Cyclopropyl Containing Fatty Acids as Mechanistic Probes for Cytochromes P450 - Cryle, Max J; Ortiz de Montellano, Paul R; De Voss, James J (Journal of organic chemistry, 2005)
Keywords: Bioconversions. Hemisynthesis; Biological and medical sciences; Biotechnology; Catalysis; Chemistry; Chemistry, Organic; Cytochrome P-450 Enzyme System - chemistry; Exact sciences and technology; Fatty Acids - chemistry; Fundamental and applied biological sciences. Psychology; Gas Chromatography-Mass Spectrometry; Lipids; Methods. Procedures. Technologies; Molecular Probes; Nuclear Magnetic Resonance, Biomolecular; Organic chemistry; Oxidation-Reduction; Physical Sciences; Preparations and properties; Science & Technology; SITE; ALDEHYDE DIMETHYLHYDRAZONES; HYDROCARBONS; P450-CATALYZED HYDROXYLATION; 2-STATE REACTIVITY; RADICALS; IDENTIFICATION; CLOCKS; MASS-SPECTROMETRY; THERMOPHILIC CYP119; Chemical rearrangement; Cyclopropane derivatives; Hydroxylation; Aliphatic compound; Enzyme; Cytochrome P450; Isomerization; Alcohol; Lipids; Reaction rate; Fatty acids; Ring cleavage; Oxygenase; Organic free radical; Reaction mechanism; Cations; Oxidation; Oxidoreductases; Homoallylic compound