Science and Technology of Rubber (3rd Edition)
This book provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd Edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theo...
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| Main Authors | , |
|---|---|
| Format | eBook |
| Language | English |
| Published |
San Diego
Elsevier
2005
Elsevier Science & Technology Academic Press |
| Edition | 3 |
| Subjects | |
| Online Access | Get full text |
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| Abstract | This book provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd Edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling. Practicing engineers involved with materials science and research, professionals and practitioners in the rubber industry, and professional societies will benefit from this book. |
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| AbstractList | This book provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd Edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling. Practicing engineers involved with materials science and research, professionals and practitioners in the rubber industry, and professional societies will benefit from this book. The 3rd edition of The Science and Technology of Rubber provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Many advances have been made in polymer and elastomers research over the past ten years since the 2nd edition was published. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling. · Explores new applications of rubber within the tire industry, from new filler materials to "green tires" (a tire that has yet to undergo curing and vulcanization).· 30% of the material has been revised from the previous edition with the addition of 20% new material, including a chapter on the environment.· A mixture of theory, experiments, and practical procedures will offer value to students, practitioners, and research & development departments in industry. |
| Author | Erman Burak Eirich Frederick R Mark James E |
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| Copyright | 2005 |
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| Snippet | This book provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd Edition, the emphasis remains... The 3rd edition of The Science and Technology of Rubber provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity.... |
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| SubjectTerms | Materials & Their Applications Plastics & Rubber Rubber |
| TableOfContents | Title Page
Prefaces
Table of Contents
1. Rubber Elasticity: Basic Concepts and Behavior
2. Polymerization: Elastomer Synthesis
3. Structure Characterization in the Science and Technology of Elastomers
4. The Molecular Basis of Rubberlike Elasticity
5. The Viscoelastic Behavior of Rubber
6. Rheological Behavior and Processing of Unvulcanized Rubber
7. Vulcanization
8. Reinforcement of Elastomers by Particulate Fillers
9. The Science of Rubber Compounding
10. Strength of Elastomers
11. The Chemical Modification of Polymers
12. Elastomer Blends
13. Thermoplastic Elastomers
14. Tire Engineering
15. Recycling of Rubbers
Index Cover -- Frontmatter -- Half Title Page -- Title Page -- Copyright -- Contents -- Contributors -- Preface to the Third Edition -- Preface to the Second Edition -- Preface to the First Edition -- 1. Rubber Elasticity: Basic Concepts and Behavior -- I. INTRODUCTION -- II. ELASTICITY OF A SINGLE MOLECULE -- III. ELASTICITY OF A THREE-DIMENSIONAL NETWORK OF POLYMER MOLECULES -- IV. COMPARISON WITH EXPERIMENT -- V. CONTINUUM THEORY OF RUBBER ELASTICITY -- VI. SECOND-ORDER STRESSES -- VII. ELASTIC BEHAVIOR UNDER SMALL DEFORMATIONS -- VIII. SOME UNSOLVED PROBLEMS IN RUBBER ELASTICITY -- ACKNOWLEDGMENTS -- REFERENCES -- 2. Polymerization: Elastomer Synthesis -- I. INTRODUCTION -- II. CLASSIFICATION OF POLYMERIZATION REACTIONS AND KINETIC CONSIDERATIONS -- III. Polyaddition/Polycondensation -- IV. CHAIN POLYMERIZATION BY FREE RADICAL MECHANISM -- V. EMULSION POLYMERIZATION -- VI. COPOLYMERIZATION -- VII. Chain Polymerization by Cationic Mechanism -- VIII. CHAIN POLYMERIZATION BY ANIONIC MECHANISM -- IX. STEREOSPECIFIC CHAIN POLYMERIZATION AND COPOLYMERIZATION BY COORDINATION CATALYSTS -- X. GRAFT AND BLOCK COPOLYMERIZATION -- REFERENCES -- 3. Structure Characterization in the Science and Technology of Elastomers -- I. INTRODUCTION -- II. CHEMICAL COMPOSITION -- III. SEQUENCE DISTRIBUTION OF REPEAT UNITS -- IV. CHAIN ARCHITECTURE -- V. GLASS TRANSITION AND SECONDARY RELAXATION