Differential Capacitance of Room Temperature Ionic Liquids: The Role of Dispersion Forces

We investigate theoretical models of room temperature ionic liquids, and find that the experimentally observed camel-shape of the differential capacitance is strongly related to dispersion interactions in these systems. At low surface charge densities, the loss of dispersion interactions in the vici...

Full description

Saved in:
Bibliographic Details
Published inThe journal of physical chemistry letters Vol. 1; no. 8; pp. 1191 - 1195
Main Authors Trulsson, Martin, Algotsson, Jenny, Forsman, Jan, Woodward, Clifford E
Format Journal Article
LanguageEnglish
Published American Chemical Society 15.04.2010
Subjects
Chemical Sciences
Kemi
Natural Sciences
Naturvetenskap
Surfaces, Interfaces, Catalysis
Teoretisk kemi
Theoretical Chemistry
Online AccessGet full text

Cover

Abstract We investigate theoretical models of room temperature ionic liquids, and find that the experimentally observed camel-shape of the differential capacitance is strongly related to dispersion interactions in these systems. At low surface charge densities, the loss of dispersion interactions in the vicinity of the electrodes generates depleted densities, with a concomitant drop of the differential capacitance. This behavior is not observed in models where dispersion interactions have been removed.
AbstractList We investigate theoretical models of room temperature ionic liquids, and find that the experimentally observed camel-shape of the differential capacitance is strongly related to dispersion interactions in these systems. At low surface charge densities, the loss of dispersion interactions in the vicinity of the electrodes generates depleted densities, with a concomitant drop of the differential capacitance. This behavior is not observed in models where dispersion interactions have been removed.
Author Algotsson, Jenny
Trulsson, Martin
Forsman, Jan
Woodward, Clifford E
Author_xml – sequence: 1
  givenname: Martin
  surname: Trulsson
  fullname: Trulsson, Martin
– sequence: 2
  givenname: Jenny
  surname: Algotsson
  fullname: Algotsson, Jenny
– sequence: 3
  givenname: Jan
  surname: Forsman
  fullname: Forsman, Jan
  email: jan.forsman@teokem.lu.se
– sequence: 4
  givenname: Clifford E
  surname: Woodward
  fullname: Woodward, Clifford E
BackLink https://lup.lub.lu.se/record/1601670$$DView record from Swedish Publication Index
BookMark eNptkEFLwzAUx4NMcJse_Aa9ePBQTdq0SbzJ5nRQEGQePIU0fcGMrqlJi-inNzoZHjz8eQ_ejx-8_wxNOtcBQucEXxGckevtp8CYkmw4QlMiKE8Z4cXkz36CZiFsMS4F5myKXpbWGPDQDVa1yUL1SttBdRoSZ5In53bJBnY9eDWMHpK166xOKvs22ibcJJtXiEz7wy5tiFiwrktWzmsIp-jYqDbA2e-co-fV3WbxkFaP9-vFbZWqXNAhFcQUnHFlaFaUuuECBECugLCM66KkTLOa55oxU9ccjC5JKbSJF0Exodjkc1TtveEd-rGWvbc75T-kU1a2Yx9Tx8gAkhel0bRuZMaBSEqIkTxXTOa54XnWCG6EirrLvU57F4IHcxASLL8rloeKI3uxZ5UOcutG38VH_-G-AKJPfJM
CitedBy_id crossref_primary_10_1002_elps_201600455
crossref_primary_10_1021_cr400374x
crossref_primary_10_1021_acs_jpcc_1c05698
crossref_primary_10_1063_1_4919314
crossref_primary_10_1002_celc_202200274
crossref_primary_10_1063_1_4893714
crossref_primary_10_1016_j_electacta_2018_08_011
crossref_primary_10_1016_j_electacta_2016_12_154
crossref_primary_10_1016_j_electacta_2023_142314
crossref_primary_10_1021_acs_jctc_9b00804
crossref_primary_10_1021_ja104273r
