Doping-Induced Anisotropic Self-Assembly of Silver Icosahedra in [Pt2Ag23Cl7(PPh3)10] Nanoclusters
Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled dop...
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Published in | Journal of the American Chemical Society Vol. 139; no. 3; pp. 1053 - 1056 |
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Main Authors | , , , , , , , , , , , , |
Format | Journal Article |
Language | English |
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American Chemical Society
25.01.2017
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Abstract | Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled doping strategy, we synthesized and characterized a rod-shaped, charge-neutral, diplatinum-doped Ag nanocluster (NC) of [Pt2Ag23Cl7(PPh3)10]. Its crystal structure revealed the self-assembly of two Pt-centered Ag icosahedra through vertex sharing. Five bridging and two terminal chlorides and 10 PPh3 ligands were found to stabilize the cluster. Electronic structure simulations corroborated structural and optical characterization of the cluster and provided insights into the effect of the Pt dopants on the optical properties and stability of the cluster. Our study will open new avenues for designing novel self-assembled NCs using different elemental dopants. |
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AbstractList | Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled doping strategy, we synthesized and characterized a rod-shaped, charge-neutral, diplatinum-doped Ag nanocluster (NC) of [Pt
Ag
Cl
(PPh
)
]. Its crystal structure revealed the self-assembly of two Pt-centered Ag icosahedra through vertex sharing. Five bridging and two terminal chlorides and 10 PPh
ligands were found to stabilize the cluster. Electronic structure simulations corroborated structural and optical characterization of the cluster and provided insights into the effect of the Pt dopants on the optical properties and stability of the cluster. Our study will open new avenues for designing novel self-assembled NCs using different elemental dopants. Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled doping strategy, we synthesized and characterized a rod-shaped, charge-neutral, diplatinum-doped Ag nanocluster (NC) of [Pt₂Ag₂₃Cl₇(PPh₃)₁₀]. Its crystal structure revealed the self-assembly of two Pt-centered Ag icosahedra through vertex sharing. Five bridging and two terminal chlorides and 10 PPh₃ ligands were found to stabilize the cluster. Electronic structure simulations corroborated structural and optical characterization of the cluster and provided insights into the effect of the Pt dopants on the optical properties and stability of the cluster. Our study will open new avenues for designing novel self-assembled NCs using different elemental dopants. Atomically precise self-assembled architectures of noble metals with unique surface structures are necessary for prospective applications. However, the synthesis of such structures based on silver is challenging because of their instability. In this work, by developing a selective and controlled doping strategy, we synthesized and characterized a rod-shaped, charge-neutral, diplatinum-doped Ag nanocluster (NC) of [Pt2Ag23Cl7(PPh3)10]. Its crystal structure revealed the self-assembly of two Pt-centered Ag icosahedra through vertex sharing. Five bridging and two terminal chlorides and 10 PPh3 ligands were found to stabilize the cluster. Electronic structure simulations corroborated structural and optical characterization of the cluster and provided insights into the effect of the Pt dopants on the optical properties and stability of the cluster. Our study will open new avenues for designing novel self-assembled NCs using different elemental dopants. |
Author | Harb, Moussab Parida, Manas R Cavallo, Luigi Shkurenko, Aleksander Eddaoudi, Mohamed Kozlov, Sergey M Basset, Jean-Marie Bakr, Osman M Cao, Zhen Hedhili, Mohamed N Mohammed, Omar F Bootharaju, Megalamane S Maity, Niladri |
AuthorAffiliation | Imaging and Characterization Laboratory KAUST Catalysis Center KAUST Solar Center Functional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center |
AuthorAffiliation_xml | – name: KAUST Catalysis Center – name: Imaging and Characterization Laboratory – name: KAUST Solar Center – name: Functional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center |
Author_xml | – sequence: 1 givenname: Megalamane S surname: Bootharaju fullname: Bootharaju, Megalamane S – sequence: 2 givenname: Sergey M surname: Kozlov fullname: Kozlov, Sergey M – sequence: 3 givenname: Zhen surname: Cao fullname: Cao, Zhen – sequence: 4 givenname: Moussab orcidid: 0000-0001-5540-9792 surname: Harb fullname: Harb, Moussab – sequence: 5 givenname: Niladri surname: Maity fullname: Maity, Niladri – sequence: 6 givenname: Aleksander surname: Shkurenko fullname: Shkurenko, Aleksander – sequence: 7 givenname: Manas R surname: Parida fullname: Parida, Manas R – sequence: 8 givenname: Mohamed N surname: Hedhili fullname: Hedhili, Mohamed N – sequence: 9 givenname: Mohamed surname: Eddaoudi fullname: Eddaoudi, Mohamed – sequence: 10 givenname: Omar F orcidid: 0000-0001-8500-1130 surname: Mohammed fullname: Mohammed, Omar F – sequence: 11 givenname: Osman M orcidid: 0000-0002-3428-1002 surname: Bakr fullname: Bakr, Osman M email: osman.bakr@kaust.edu.sa – sequence: 12 givenname: Luigi orcidid: 0000-0002-1398-338X surname: Cavallo fullname: Cavallo, Luigi email: luigi.cavallo@kaust.edu.sa – sequence: 13 givenname: Jean-Marie orcidid: 0000-0003-3166-8882 surname: Basset fullname: Basset, Jean-Marie email: jeanmarie.basset@kaust.edu.sa |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28064484$$D View this record in MEDLINE/PubMed |
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SubjectTerms | chlorides crystal structure ligands nanoparticles optical properties silver |
Title | Doping-Induced Anisotropic Self-Assembly of Silver Icosahedra in [Pt2Ag23Cl7(PPh3)10] Nanoclusters |
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