PROCESSES -- VI. MORPHOLOGY -- ACKNOWLEDGMENTS -- REFERENCES -- 4. The Molecular Basis of Rubberlike Elasticity -- I. INTRODUCTION -- II. STRUCTURE OF A TYPICAL NETWORK -- III. ELEMENTARY MOLECULAR THEORIES -- IV. MORE ADVANCED MOLECULAR THEORIES -- V. PHENOMENOLOGICAL THEORIES AND MOLECULAR STRUCTURE -- VI. SWELLING OF NETWORKS AND RESPONSIVE GELS -- VII. ENTHALPIC AND ENTROPIC CONTRIBUTIONS TO RUBBER ELASTICITY: FORCE-TEMPERATURE RELATIONS IV. STABILIZER SYSTEMS -- V. VULCANIZATION SYSTEM -- VI. SPECIAL COMPOUNDING INGREDIENTS -- VII. COMPOUND DEVELOPMENT -- VIII. COMPOUND PREPARATION -- IX. ENVIRONMENTAL REQUIREMENTS IN COMPOUNDING -- X. SUMMARY -- REFERENCES -- 10. Strength of Elastomers -- I. INTRODUCTION -- II. INITIATION OF FRACTURE -- III. THRESHOLD STRENGTHS AND EXTENSIBILITIES -- IV. FRACTURE UNDER MULTIAXIAL STRESSES -- V. CRACK PROPAGATION -- VI. TENSILE RUPTURE -- VII. REPEATED STRESSING: MECHANICAL FATIGUE -- VIII. SURFACE CRACKING BY OZONE -- IX. ABRASIVE WEAR -- ACKNOWLEDGMENTS -- REFERENCES -- 11. The Chemical Modification of Polymers -- I. INTRODUCTION -- II. CHEMICAL MODIFICATION OF POLYMERS WITHIN BACKBONE AND CHAIN ENDS -- III. ESTERIFICATION, ETHERIFICATION, AND HYDROLYSIS OF POLYMERS -- IV. THE HYDROGENATION OF POLYMERS -- V. DEHALOGENATION, ELIMINATION, AND HALOGENATION REACTIONS IN POLYMERS -- VI. OTHER ADDITION REACTIONS TO DOUBLE BONDS -- VII. OXIDATION REACTIONS OF POLYMERS -- VIII. FUNCTIONALIZATION OF POLYMERS -- IX. MISCELLANEOUS CHEMICAL REACTIONS OF POLYMERS -- X. BLOCK AND GRAFT COPOLYMERIZATION -- REFERENCES -- 12. Elastomer Blends -- I. INTRODUCTION -- II. MISCIBLE ELASTOMER BLENDS -- III. IMMISCIBLE ELASTOMER BLENDS -- IV. CONCLUSION -- V. APPENDIX 1: ACRONYMS FOR COMMON ELASTOMERS -- REFERENCES -- 13. Thermoplastic Elastomers -- I. INTRODUCTION -- II. SYNTHESIS OF THERMOPLASTIC ELASTOMERS -- III. MORPHOLOGY OF THERMOPLASTIC ELASTOMERS -- IV. PROPERTIES AND EFFECT OF STRUCTURE -- V. THERMODYNAMICS OF PHASE SEPARATION -- VI. THERMOPLASTIC ELASTOMERS AT SURFACES -- VII. RHEOLOGY AND PROCESSING -- VIII. APPLICATIONS -- REFERENCES -- 14. Tire Engineering -- I. INTRODUCTION -- II. TIRE TYPES AND PERFORMANCE -- III. BASIC TIRE DESIGN -- IV. TIRE ENGINEERING -- V. TIRE MATERIALS -- VI. TIRE TESTING -- VII. TIRE MANUFACTURING -- VIII. SUMMARY -- REFERENCES VIII. DIRECT DETERMINATION OF MOLECULAR DIMENSIONS -- IX. SINGLE-MOLECULE ELASTICITY -- REFERENCES -- 5. The Viscoelastic Behavior of Rubber -- I. INTRODUCTION -- II. DEFINITIONS OF MEASURED QUANTITIES, J(t), G(t), AND G*(ω), AND SPECTRA L(log λ) AND H(log τ) -- III. THE GLASS TEMPERATURE -- IV. VOLUME CHANGES DURING CURING -- V. VISCOELASTIC BEHAVIOR ABOVE Tg -- VI. VISCOELASTIC BEHAVIOR OF OTHER MODEL ELASTOMERS -- VII. THE CALCULATION OF THE TEAR ENERGY OF ELASTOMERS FROM THEIR VISCOELASTIC BEHAVIOR -- VIII. THEORETICAL INTERPRETATION OF VISCOELASTIC MECHANISMS AND ANOMALIES -- IX. APPENDIX: NOMENCLATURE -- REFERENCES -- 6. Rheological Behavior and Processing of Unvulcanized Rubber -- I. INTRODUCTION -- II. BASIC CONCEPTS OF MECHANICS -- III. RHEOLOGICAL PROPERTIES -- IV. BOUNDARY CONDITIONS -- V. MECHANOCHEMICAL BEHAVIOR -- VI. RHEOLOGICAL MEASUREMENTS -- VII. PROCESSING TECHNOLOGY -- VIII. ENGINEERING ANALYSIS OF PROCESSING -- REFERENCES -- 7. Vulcanization -- I. INTRODUCTION -- II. DEFINITION OF VULCANIZATION -- III. EFFECTS OF VULCANIZATION ON VULCANIZATE PROPERTIES -- IV. CHARACTERIZATION OF THE VULCANIZATION PROCESS -- V. VULCANIZATION BY SULFUR WITHOUT ACCELERATOR -- VI. ACCELERATED-SULFUR VULCANIZATION -- VII. VULCANIZATION BY PHENOLIC CURATIVES, BENZOQUINONE DERIVATIVES, OR BISMALEIMIDES -- VIII. VULCANIZATION BY THE ACTION OF METAL OXIDES -- IX. VULCANIZATION BY THE ACTION OF ORGANIC PEROXIDES -- X. DYNAMIC VULCANIZATION -- REFERENCES -- 8. Reinforcement of Elastomers by Particulate Fillers -- I. INTRODUCTION -- II. PREPARATION OF FILLERS -- III. MORPHOLOGICAL AND PHYSICOCHEMICAL CHARACTERIZATION OF FILLERS -- IV. THE MIX: A NANOCOMPOSITE OF ELASTOMER AND FILLER -- V. MECHANICAL PROPERTIES OF FILLED RUBBERS -- REFERENCES -- 9. The Science of Rubber Compounding -- I. INTRODUCTION -- II. POLYMERS -- III. FILLER SYSTEMS 15. Recycling of Rubbers -- I. INTRODUCTION -- II. RETREADING OF TIRE -- III. RECYCLING OF RUBBER VULCANIZATES -- IV. USE OF RECYCLED RUBBER -- V. PYROLYSIS AND INCINERATION OF RUBBER -- VI. CONCLUDING REMARKS -- ACKNOWLEDGMENTS -- REFERENCES -- Index |
| Title | Science and Technology of Rubber (3rd Edition) |
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