A New Core/Shell NiAu/Au Nanoparticle Catalyst with Pt-like Activity for Hydrogen Evolution Reaction
We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)2 (acac = acetylacetonate) and HAuCl4·3H2O at 220 °C in the presence of oleylamine and oleic acid. Subject to potential cycling between 0.6 and 1.0 V (vs reversible hydrogen electrode) in 0.5 M H2SO4, the NiAu...
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| Published in | Journal of the American Chemical Society Vol. 137; no. 18; pp. 5859 - 5862 |
|---|---|
| Main Authors | , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
13.05.2015
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| Subjects | |
| Online Access | Get full text |
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| Abstract | We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)2 (acac = acetylacetonate) and HAuCl4·3H2O at 220 °C in the presence of oleylamine and oleic acid. Subject to potential cycling between 0.6 and 1.0 V (vs reversible hydrogen electrode) in 0.5 M H2SO4, the NiAu NPs are transformed into core/shell NiAu/Au NPs that show much enhanced catalysis for hydrogen evolution reaction (HER) with Pt-like activity and much robust durability. The first-principles calculations suggest that the high activity arises from the formation of Au sites with low coordination numbers around the shell. Our synthesis is not limited to NiAu but can be extended to FeAu and CoAu as well, providing a general approach to MAu/Au NPs as a class of new catalyst superior to Pt for water splitting and hydrogen generation. |
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| AbstractList | We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)2 (acac = acetylacetonate) and HAuCl4·3H2O at 220 °C in the presence of oleylamine and oleic acid. Subject to potential cycling between 0.6 and 1.0 V (vs reversible hydrogen electrode) in 0.5 M H2SO4, the NiAu NPs are transformed into core/shell NiAu/Au NPs that show much enhanced catalysis for hydrogen evolution reaction (HER) with Pt-like activity and much robust durability. The first-principles calculations suggest that the high activity arises from the formation of Au sites with low coordination numbers around the shell. Our synthesis is not limited to NiAu but can be extended to FeAu and CoAu as well, providing a general approach to MAu/Au NPs as a class of new catalyst superior to Pt for water splitting and hydrogen generation. We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)2 (acac = acetylacetonate) and HAuCl4·3H2O at 220 °C in the presence of oleylamine and oleic acid. Subject to potential cycling between 0.6 and 1.0 V (vs reversible hydrogen electrode) in 0.5 M H2SO4, the NiAu NPs are transformed into core/shell NiAu/Au NPs that show much enhanced catalysis for hydrogen evolution reaction (HER) with Pt-like activity and much robust durability. The first-principles calculations suggest that the high activity arises from the formation of Au sites with low coordination numbers around the shell. Our synthesis is not limited to NiAu but can be extended to FeAu and CoAu as well, providing a general approach to MAu/Au NPs as a class of new catalyst superior to Pt for water splitting and hydrogen generation.We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)2 (acac = acetylacetonate) and HAuCl4·3H2O at 220 °C in the presence of oleylamine and oleic acid. Subject to potential cycling between 0.6 and 1.0 V (vs reversible hydrogen electrode) in 0.5 M H2SO4, the NiAu NPs are transformed into core/shell NiAu/Au NPs that show much enhanced catalysis for hydrogen evolution reaction (HER) with Pt-like activity and much robust durability. The first-principles calculations suggest that the high activity arises from the formation of Au sites with low coordination numbers around the shell. Our synthesis is not limited to NiAu but can be extended to FeAu and CoAu as well, providing a general approach to MAu/Au NPs as a class of new catalyst superior to Pt for water splitting and hydrogen generation. We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)2 (acac = acetylacetonate) and HAuCl4·3H2O at 220 °C in the presence of oleylamine