Gas-Phase Hydrodesulfurization of JP-8 Light Fraction Using Steam Reformate
Gas-phase hydrodesulfurization of a JP-8 light fraction was investigated over CoMo/Al2O3 and NiMo/Al2O3 catalysts. Use of a light fraction provides a fuel that is more easily desulfurized and allows the process to operate in the vapor phase. This study investigated the utilization of reformate (syng...
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| Published in | Industrial & engineering chemistry research Vol. 45; no. 21; pp. 7050 - 7056 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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Washington, DC
American Chemical Society
11.10.2006
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| Abstract | Gas-phase hydrodesulfurization of a JP-8 light fraction was investigated over CoMo/Al2O3 and NiMo/Al2O3 catalysts. Use of a light fraction provides a fuel that is more easily desulfurized and allows the process to operate in the vapor phase. This study investigated the utilization of reformate (syngas) from a steam reformer rather than pure H2 as gas feed to HDS unit. This is consistent with what might be available to the military during operation in the field. Dry syngas functions almost as well as pure H2 in the HDS reaction, and sulfur levels below 5 ppmw are readily obtained from a feed initially containing 320 ppmw sulfur. Addition of 40 vol % steam to the syngas has a significant negative impact on HDS performance with CoMo/Al2O3, but only a small effect with NiMo/Al2O3. The impacts of various process conditions on S removal efficiency were examined and will be described. |
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| AbstractList | Gas-phase hydrodesulfurization of a JP-8 light fraction was investigated over CoMo/Al2O3 and NiMo/Al2O3 catalysts. Use of a light fraction provides a fuel that is more easily desulfurized and allows the process to operate in the vapor phase. This study investigated the utilization of reformate (syngas) from a steam reformer rather than pure H2 as gas feed to HDS unit. This is consistent with what might be available to the military during operation in the field. Dry syngas functions almost as well as pure H2 in the HDS reaction, and sulfur levels below 5 ppmw are readily obtained from a feed initially containing 320 ppmw sulfur. Addition of 40 vol % steam to the syngas has a significant negative impact on HDS performance with CoMo/Al2O3, but only a small effect with NiMo/Al2O3. The impacts of various process conditions on S removal efficiency were examined and will be described. |
| Author | Huang, Xiwen King, David L |
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| Cites_doi | 10.1021/ef049804g 10.1016/S0926-3373(02)00212-6 10.1016/S0360-3199(00)00092-6 10.1016/S0920-5861(00)00308-4 10.1016/j.cattod.2004.07.048 10.1016/j.jpowsour.2004.03.009 10.1021/ie00023a013 10.1002/chem.200500858 10.1016/S0016-2361(02)00324-1 10.1081/CR-200032697 10.1016/S0016-2361(96)00238-4 10.1021/ie020995p 10.1016/j.fuel.2003.10.001 10.1016/S0378-7753(01)01021-7 10.1021/ie00057a001 10.1016/S0167-2738(00)00653-6 10.1016/j.jpowsour.2005.03.209 10.2514/2.5765 10.1016/0021-9517(83)90230-0 10.1021/ef0300747 10.1021/ie960137r 10.1039/b108411a 10.1021/ef000096i 10.1021/ef049800b |
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| References | Babich I. (ie0607301b00021/ie0607301b00021_1) 2003; 82 Li Z. (ie0607301b00014/ie0607301b00014_1) 2005 Velu S. (ie0607301b00013/ie0607301b00013_1) 2005; 19 Link D. (ie0607301b00017/ie0607301b00017_1) 2003; 17 Kim J. (ie0607301b00022/ie0607301b00022_1) 2005; 19 ie0607301b00016/ie0607301b00016_1 Ishikuro K (ie0607301b00027/ie0607301b00027_1) 1997 Girgis M. (ie0607301b00024/ie0607301b00024_1) 1991; 30 Ma X. (ie0607301b00019/ie0607301b00019_1) 1997; 76 Cheekatamarla P. (ie0607301b00002/ie0607301b00002_1) 2005; 152 Bosmann (ie0607301b00012/ie0607301b00012_1) 2001 Matsuzaki Y. (ie0607301b00005/ie0607301b00005_1) 2000; 132 Ho T (ie0607301b00023/ie0607301b00023_1) 2004; 98 Odebunmi E. (ie0607301b00026/ie0607301b00026_1) 1983; 80 Laurent E. (ie0607301b00025/ie0607301b00025_1) 1993; 32 Yang R (ie0607301b00009/ie0607301b00009_1) 2004; 46 Edwards T. (ie0607301b00015/ie0607301b00015_1) 2001; 17 Shafi R. (ie0607301b00020/ie0607301b00020_1) 2000; 59 Chica A. (ie0607301b00011/ie0607301b00011_1) 2006; 12 Topsøe H. (ie0607301b00007/ie0607301b00007_1) 1996; 11 Gorte R. (ie0607301b00006/ie0607301b00006_1) 2002; 106 Darwish N. (ie0607301b00004/ie0607301b00004_1) 2004; 83 Otsuki S. (ie0607301b00010/ie0607301b00010_1) 2000; 14 Velu S. (ie0607301b00008/ie0607301b00008_1) 2003; 42 Patil A. (ie0607301b00001/ie0607301b00001_1) 2004; 136 Brown L (ie0607301b00003/ie0607301b00003_1) 2001; 26 Ma X. (ie0607301b00018/ie0607301b00018_1) 1996; 35 |
