Enantioselective Reductive Coupling of 1,3-Enynes to Heterocyclic Aromatic Aldehydes and Ketones via Rhodium-Catalyzed Asymmetric Hydrogenation: Mechanistic Insight into the Role of Brønsted Acid Additives - Komanduri, Venukrishnan; Krische, Michael J (Journal of the American Chemical Society, 2006)
Keywords: Acids - chemistry; Alcohols - chemical synthesis; Alcohols - chemistry; Aldehydes - chemistry; Alkynes - chemistry; Catalysis; Chemistry; Chemistry, Multidisciplinary; Exact sciences and technology; General and physical chemistry; Hydrogenation; Ketones - chemistry; Kinetics and mechanisms; Molecular Structure; Organic chemistry; Oxidation-Reduction; Physical Sciences; Reactivity and mechanisms; Rhodium - chemistry; Science & Technology; Stereoisomerism; 1,6-ENYNES; ALKENYLZINC ADDITIONS; ALLYLIC ALCOHOLS; C BOND FORMATION; CONJUGATED ALKYNES; CARBONYL-COMPOUNDS; GENERATION; CYCLIZATION; HYDROFORMYLATION; PARTNERS; Catalytic reaction; Enantioselectivity; Transition metal; Aldehyde; Ketone; Hydrogenation; Enynic compound; Chemical reduction; Brönsted acid; Rhodium; Asymmetric synthesis; Reaction mechanism; Aromatic compound; Platinoid; Heterocyclic compound