crossref_primary_10_1002_advs_201700059
crossref_primary_10_1021_jp5072583
crossref_primary_10_1063_1_5127851
crossref_primary_10_1021_jp111747w
crossref_primary_10_1088_1361_6463_ac66a7
crossref_primary_10_5402_2012_397052
crossref_primary_10_1080_00268976_2014_968648
crossref_primary_10_1016_j_cplett_2011_01_072
crossref_primary_10_1021_la4041425
crossref_primary_10_1039_D3EE00864A
crossref_primary_10_1021_acs_langmuir_7b01787
crossref_primary_10_1039_C1FD00088H
crossref_primary_10_1016_j_jelechem_2010_07_004
crossref_primary_10_1016_j_ceramint_2014_12_088
crossref_primary_10_1039_c3cp55186e
crossref_primary_10_1021_acs_jpclett_1c03900
crossref_primary_10_1021_jp105266y
crossref_primary_10_1021_jp105317e
crossref_primary_10_1088_1361_648X_aaa524
crossref_primary_10_1016_j_electacta_2023_143012
crossref_primary_10_1016_j_electacta_2020_135747
crossref_primary_10_1021_jp411698w
crossref_primary_10_1039_D3CP05039D
crossref_primary_10_1016_j_jelechem_2012_01_005
crossref_primary_10_1063_1_5013134
crossref_primary_10_1016_j_electacta_2018_07_126
crossref_primary_10_1021_jp203458b
crossref_primary_10_1016_j_electacta_2019_05_038
crossref_primary_10_1021_jp504001u
crossref_primary_10_1021_acs_jpcc_8b09756
crossref_primary_10_1021_acs_langmuir_7b01677
crossref_primary_10_1080_00268976_2010_519731
crossref_primary_10_1063_1_5082561
crossref_primary_10_1103_PhysRevLett_106_046102
crossref_primary_10_1016_j_jelechem_2012_11_018
crossref_primary_10_1088_1742_5468_ad4022
crossref_primary_10_3390_polym12030722
crossref_primary_10_1021_jz200879a
crossref_primary_10_1039_c1cp20798a
crossref_primary_10_1016_j_electacta_2022_141163
crossref_primary_10_1016_j_jelechem_2017_02_001
crossref_primary_10_1021_acs_jpclett_7b02946
crossref_primary_10_1039_D0CS00059K
crossref_primary_10_1063_1_4862998
crossref_primary_10_1021_jz4002967
crossref_primary_10_1039_c3sm53169d
crossref_primary_10_1016_j_jelechem_2013_10_004
crossref_primary_10_1149_1945_7111_acf95b
crossref_primary_10_1021_jp403547k
crossref_primary_10_1016_j_electacta_2016_12_092
crossref_primary_10_1016_j_electacta_2022_140832
crossref_primary_10_1021_ja508222m
crossref_primary_10_1021_jp301399b
crossref_primary_10_1007_s10800_021_01571_z
crossref_primary_10_1039_C1FD00086A
crossref_primary_10_1103_PhysRevE_84_051504
crossref_primary_10_1016_j_jelechem_2017_11_005
crossref_primary_10_1016_j_molliq_2022_119943
crossref_primary_10_1021_jp2001207
crossref_primary_10_1016_j_electacta_2023_142261
crossref_primary_10_1021_jp1123162
crossref_primary_10_1002_admt_202100293
crossref_primary_10_1016_j_jpowsour_2014_09_071
crossref_primary_10_1039_C6CP00202A
crossref_primary_10_1039_c2cp23267g
crossref_primary_10_1080_00268976_2019_1642527
crossref_primary_10_1021_jp309794w
crossref_primary_10_1016_j_electacta_2015_02_180
crossref_primary_10_1002_cphc_201200013
crossref_primary_10_1021_jz4014163
crossref_primary_10_1016_j_electacta_2016_07_139
crossref_primary_10_1088_0953_8984_26_28_284106
crossref_primary_10_1016_j_molliq_2017_09_077
crossref_primary_10_1021_acs_jpcc_0c03229
crossref_primary_10_1039_c1cp21428d
crossref_primary_10_1002_cphc_201000278
crossref_primary_10_1063_1_5048309
crossref_primary_10_1016_j_electacta_2017_06_169
crossref_primary_10_1063_1_5045237
crossref_primary_10_1039_c3cp51218e
