Doping-Induced Anisotropic Self-Assembly of Silver Icosahedra in [Pt2Ag23Cl7(PPh3)10] Nanoclusters

Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled dop...

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Published inJournal of the American Chemical Society Vol. 139; no. 3; pp. 1053 - 1056
Main Authors Bootharaju, Megalamane S, Kozlov, Sergey M, Cao, Zhen, Harb, Moussab, Maity, Niladri, Shkurenko, Aleksander, Parida, Manas R, Hedhili, Mohamed N, Eddaoudi, Mohamed, Mohammed, Omar F, Bakr, Osman M, Cavallo, Luigi, Basset, Jean-Marie
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 25.01.2017
Subjects
chlorides
crystal structure
ligands
nanoparticles
optical properties
silver
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Abstract Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled doping strategy, we synthesized and characterized a rod-shaped, charge-neutral, diplatinum-doped Ag nanocluster (NC) of [Pt2Ag23Cl7(PPh3)10]. Its crystal structure revealed the self-assembly of two Pt-centered Ag icosahedra through vertex sharing. Five bridging and two terminal chlorides and 10 PPh3 ligands were found to stabilize the cluster. Electronic structure simulations corroborated structural and optical characterization of the cluster and provided insights into the effect of the Pt dopants on the optical properties and stability of the cluster. Our study will open new avenues for designing novel self-assembled NCs using different elemental dopants.
AbstractList Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled doping strategy, we synthesized and characterized a rod-shaped, charge-neutral, diplatinum-doped Ag nanocluster (NC) of [Pt Ag Cl (PPh ) ]. Its crystal structure revealed the self-assembly of two Pt-centered Ag icosahedra through vertex sharing. Five bridging and two terminal chlorides and 10 PPh ligands were found to stabilize the cluster. Electronic structure simulations corroborated structural and optical characterization of the cluster and provided insights into the effect of the Pt dopants on the optical properties and stability of the cluster. Our study will open new avenues for designing novel self-assembled NCs using different elemental dopants.
Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled doping strategy, we synthesized and characterized a rod-shaped, charge-neutral, diplatinum-doped Ag nanocluster (NC) of [Pt₂Ag₂₃Cl₇(PPh₃)₁₀]. Its crystal structure revealed the self-assembly of two Pt-centered Ag icosahedra through vertex sharing. Five bridging and two terminal chlorides and 10 PPh₃ ligands were found to stabilize the cluster. Electronic structure simulations corroborated structural and optical characterization of the cluster and provided insights into the effect of the Pt dopants on the optical properties and stability of the cluster. Our study will open new avenues for designing novel self-assembled NCs using different elemental dopants.
Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled doping strategy, we synthesized and characterized a rod-shaped, charge-neutral, diplatinum-doped Ag nanocluster (NC) of [Pt2Ag23Cl7(PPh3)10]. Its crystal structure revealed the self-assembly of two Pt-centered Ag icosahedra through vertex sharing. Five bridging and two terminal chlorides and 10 PPh3 ligands were found to stabilize the cluster. Electronic structure simulations corroborated structural and optical characterization of the cluster and provided insights into the effect of the Pt dopants on the optical properties and stability of the cluster. Our study will open new avenues for designing novel self-assembled NCs using different elemental dopants.
Author Harb, Moussab
Parida, Manas R
Cavallo, Luigi
Shkurenko, Aleksander
Eddaoudi, Mohamed
Kozlov, Sergey M
Basset, Jean-Marie
Bakr, Osman M
Cao, Zhen
Hedhili, Mohamed N
Mohammed, Omar F
Bootharaju, Megalamane S
Maity, Niladri
AuthorAffiliation Imaging and Characterization Laboratory
KAUST Catalysis Center
KAUST Solar Center
Functional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center
AuthorAffiliation_xml – name: KAUST Catalysis Center
– name: Imaging and Characterization Laboratory
– name: KAUST Solar Center
– name: Functional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/28064484$$D View this record in MEDLINE/PubMed
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Snippet Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the...
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SubjectTerms chlorides
crystal structure
ligands
nanoparticles
optical properties
silver
Title Doping-Induced Anisotropic Self-Assembly of Silver Icosahedra in [Pt2Ag23Cl7(PPh3)10] Nanoclusters
URI http://dx.doi.org/10.1021/jacs.6b11875
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