Amperometric and fast scan-rate cyclic voltammetry detection at a microelectrode for gel permeation high-performance liquid chromatography of fullerenes
A study utilized amperometry and fast scan-rate cyclic voltammetry (CV) for detection and identification of fullerenes, which were separated by gel permeation high-performance liquid chromatography. The technique allows a rapid and feasible means for electrochemical characterization.
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| Published in | Analytical chemistry (Washington) Vol. 65; no. 6; pp. 669 - 672 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Washington, DC
American Chemical Society
01.03.1993
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| Subjects | |
| Online Access | Get full text |
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| Abstract | A study utilized amperometry and fast scan-rate cyclic voltammetry (CV) for detection and identification of fullerenes, which were separated by gel permeation high-performance liquid chromatography. The technique allows a rapid and feasible means for electrochemical characterization. |
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| AbstractList | Amperometry and fast scan-rate cyclic voltammetry (CV) at a 10-[mu]m-diameter platinum microelectrode were utilized for detection and in situ identification of fullerenes which were separated by gel permeation high-performance liquid chromatography. The microelectrode and inlet capillary nozzle were arranged perpendicularly. The limiting currents were virtually independent of the mobile phase flow rate in the range 0.1--2.0 mL min[sup [minus]1] for a distance between the microelectrode and inlet capillary nozzle [le] 0.10 mm. A toluene extract of the laser-vaporized soot containing low molecular mass fullerenes was resolved on two gel permeation columns which were connected in series. The mobile phase was dichloromethane/cyclohexane, 90/10 (v/v), 0.01 M tetra-n-butylammonium perchlorate. C[sub 60] and C[sub 70] were the major components of the extract and were present in a 3:1 mass ratio. Other higher fullerenes were also present in a 3:1 major concentration. The number and shapes of the peaks in chromatograms obtained with amperometric detection at [minus]1.3 V vs SCE were the same as those obtained with UV-visible spectroscopic detection at 366 nm, thus indicating that all of the detected compounds both absorb UV-visible light and are electrochemically active. Extracolumn peak broadenings due to detection and detectability (83.8 ng for C[sub 60]) were also the same in both detection techniques. In situ fast scan-rate voltammograms of C[sub 60] and C[sub 70] were obtained during elution, and the reversible E[sub 1/2] values of the third and fourth electroreductions could be used for their identification. 40 refs., 4 figs., 1 tab. A study utilized amperometry and fast scan-rate cyclic voltammetry (CV) for detection and identification of fullerenes, which were separated by gel permeation high-performance liquid chromatography. The technique allows a rapid and feasible means for electrochemical characterization. |
| Author | Kutner, Wlodzimierz Soucaze-Guillous, Benoit Kadish, Karl M |
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| CitedBy_id | crossref_primary_10_1021_ac800108j crossref_primary_10_1080_10826079408013619 crossref_primary_10_1016_j_jelechem_2019_113609 crossref_primary_10_1002_bmc_1130090212 crossref_primary_10_1016_0003_2670_94_80100_2 crossref_primary_10_1016_S0003_2670_96_00546_6 crossref_primary_10_1002_elan_200390041 crossref_primary_10_1016_j_aca_2010_12_024 crossref_primary_10_1016_0022_0728_93_80513_H crossref_primary_10_1002_1521_4109_200110_13_14_1185__AID_ELAN1185_3_0_CO_2_0 crossref_primary_10_1002_elan_1140090109 crossref_primary_10_1002_elps_11501501205 crossref_primary_10_1021_jp9814707 |
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| Copyright | 1993 INIST-CNRS Copyright American Chemical Society Mar 15, 1993 |
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| DOI | 10.1021/ac00054a003 |
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| Keywords | Cyclic voltammetry Amperometry HPLC chromatography Microelectrode Fullerenes Atomic cluster Qualitative analysis Gel permeation chromatography Electrochemical detector |
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| Snippet | A study utilized amperometry and fast scan-rate cyclic voltammetry (CV) for detection and identification of fullerenes, which were separated by gel permeation... Amperometry and fast scan-rate cyclic voltammetry (CV) at a 10-[mu]m-diameter platinum microelectrode were utilized for detection and in situ identification of... |
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| SubjectTerms | 360600 - Other Materials 400201 - Chemical & Physicochemical Properties AMPEROMETRY Analytical chemistry Biochemistry CARBON CHEMICAL ANALYSIS Chemistry Chromatographic methods and physical methods associated with chromatography CHROMATOGRAPHY DETECTION ELEMENTS Exact sciences and technology FULLERENES GEL PERMEATION CHROMATOGRAPHY INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LIQUID COLUMN CHROMATOGRAPHY MATERIALS SCIENCE NONMETALS Other chromatographic methods QUANTITATIVE CHEMICAL ANALYSIS Scientific imaging SEPARATION PROCESSES TITRATION VOLTAMETRY |
| Title | Amperometric and fast scan-rate cyclic voltammetry detection at a microelectrode for gel permeation high-performance liquid chromatography of fullerenes |
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