Cites_doi 10.1039/b815835e
10.1016/j.elecom.2007.07.009
10.1103/PhysRevLett.103.117801
10.1016/j.elecom.2009.12.019
10.1021/ct600083s
10.1039/b920080k
10.1063/1.479595
10.1021/jp900037h
10.1021/ar700065s
10.1149/1.1838024
10.1021/ja0619612
10.1021/jp8058849
10.1021/jp7100732
10.1002/anie.200900300
10.1021/jp067857o
10.1021/jp803440q
10.1063/1.440065
ContentType Journal Article
Copyright Copyright © 2010 American Chemical Society
Copyright_xml – notice: Copyright © 2010 American Chemical Society
DBID AAYXX
CITATION
ADTPV
AOWAS
D95
DOI 10.1021/jz900412t
DatabaseName CrossRef
SwePub
SwePub Articles
SWEPUB Lunds universitet
DatabaseTitle CrossRef
DatabaseTitleList

DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1948-7185
EndPage 1195
ExternalDocumentID oai_lup_lub_lu_se_856fc4bd_28e1_411f_83a7_33f832d98f9a
10_1021_jz900412t
c829987640
GroupedDBID 4.4
53G
55A
5VS
7~N
AABXI
ABMVS
ABUCX
ACGFS
ACS
AEESW
AENEX
AFEFF
ALMA_UNASSIGNED_HOLDINGS
AQSVZ
BAANH
DU5
EBS
ED
ED~
EJD
GNL
IH9
JG
JG~
P2P
RNS
ROL
UI2
VF5
VG9
W1F
XKZ
AAYXX
ABJNI
ABQRX
ACGFO
ADHLV
AHGAQ
CITATION
CUPRZ
GGK
ADTPV
AOWAS
D95
ID FETCH-LOGICAL-a394t-91f5878af4256cd89e9ee3ae1728c5647c7b83c77fbb8efc6169cfc56940140f3
IEDL.DBID ACS
ISSN 1948-7185
IngestDate Sat Aug 24 00:48:29 EDT 2024
Fri Aug 23 00:26:53 EDT 2024
Thu Aug 27 13:42:59 EDT 2020
IsPeerReviewed true
IsScholarly true
Issue 8
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-a394t-91f5878af4256cd89e9ee3ae1728c5647c7b83c77fbb8efc6169cfc56940140f3
PageCount 5
ParticipantIDs swepub_primary_oai_lup_lub_lu_se_856fc4bd_28e1_411f_83a7_33f832d98f9a
crossref_primary_10_1021_jz900412t
acs_journals_10_1021_jz900412t
ProviderPackageCode JG~
55A
AABXI
GNL
VF5
XKZ
7~N
VG9
W1F
ACS
AEESW
AFEFF
ABMVS
ABUCX
IH9
BAANH
AQSVZ
ED~
UI2
PublicationCentury 2000
PublicationDate 2010-04-15
PublicationDateYYYYMMDD 2010-04-15
PublicationDate_xml – month: 04
  year: 2010
  text: 2010-04-15
  day: 15
PublicationDecade 2010
PublicationTitle The journal of physical chemistry letters
PublicationTitleAlternate J. Phys. Chem. Lett
PublicationYear 2010
Publisher American Chemical Society
Publisher_xml – name: American Chemical Society
References Alam M. T. (ref4/cit4) 2007; 9
Izgordina E. I. (ref14/cit14) 2009; 11
Yang Y. (ref18/cit18) 2006; 2
Lockett V. (ref7/cit7) 2008; 112
Fedorov M. V. (ref11/cit11) 2010; 12
Lynden-Bell R. M. (ref12/cit12) 2007; 40
Kobrak M. N. (ref15/cit15) 2010; 12
Yeh I.-C. (ref17/cit17) 1999; 111
Nanjundiah C. (ref6/cit6) 1997; 144
Lamperski S. (ref9/cit9) 2009; 113
Wasserscheid P. (ref2/cit2) 2003
Su Y.-Z. (ref16/cit16) 2009; 48
Alam M. T. (ref5/cit5) 2008; 112
Kornyshev A. A. (ref3/cit3) 2007; 111
Rogers R. K. (ref1/cit1) 2002
Lauw Y. (ref10/cit10) 2009; 103
Fedorov M. V. (ref8/cit8) 2008; 112
Krossing I. (ref13/cit13) 2006; 128
Torrie G. M. (ref19/cit19) 1980; 73
References_xml – volume: 11
  start-page: 2452
  year: 2009
  ident: ref14/cit14
  publication-title: Phys. Chem. Chem. Phys.
  doi: 10.1039/b815835e
  contributor:
    fullname: Izgordina E. I.
– volume: 9
  start-page: 2370
  year: 2007
  ident: ref4/cit4
  publication-title: Electrochem. Commun.
  doi: 10.1016/j.elecom.2007.07.009
  contributor:
    fullname: Alam M. T.
– volume-title: Ionic Liquids in Synthesis
  year: 2003
  ident: ref2/cit2
  contributor:
    fullname: Wasserscheid P.
