Synthesis of Yellow-Emitting Platinum Nanoclusters by Ligand Etching

New types of fluorescent platinum nanoclusters (λmax.= 570 nm) have been synthesized using glutathione for ligand etching. These nanoclusters are mainly in the oxidation state PtI (90%) exhibiting an intense fluorescence signal (QY∼17%) in the yellow region and lead to the formation of blue-emitting...

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Published inJournal of physical chemistry. C Vol. 116; no. 10; pp. 6047 - 6051
Main Authors Le Guével, Xavier, Trouillet, Vanessa, Spies, Christian, Jung, Gregor, Schneider, Marc
Format Journal Article
LanguageEnglish
Published Columbus, OH American Chemical Society 15.03.2012
Subjects
Chemical Sciences
Cross-disciplinary physics: materials science; rheology
Engineering Sciences
Exact sciences and technology
Material chemistry
Materials science
Methods of nanofabrication
Optics
Photonic
Physics
Nanocluster
Solid clusters
Valence
Fluorescent material
Platinum
Fluorescence
Ligands
Etching
Nanomaterial synthesis
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Abstract New types of fluorescent platinum nanoclusters (λmax.= 570 nm) have been synthesized using glutathione for ligand etching. These nanoclusters are mainly in the oxidation state PtI (90%) exhibiting an intense fluorescence signal (QY∼17%) in the yellow region and lead to the formation of blue-emitting species for a long etching time process.
AbstractList New types of fluorescent platinum nanoclusters (λmax.= 570 nm) have been synthesized using glutathione for ligand etching. These nanoclusters are mainly in the oxidation state PtI (90%) exhibiting an intense fluorescence signal (QY∼17%) in the yellow region and lead to the formation of blue-emitting species for a long etching time process.
Author Le Guével, Xavier
Spies, Christian
Trouillet, Vanessa
Jung, Gregor
Schneider, Marc
AuthorAffiliation KIT-Campus North
Saarland University
AuthorAffiliation_xml – name: KIT-Campus North
– name: Saarland University
Author_xml – sequence: 1
  givenname: Xavier
  surname: Le Guével
  fullname: Le Guével, Xavier
– sequence: 2
  givenname: Vanessa
  surname: Trouillet
  fullname: Trouillet, Vanessa
– sequence: 3
  givenname: Christian
  surname: Spies
  fullname: Spies, Christian
– sequence: 4
  givenname: Gregor
  surname: Jung
  fullname: Jung, Gregor
– sequence: 5
  givenname: Marc
  surname: Schneider
  fullname: Schneider, Marc
  email: Marc.Schneider@mx.uni-saarland.de
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2014 INIST-CNRS
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Issue 10
Keywords Nanocluster
Solid clusters
Valence
Fluorescent material
Platinum
Fluorescence
Ligands
Etching
Nanomaterial synthesis
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Snippet New types of fluorescent platinum nanoclusters (λmax.= 570 nm) have been synthesized using glutathione for ligand etching. These nanoclusters are mainly in the...
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SubjectTerms Chemical Sciences
Cross-disciplinary physics: materials science; rheology
Engineering Sciences
Exact sciences and technology
Material chemistry
Materials science
Methods of nanofabrication
Optics
Photonic
Physics
Title Synthesis of Yellow-Emitting Platinum Nanoclusters by Ligand Etching
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