling N–H Deprotonation, C–H Activation, and Oxidation: Metal-Free C(sp3)–H Aminations with Unprotected Anilines - Evoniuk, Christopher J; Gomes, Gabriel dos Passos; Hill, Sean P; Fujita, Satoshi; Hanson, Kenneth; Alabugin, Igor V (Journal of the American Chemical Society, 2017)
Keywords: acidity; amination; aromatic compounds; carbon-hydrogen bond activation; chemical bonding; Chemistry; Chemistry, Multidisciplinary; dimethylformamide; heterocyclic nitrogen compounds; oxidants; oxidation; oxygen; Physical Sciences; Science & Technology; transition elements; AROMATIC-HYDROCARBONS; DENSITY FUNCTIONALS; CHEMICAL-SHIFTS NICS; RADICAL STABILITY; SOMO-HOMO CONVERSION; EFFICIENT SYNTHESIS; CONNECTOR GROUPS; SINGLET OXYGEN; SYNTHETIC APPROACH; INTRAMOLECULAR ADDITION