Latent methane in fossil coals
It is established experimentally using 1H NMR wide line spectroscopy that methane can exist in coals not only in open or closed porosity and fracture systems but also in solid solutions in coal substance, in particular, under methane pressure 2 MPa or higher. Methane dissolved in coal minerals rever...
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| Published in | Fuel (Guildford) Vol. 83; no. 10; pp. 1407 - 1411 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Oxford
Elsevier Ltd
01.07.2004
Elsevier |
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| Abstract | It is established experimentally using
1H NMR wide line spectroscopy that methane can exist in coals not only in open or closed porosity and fracture systems but also in solid solutions in coal substance, in particular, under methane pressure 2 MPa or higher. Methane dissolved in coal minerals reversibly modifies their lattice parameters as determined from X-ray diffraction analysis. Co-existence of these methane forms in fossil coals causes multi-step desorption kinetics. It is shown experimentally that the long-term latent methane desorption is effected mainly by closed porosity, which in turn is determined by coal rank. |
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| AbstractList | It is established experimentally using (super 1)H NMR wide line spectroscopy that methane can exist in coals not only in open or closed porosity and fracture systems but also in solid solutions in coal substance, in particular, under methane pressure 2 MPa or higher. Methane dissolved in coal minerals reversibly modifies their lattice parameters as determined from X-ray diffraction analysis. Co-existence of these methane forms in fossil coals causes multi-step desorption kinetics. It is shown experimentally that the long-term latent methane desorption is effected mainly by closed porosity, which in turn is determined by coal rank. It is established experimentally using 1H NMR wide line spectroscopy that methane can exist in coals not only in open or closed porosity and fracture systems but also in solid solutions in coal substance, in particular, under methane pressure 2 MPa or higher. Methane dissolved in coal minerals reversibly modifies their lattice parameters as determined from X-ray diffraction analysis. Co-existence of these methane forms in fossil coals causes multi-step desorption kinetics. It is shown experimentally that the long-term latent methane desorption is effected mainly by closed porosity, which in turn is determined by coal rank. |
| Author | Kovriga, N.N Starikov, G.P Ulyanova, E.V Alexeev, A.D |
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| Cites_doi | 10.1016/0016-2361(95)00106-F 10.1016/S0016-2361(98)00198-7 10.1016/S0016-2361(99)00213-6 10.1016/S0016-2361(99)00056-3 10.1016/S0016-2361(97)00178-6 |
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| Keywords | X-ray diffraction NMR Desorption Coalbed methane Methane Coal deposit Coal seam gas NMR spectrometry Porosity Nuclear magnetic resonance X ray diffractometry |
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| Snippet | It is established experimentally using
1H NMR wide line spectroscopy that methane can exist in coals not only in open or closed porosity and fracture systems... It is established experimentally using (super 1)H NMR wide line spectroscopy that methane can exist in coals not only in open or closed porosity and fracture... |
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| SubjectTerms | Applied sciences Coal and derived products Coalbed methane Desorption Energy Exact sciences and technology Fuels NMR Structure, chemical and physical properties X-ray diffraction |
| Title | Latent methane in fossil coals |
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