A Crown-Shaped 24-Molybdate Cluster Constructed by Organotriphosphonate Ligand

A crown-shaped organic–inorganic hybrid polyoxomolybdate, Na5[H7{N(CH2PO3)3}Mo6O16(OH) (H2O)4]4·18H2O (1) has been presented and characterized. Such an intriguing structure consists of a 24-molybdenum-membered polyanion constructed by organotriphosphonate ligands, which represents the highest nuclea...

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Published inInorganic chemistry Vol. 52; no. 15; pp. 8285 - 8287
Main Authors Yang, Lu, Ma, Pengtao, Zhou, Zhen, Wang, Jingping, Niu, Jingyang
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 05.08.2013
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Summary:A crown-shaped organic–inorganic hybrid polyoxomolybdate, Na5[H7{N(CH2PO3)3}Mo6O16(OH) (H2O)4]4·18H2O (1) has been presented and characterized. Such an intriguing structure consists of a 24-molybdenum-membered polyanion constructed by organotriphosphonate ligands, which represents the highest nuclearity of metal atoms in the area of organophosphonate-based polyoxometalates.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic400848r