Sequence and Stacking Dependence of 8-Oxoguanine Oxidation: Comparison of One-Electron vs Singlet Oxygen Mechanisms
The oxidation of 7,8-dihydro-8-oxoguanine (8-oxoG)-containing oligodeoxynucleotides has been investigated using a variety of oxidants, including one-electron oxidants (Ir(IV), Fe(III), NiCR/KHSO5, and SO4 -•) as well as singlet oxygen, generated both photochemically and thermally. The extents of oxi...
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Published in | Journal of the American Chemical Society Vol. 121; no. 40; pp. 9423 - 9428 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
13.10.1999
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Subjects | |
Online Access | Get full text |
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