| References_xml | – volume: 11 start-page: 310 volume-title: Catalysis: Science and Technology year: 1996 ident: ie0607301b00007/ie0607301b00007_1 – volume: 19 start-page: 353 year: 2005 ident: ie0607301b00022/ie0607301b00022_1 publication-title: Energy Fuel doi: 10.1021/ef049804g – volume-title: Fuel Cell Seminar year: 2005 ident: ie0607301b00014/ie0607301b00014_1 – ident: ie0607301b00016/ie0607301b00016_1 doi: 10.1016/S0926-3373(02)00212-6 – volume: 26 start-page: 381 issue: 4 year: 2001 ident: ie0607301b00003/ie0607301b00003_1 publication-title: Int. J. Hydrogen Energy doi: 10.1016/S0360-3199(00)00092-6 – volume: 59 start-page: 423 year: 2000 ident: ie0607301b00020/ie0607301b00020_1 publication-title: Catal. Today doi: 10.1016/S0920-5861(00)00308-4 – volume: 98 start-page: 3 year: 2004 ident: ie0607301b00023/ie0607301b00023_1 publication-title: Catal. Today doi: 10.1016/j.cattod.2004.07.048 – volume: 136 start-page: 220 year: 2004 ident: ie0607301b00001/ie0607301b00001_1 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2004.03.009 – volume: 32 start-page: 2516 year: 1993 ident: ie0607301b00025/ie0607301b00025_1 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie00023a013 – volume: 12 start-page: 1960 year: 2006 ident: ie0607301b00011/ie0607301b00011_1 publication-title: Chem. Eur. J. doi: 10.1002/chem.200500858 – volume: 82 start-page: 607 year: 2003 ident: ie0607301b00021/ie0607301b00021_1 publication-title: Fuel doi: 10.1016/S0016-2361(02)00324-1 – volume: 46 start-page: 111 issue: 2 year: 2004 ident: ie0607301b00009/ie0607301b00009_1 publication-title: Catal. Rev. doi: 10.1081/CR-200032697 – volume: 76 start-page: 329 year: 1997 ident: ie0607301b00019/ie0607301b00019_1 publication-title: Fuel doi: 10.1016/S0016-2361(96)00238-4 – volume: 42 start-page: 5293 year: 2003 ident: ie0607301b00008/ie0607301b00008_1 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie020995p – volume: 83 start-page: 409 year: 2004 ident: ie0607301b00004/ie0607301b00004_1 publication-title: Fuel doi: 10.1016/j.fuel.2003.10.001 – volume: 106 start-page: 10 year: 2002 ident: ie0607301b00006/ie0607301b00006_1 publication-title: J. Power Sources doi: 10.1016/S0378-7753(01)01021-7 – start-page: 119 year: 1997 ident: ie0607301b00027/ie0607301b00027_1 publication-title: Fuel Energy Abstr. – volume: 30 start-page: 2021 issue: 9 year: 1991 ident: ie0607301b00024/ie0607301b00024_1 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie00057a001 – volume: 132 start-page: 261 year: 2000 ident: ie0607301b00005/ie0607301b00005_1 publication-title: Solid State Ionics doi: 10.1016/S0167-2738(00)00653-6 – volume: 152 start-page: 256 year: 2005 ident: ie0607301b00002/ie0607301b00002_1 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2005.03.209 – volume: 17 start-page: 461 issue: 2 year: 2001 ident: ie0607301b00015/ie0607301b00015_1 publication-title: J. Propul. Power doi: 10.2514/2.5765 – volume: 80 start-page: 65 year: 1983 ident: ie0607301b00026/ie0607301b00026_1 publication-title: J. Catal. doi: 10.1016/0021-9517(83)90230-0 – volume: 17 start-page: 1292 year: 2003 ident: ie0607301b00017/ie0607301b00017_1 publication-title: Energy Fuels doi: 10.1021/ef0300747 – volume: 35 start-page: 2487 year: 1996 ident: ie0607301b00018/ie0607301b00018_1 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie960137r – start-page: 2494 year: 2001 ident: ie0607301b00012/ie0607301b00012_1 publication-title: Chem. Commun. doi: 10.1039/b108411a – volume: 14 start-page: 1232 year: 2000 ident: ie0607301b00010/ie0607301b00010_1 publication-title: Energy Fuels doi: 10.1021/ef000096i – volume: 19 start-page: 1116 year: 2005 ident: ie0607301b00013/ie0607301b00013_1 publication-title: Energy and Fuels doi: 10.1021/ef049800b |
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| Title | Gas-Phase Hydrodesulfurization of JP-8 Light Fraction Using Steam Reformate |
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