Self-Sorting of Amphiphilic Copolymers for Self-Assembled Materials in Water: Polymers Can Recognize Themselves

Amphiphilic random copolymers bearing hydrophilic poly­(ethylene glycol) (PEG) and hydrophobic alkyl pendants showed dynamic self-sorting behavior, that is, self-recognition, under competitive conditions in aqueous media. The self-sorting universally takes place not only in water but also in hydroge...

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Published inJournal of the American Chemical Society Vol. 141; no. 1; pp. 511 - 519
Main Authors Imai, Shota, Takenaka, Mikihito, Sawamoto, Mitsuo, Terashima, Takaya
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 09.01.2019
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Abstract Amphiphilic random copolymers bearing hydrophilic poly­(ethylene glycol) (PEG) and hydrophobic alkyl pendants showed dynamic self-sorting behavior, that is, self-recognition, under competitive conditions in aqueous media. The self-sorting universally takes place not only in water but also in hydrogels and on the material surfaces, according to encoded information originating from the primary structure of composition and pendants. Binary blends of the copolymers with different composition or alkyl pendants readily induced composition- or alkyl pendant-dependent self-sorting to simultaneously provide discrete and size-controlled micelles with hydrophobic cores. Surprisingly, the micelles reversibly keep exchanging polymer chains exclusively between identical polymer micelles even in the presence of different counterparts. Owing to the dynamic self-sorting behavior, ABA-triblock copolymers comprising the amphiphilic random copolymer A segments and a hydrophilic PEG chain B segment further provided hydrogels with self-healing yet selectively adhesive properties.
AbstractList Amphiphilic random copolymers bearing hydrophilic poly(ethylene glycol) (PEG) and hydrophobic alkyl pendants showed dynamic self-sorting behavior, that is, self-recognition, under competitive conditions in aqueous media. The self-sorting universally takes place not only in water but also in hydrogels and on the material surfaces, according to encoded information originating from the primary structure of composition and pendants. Binary blends of the copolymers with different composition or alkyl pendants readily induced composition- or alkyl pendant-dependent self-sorting to simultaneously provide discrete and size-controlled micelles with hydrophobic cores. Surprisingly, the micelles reversibly keep exchanging polymer chains exclusively between identical polymer micelles even in the presence of different counterparts. Owing to the dynamic self-sorting behavior, ABA-triblock copolymers comprising the amphiphilic random copolymer A segments and a hydrophilic PEG chain B segment further provided hydrogels with self-healing yet selectively adhesive properties.
Amphiphilic random copolymers bearing hydrophilic poly­(ethylene glycol) (PEG) and hydrophobic alkyl pendants showed dynamic self-sorting behavior, that is, self-recognition, under competitive conditions in aqueous media. The self-sorting universally takes place not only in water but also in hydrogels and on the material surfaces, according to encoded information originating from the primary structure of composition and pendants. Binary blends of the copolymers with different composition or alkyl pendants readily induced composition- or alkyl pendant-dependent self-sorting to simultaneously provide discrete and size-controlled micelles with hydrophobic cores. Surprisingly, the micelles reversibly keep exchanging polymer chains exclusively between identical polymer micelles even in the presence of different counterparts. Owing to the dynamic self-sorting behavior, ABA-triblock copolymers comprising the amphiphilic random copolymer A segments and a hydrophilic PEG chain B segment further provided hydrogels with self-healing yet selectively adhesive properties.
Author Takenaka, Mikihito
Imai, Shota
Sawamoto, Mitsuo
Terashima, Takaya
AuthorAffiliation Institute of Science and Technology Research
Department of Polymer Chemistry, Graduate School of Engineering
RIKEN SPring-8 Center
Chubu University
Institute for Chemical Research
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/30507172$$D View this record in MEDLINE/PubMed
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Snippet Amphiphilic random copolymers bearing hydrophilic poly­(ethylene glycol) (PEG) and hydrophobic alkyl pendants showed dynamic self-sorting behavior, that is,...
Amphiphilic random copolymers bearing hydrophilic poly(ethylene glycol) (PEG) and hydrophobic alkyl pendants showed dynamic self-sorting behavior, that is,...
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Title Self-Sorting of Amphiphilic Copolymers for Self-Assembled Materials in Water: Polymers Can Recognize Themselves
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