– volume: 103
  start-page: 117801-1
  year: 2009
  ident: ref10/cit10
  publication-title: Phys. Rev. Lett.
  doi: 10.1103/PhysRevLett.103.117801
  contributor:
    fullname: Lauw Y.
– volume: 12
  start-page: 296
  year: 2010
  ident: ref11/cit11
  publication-title: Electrochem. Commun.
  doi: 10.1016/j.elecom.2009.12.019
  contributor:
    fullname: Fedorov M. V.
– volume: 2
  start-page: 1618
  year: 2006
  ident: ref18/cit18
  publication-title: J. Chem. Theory Comput.
  doi: 10.1021/ct600083s
  contributor:
    fullname: Yang Y.
– volume: 12
  start-page: 1922
  year: 2010
  ident: ref15/cit15
  publication-title: Phys. Chem. Chem. Phys.
  doi: 10.1039/b920080k
  contributor:
    fullname: Kobrak M. N.
– volume: 111
  start-page: 3155
  year: 1999
  ident: ref17/cit17
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.479595
  contributor:
    fullname: Yeh I.-C.
– volume: 113
  start-page: 8925
  year: 2009
  ident: ref9/cit9
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp900037h
  contributor:
    fullname: Lamperski S.
– volume: 40
  start-page: 1138
  year: 2007
  ident: ref12/cit12
  publication-title: Acc. Chem. Res.
  doi: 10.1021/ar700065s
  contributor:
    fullname: Lynden-Bell R. M.
– volume: 144
  start-page: 3392
  year: 1997
  ident: ref6/cit6
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/1.1838024
  contributor:
    fullname: Nanjundiah C.
– volume: 128
  start-page: 13427
  year: 2006
  ident: ref13/cit13
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja0619612
  contributor:
    fullname: Krossing I.
– volume: 112
  start-page: 16568
  year: 2008
  ident: ref5/cit5
  publication-title: J. Phys. Chem. C
  doi: 10.1021/jp8058849
  contributor:
    fullname: Alam M. T.
– volume: 112
  start-page: 7486
  year: 2008
  ident: ref7/cit7
  publication-title: J. Phys. Chem. C
  doi: 10.1021/jp7100732
  contributor:
    fullname: Lockett V.
– volume: 48
  start-page: 5148
  year: 2009
  ident: ref16/cit16
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200900300
  contributor:
    fullname: Su Y.-Z.
– volume-title: Ionic Liquids, Industrial Applications to Green Chemistry
  year: 2002
  ident: ref1/cit1
  contributor:
    fullname: Rogers R. K.
– volume: 111
  start-page: 5545
  year: 2007
  ident: ref3/cit3
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp067857o
  contributor:
    fullname: Kornyshev A. A.
– volume: 112
  start-page: 11868
  year: 2008
  ident: ref8/cit8
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp803440q
  contributor:
    fullname: Fedorov M. V.
– volume: 73
  start-page: 5807
  year: 1980
  ident: ref19/cit19
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.440065
  contributor:
    fullname: Torrie G. M.
SSID ssj0069087
Score 2.3381321
Snippet We investigate theoretical models of room temperature ionic liquids, and find that the experimentally observed camel-shape of the differential capacitance is...
