Mechanics, Ionics, and Optics of Metal–Organic Framework and Coordination Polymer Glasses

• Published in: Nano letters Vol. 21; no. 15; pp. 6382 - 6390
• Main Authors: Horike, Satoshi, Ma, Nattapol, Fan, Zeyu, Kosasang, Soracha, Smedskjaer, Morten M
• Format: Journal Article
• Language: English
• Published: American Chemical Society 11.08.2021
• Subjects: coordination polymers; ion conductivity; metal−organic frameworks; mechanical properties; Glass

Melt and glassy states of coordination polymers (CPs)/metal–organic frameworks (MOFs) have gained attention as a new class of amorphous materials. Many bridging ligands such as azolate, nitrile, thiocyanide, thiolate, pyridine, sulfonate, and amide are available to construct crystals with melting te...