and oleic acid. Subject to potential cycling between 0.6 and 1.0 V (vs reversible hydrogen electrode) in 0.5 M H2SO4, the NiAu NPs are transformed into core/shell NiAu/Au NPs that show much enhanced catalysis for hydrogen evolution reaction (HER) with Pt-like activity and much robust durability. The first-principles calculations suggest that the high activity arises from the formation of Au sites with low coordination numbers around the shell. Our synthesis is not limited to NiAu but can be extended to FeAu and CoAu as well, providing a general approach to MAu/Au NPs as a class of new catalyst superior to Pt for water splitting and hydrogen generation. We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)₂ (acac = acetylacetonate) and HAuCl₄·3H₂O at 220 °C in the presence of oleylamine and oleic acid. Subject to potential cycling between 0.6 and 1.0 V (vs reversible hydrogen electrode) in 0.5 M H₂SO₄, the NiAu NPs are transformed into core/shell NiAu/Au NPs that show much enhanced catalysis for hydrogen evolution reaction (HER) with Pt-like activity and much robust durability. The first-principles calculations suggest that the high activity arises from the formation of Au sites with low coordination numbers around the shell. Our synthesis is not limited to NiAu but can be extended to FeAu and CoAu as well, providing a general approach to MAu/Au NPs as a class of new catalyst superior to Pt for water splitting and hydrogen generation. |
| Author | Mu, Shichun Pan, Mu Sun, Shouheng Li, Qing Yu, Yongsheng Zhang, Xu Xi, Zheng Chen, Zhengzheng Guo, Shaojun Lv, Haifeng Zhu, Wenlei Lu, Gang |
| AuthorAffiliation | Department of Chemistry Brown University Wuhan University of Technology State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Department of Physics and Astronomy California State University Northridge School of Chemical Engineering and Technology Harbin Institute of Technology, Harbin |
| AuthorAffiliation_xml | – name: State Key Laboratory of Advanced Technology for Materials Synthesis and Processing – name: Department of Chemistry – name: Brown University – name: Department of Physics and Astronomy – name: California State University Northridge – name: Harbin Institute of Technology, Harbin – name: Wuhan University of Technology – name: School of Chemical Engineering and Technology |
| Author_xml | – sequence: 1 givenname: Haifeng surname: Lv fullname: Lv, Haifeng – sequence: 2 givenname: Zheng surname: Xi fullname: Xi, Zheng – sequence: 3 givenname: Zhengzheng surname: Chen fullname: Chen, Zhengzheng – sequence: 4 givenname: Shaojun surname: Guo fullname: Guo, Shaojun – sequence: 5 givenname: Yongsheng surname: Yu fullname: Yu, Yongsheng – sequence: 6 givenname: Wenlei surname: Zhu fullname: Zhu, Wenlei – sequence: 7 givenname: Qing surname: Li fullname: Li, Qing – sequence: 8 givenname: Xu surname: Zhang fullname: Zhang, Xu – sequence: 9 givenname: Mu surname: Pan fullname: Pan, Mu – sequence: 10 givenname: Gang surname: Lu fullname: Lu, Gang email: ganglu@csun.edu – sequence: 11 givenname: Shichun surname: Mu fullname: Mu, Shichun email: msc@whut.edu.cn – sequence: 12 givenname: Shouheng surname: Sun fullname: Sun, Shouheng email: ssun@brown.edu |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/25927960$$D View this record in MEDLINE/PubMed |
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| Snippet | We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)2 (acac = acetylacetonate) and HAuCl4·3H2O at 220 °C in the presence... We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)2 (acac = acetylacetonate) and HAuCl4·3H2O at 220 °C in the presence... We report a general approach to NiAu alloy nanoparticles (NPs) by co-reduction of Ni(acac)₂ (acac = acetylacetonate) and HAuCl₄·3H₂O at 220 °C in the presence... |
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| SubjectTerms | alloy nanoparticles catalysts catalytic activity durability electrodes gold hydrogen hydrogen production nanogold nickel oleic acid sulfuric acid |
| Title | A New Core/Shell NiAu/Au Nanoparticle Catalyst with Pt-like Activity for Hydrogen Evolution Reaction |
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