SourceID swepub
crossref
acs
SourceType Open Access Repository
Aggregation Database
Publisher
StartPage 1191
SubjectTerms Chemical Sciences
Kemi
Natural Sciences
Naturvetenskap
Surfaces, Interfaces, Catalysis
Teoretisk kemi
Theoretical Chemistry
Title Differential Capacitance of Room Temperature Ionic Liquids: The Role of Dispersion Forces
URI http://dx.doi.org/10.1021/jz900412t
https://lup.lub.lu.se/record/1601670
Volume 1
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwhV07T8MwELZKGWDhjSgvWcCaguMkttlQSwUIGKCVymQ5fkiFqi1tuvTXc04aRMVr8JSLZPl833cXO98hdHbhiAYivgiUDXUA6EcDZZwKqLKEMWq4zVsnPDwmN53orht3K-j0lxP8kJy_zkQuCpUtoeWQQVD4_KfxXMItVHd5FzwoxnkAQBuX8kFfX_XUoycL1LMgDJqTSWsdNctfcoo7JG_1aZbW9ey7QuNf89xAa_NkEl8V3t9EFTvYQiuNsofbNnppzvufQBz3cQOIUfcy72c8dPgJcmbctpA3F7rK-NbL5OL73vu0ZyaXGHYQ2PRz22bPK4r7L2u4NRwDtuygTuu63bgJ5s0UAkVFlAGouZgzrhwEaaINF1ZYm3sk5DpOIqZZyqlmzKUpt04nJBHawRMR-SLM0V1UHQwHdg_hOFGOGRdxyyGfMVoIaywQP_H9ESgNa-gYVlvOg2Ei83PuEOqMcoVq6KR0hBwVoho_GV0XLvo08UrY_ekIRgpDTqzkceJ0lBoZcktkRIiTnComKXWAVEZwJ9T-f7M5QKvFlYAoIPEhqmbjqT2CTCNLj_Od9gHbzs0I
link.rule.ids 230,315,783,787,888,2772,27088,27936,27937,57070,57120
linkProvider American Chemical Society
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV3JTsMwELVYDnBhR-xYiGsAx0lsc0OFqkDhAEWCk-V4kQpVCyS98PWMnYRNSHDwKZNo5BnPEtvvIbR_5IiGRHwUKRvrCKIfjZRxKqLKEsao4TZQJ1xdZ5275OI-va9hcvxdGFCigC8VYRP_E12AHD6-iYANVU6i6ZSBo_oyqHXbRF1o8gIZHvTkPIJ4mzYoQl9f9RlIF98y0Dd80JBT2vMVOVHQJhwleToYl_mBfvsB1Pg_dRfQXF1a4pPKFxbRhB0uoZlWw-i2jB5OazYUWNUD3II0qfultzoeOXwDFTTuWaiiK5RlfO5Bc3G3_zLum-IYgz-BzCDInvY9vrj_z4bbo1eINCvorn3Wa3WimlohUlQkJYQ4l3LGlYMlm2nDhRXWBvvEXKdZwjTLOdWMuTzn1umMZEI7eCIS35I5uoqmhqOhXUM4zZRjxiXccqhujBbCGgtlAPFsCZTG62gHJkjWS6OQYdc7hq6jmaF1tNfYQz5XEBu_CZ1VlvoQ8bjYg_EzjByGLKzkaeZ0khsZc0tkQoiTnComKXUQt4zgTqiNv7TZRTOd3lVXds-vLzfRbHVYIIlIuoWmytex3YYapMx3gvO9A0q21Wg
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1bb9MwFLagSMDLYDcxLsVCe003x0ls721qV7VsFASt1D1Zji9St6otTfqyX8-xk1QUTRoPfspJdOTjc4vt70Po9NwRDYn4PFI21hFEPxop41RElSWMUcNtoE74NsoGk-TrNJ3WjaK_CwNKFPClImzie69eGVcjDJCzuwcR8KHK5-hFykjsqRouu7-ayAuNXiDEg76cRxBz0wZJ6O9XfRbSxU4W2sEIDXml_wZ932oUjpPcdzZl3tEP_4A1_r_Kb9FeXWLiy2pN7KNndnGAXnUbZrdDdNurWVHAu-e4C-lSz0pvfbx0-CdU0nhsoZqu0Jbx0IPn4pvZ783MFBcY1hXIzINsb-Zxxv3_NtxfriHiHKFJ_2rcHUQ1xUKkqEhKCHUu5YwrB66bacOFFdYGO8Vcp1nCNMs51Yy5POfW6YxkQjt4IhLfmjl6jFqL5cK-QzjNlGPGJdxyqHKMFsIaC-UA8awJlMYnqA2TJGsXKWTY_Y6h-2hm6AR9aWwiVxXUxmNCV5W1tiIeH3u-WcHIYcjCSp5mTie5kTG3RCaEOMmpYpJSB_HLCO6Eev-UNp_Ryx-9vrwZjq4_oNfVmYEkIulH1CrXG_sJSpEyb4f19wdJqtfi
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Differential+Capacitance+of+Room+Temperature+Ionic+Liquids%3A+The+Role+of+Dispersion+Forces&rft.jtitle=The+journal+of+physical+chemistry+letters&rft.au=Trulsson%2C+Martin&rft.au=Algotsson%2C+Jenny&rft.au=Forsman%2C+Jan&rft.au=Woodward%2C+Clifford+E&rft.date=2010-04-15&rft.pub=American+Chemical+Society&rft.issn=1948-7185&rft.eissn=1948-7185&rft.volume=1&rft.issue=8&rft.spage=1191&rft.epage=1195&rft_id=info:doi/10.1021%2Fjz900412t&rft.externalDocID=c829987640
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1948-7185&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1948-7185&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1948-7185&client=summon