Modulation of the Structure and Properties of Uranyl Ion Coordination Polymers Derived from 1,3,5-Benzenetriacetate by Incorporation of Ag(I) or Pb(II)

• Published in: Inorganic chemistry Vol. 55; no. 13; pp. 6799 - 6816
• Main Authors: Thuéry, Pierre, Harrowfield, Jack
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 05.07.2016
• Subjects: Chemical Sciences; Material chemistry

Reaction of uranyl nitrate with 1,3,5-benzenetriacetic acid (H3BTA) in the presence of additional species, either organic bases or their conjugate acids or metal cations, has provided 12 new crystalline complexes, all but one obtained under solvo-hydrothermal conditions. The complexes [C­(NH2)3]­[UO...