Steric Engineering of Cyclometalated Pt(II) Complexes toward High-Contrast Monomer–Excimer-Based Mechanochromic and Vapochromic Luminescence

• Published in: Inorganic chemistry Vol. 59; no. 16; pp. 11584 - 11594
• Main Authors: Lien, Chen-Yu, Hsu, Ying-Feng, Liu, Yi-Hung, Peng, Shie-Ming, Shinmyozu, Teruo, Yang, Jye-Shane
• Format: Journal Article
• Language: English
• Published: American Chemical Society 17.08.2020

Ligands play a crucial role in the supramolecular photoluminescence properties of Pt­(II) square-planar complexes. To improve the luminescence color responses of N∧C∧N cyclometalated Pt­(II) complexes to external stimuli such as mechanical stress and chemical vapors, we have conducted a steric engin...