Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene: Enhanced Enchainment Mediated by Binuclear Catalysts and Cocatalysts
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs), (μ-CH2CH2-3,3‘){(η5-indenyl)[1-Me2Si( t BuN)](TiMe2)}2[EBICGC(TiMe2)2; Ti 2 ] and (μ-CH2-3,3‘){(η5-indenyl)[1-Me2Si( t BuN)](TiMe2)}2[MBICGC(TiMe2)2; C1 − Ti 2 ], in combination wi...
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| Published in | Journal of the American Chemical Society Vol. 127; no. 42; pp. 14756 - 14768 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
WASHINGTON
American Chemical Society
26.10.2005
Amer Chemical Soc |
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| Online Access | Get full text |
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| Abstract | This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs), (μ-CH2CH2-3,3‘){(η5-indenyl)[1-Me2Si( t BuN)](TiMe2)}2[EBICGC(TiMe2)2; Ti 2 ] and (μ-CH2-3,3‘){(η5-indenyl)[1-Me2Si( t BuN)](TiMe2)}2[MBICGC(TiMe2)2; C1 − Ti 2 ], in combination with the bifunctional bisborane activator 1,4-(C6F5)2BC6F4B(C6F5)2 (BN 2 ) in ethylene + olefin copolymerization processes. Specifically examined are the classically poorly responsive 1,1-disubstituted comonomers, methylenecyclopentane (C), methylenecyclohexane (D), 1,1,2-trisubstituted 2-methyl-2-butene (E), and isobutene (F). For the first three comonomers, this represents the first report of their incorporation into a polyethylene backbone via a coordination polymerization process. C and D are incorporated via a ring-unopened pathway, and E is incorporated via a novel pathway involving 2-methyl-1-butene enchainment in the copolymer backbone. In ethylene copolymerization, Ti 2 + BN 2 enchains ∼2.5 times more C, ∼2.5 times more D, and ∼2.3 times more E than the mononuclear catalyst analogue [1-Me2Si(3-ethylindenyl)( t BuN)]TiMe2 (Ti 1 ) + B(C6F5)3 (BN) under identical polymerization conditions. Polar solvents are found to weaken the catalyst−cocatalyst ion pairing, thus influencing the comonomer enchainment selectivity. |
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| AbstractList | This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs), (μ-CH2CH2-3,3‘){(η5-indenyl)[1-Me2Si( t BuN)](TiMe2)}2[EBICGC(TiMe2)2; Ti 2 ] and (μ-CH2-3,3‘){(η5-indenyl)[1-Me2Si( t BuN)](TiMe2)}2[MBICGC(TiMe2)2; C1 − Ti 2 ], in combination with the bifunctional bisborane activator 1,4-(C6F5)2BC6F4B(C6F5)2 (BN 2 ) in ethylene + olefin copolymerization processes. Specifically examined are the classically poorly responsive 1,1-disubstituted comonomers, methylenecyclopentane (C), methylenecyclohexane (D), 1,1,2-trisubstituted 2-methyl-2-butene (E), and isobutene (F). For the first three comonomers, this represents the first report of their incorporation into a polyethylene backbone via a coordination polymerization process. C and D are incorporated via a ring-unopened pathway, and E is incorporated via a novel pathway involving 2-methyl-1-butene enchainment in the copolymer backbone. In ethylene copolymerization, Ti 2 + BN 2 enchains ∼2.5 times more C, ∼2.5 times more D, and ∼2.3 times more E than the mononuclear catalyst analogue [1-Me2Si(3-ethylindenyl)( t BuN)]TiMe2 (Ti 1 ) + B(C6F5)3 (BN) under identical polymerization conditions. Polar solvents are found to weaken the catalyst−cocatalyst ion pairing, thus influencing the comonomer enchainment selectivity. This contribution describes the implementation of the binuclear organotitanium "constrained geometry catalysts" (CGCs), (mu-CH(2)CH(2)-3,3'){(eta(5)-indenyl)[1-Me(2)Si((t)()BuN)](TiMe(2))}(2)[EBICGC(TiMe(2))(2); Ti(2)] and (mu-CH(2)-3,3'){(eta(5)-indenyl)[1-Me(2)Si((t)BuN)](TiMe(2))}(2)[MBICGC(TiMe(2))(2); C1-Ti(2)], in combination with the bifunctional bisborane activator 1,4-(C(6)F(5))(2)BC(6)F(4)B(C(6)F(5))(2) (BN(2)) in ethylene + olefin copolymerization processes. Specifically examined are the classically poorly responsive 1,1-disubstituted comonomers, methylenecyclopentane (C), methylenecyclohexane (D), 1,1,2-trisubstituted 2-methyl-2-butene (E), and isobutene (F). For the first three comonomers, this represents the first report of their incorporation into a polyethylene backbone via a coordination polymerization process. C and D are incorporated via a ring-unopened pathway, and E is incorporated via a novel pathway involving 2-methyl-1-butene enchainment in the copolymer backbone. In ethylene copolymerization, Ti(2) + BN(2) enchains approximately 2.5 times more C, approximately 2.5 times more D, and approximately 2.3 times more E than the mononuclear catalyst analogue [1-Me(2)Si(3-ethylindenyl)((t)BuN)]TiMe(2) (Ti(1)) + B(C(6)F(5))(3) (BN) under identical polymerization conditions. Polar solvents are found to weaken the catalyst-cocatalyst ion pairing, thus influencing the comonomer enchainment selectivity. This contribution describes the implementation of the binuclear organotitanium "constrained geometry catalysts" (CGCs), (mu-CH2CH2-3,3'){(eta(5)-indenyl)(1-Me2Si((BuN)-Bu-t)](TiMe2)}(2)[EBICGC(TiMe2)(2); Ti-2) and (mu-CH2-3,3'){(eta(5)-indenyl)(1-Me2Si((BuN)-Bu-t)](TiMe2)}(2)[MBICGC(TiMe2)(2); C1 -Ti-2], in combination with the bifunctional bisborane activator 1,4-(C6F5)(2)BC6F4B(C6F5)(2) (BN2) in ethylene + olefin copolymerization processes, Specifically examined are the classically poorly responsive 1,1-disubstituted comonomers, methylenecyclopentane (C), methylenecyclohexane (D), 1,1,2-trisubstituted 2-methyl-2-butene (E), and isobutene (F). For the first three comonomers, this represents the first report of their incorporation into a polyethylene backbone via a coordination polymerization process. C and D are incorporated via a ring-unopened pathway, and E is incorporated via a novel pathway involving 2-methyl-1-butene enchainment in the copolymer backbone. In ethylene copolymerization, Ti-2 + BN2 enchains similar to 2.5 times more C, similar to 2.5 times more D, and similar to 2.3 times more E than the mononuclear catalyst analogue [1-Me2Si(3-ethylindenyl)((BuN)-Bu-t)]TiMe2 (Ti-1) + B(C6F5)(3) (BN) under identical polymerization conditions. Polar solvents are found to weaken the catalyst-cocatalyst ion pairing, thus influencing the comonomer enchainment selectivity. |
| Author | Rheingold, Arnold L Metz, Matthew V Marks, Tobin J Li, Liting Schwartz, David J Li, Hongbo Liable-Sands, Louise |
| Author_xml | – sequence: 1 givenname: Hongbo surname: Li fullname: Li, Hongbo – sequence: 2 givenname: Liting surname: Li fullname: Li, Liting – sequence: 3 givenname: David J surname: Schwartz fullname: Schwartz, David J – sequence: 4 givenname: Matthew V surname: Metz fullname: Metz, Matthew V – sequence: 5 givenname: Tobin J surname: Marks fullname: Marks, Tobin J – sequence: 6 givenname: Louise surname: Liable-Sands fullname: Liable-Sands, Louise – sequence: 7 givenname: Arnold L surname: Rheingold fullname: Rheingold, Arnold L |
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| Cites_doi | 10.1002/anie.200460288 10.1021/ma010960l 10.1021/om0207764 10.1021/ja000571r 10.1021/om010942s 10.1039/b111697e 10.1002/pola.20292 10.1021/ja036289c 10.1021/ja0429622 10.1021/ma0481961 10.1021/ja000810a 10.1021/cr980461r 10.1021/ar960061v 10.1021/om049248d 10.1021/ja0445387 10.1021/om049481b 10.1021/om010016d 10.1021/ja005607u 10.1021/om040057k 10.1021/ja0209971 10.1021/ja048761f 10.1021/ja003531w 10.1021/ja011510b 10.1021/om010363n 10.1021/ma021084u 10.1021/ja0346577 10.1021/ja026608k 10.1021/ma0015929 10.1002/anie.200200548 10.1021/ja003209l 10.1021/ja046653n 10.1021/ja030085e 10.1021/ar0001665 10.1021/cr0206059 10.1021/ja0201698 10.1021/ja027617w 10.1021/ja037725y 10.1021/ja020870b 10.1021/om020079b 10.1021/ja029963j 10.1021/ja0387296 10.1021/om0102899 10.1021/ja016072n 10.1021/ma020988c 10.1021/ja029708z 10.1021/om00007a005 10.1002/macp.1996.021971220 10.1021/ma00068a009 10.1002/apmc.1994.052230109 10.1021/om960104b 10.1021/ja00231a020 10.1021/ar9501683 10.1021/ma981365v 10.1016/S1381-1169(97)00163-5 10.1021/ar50103a005 10.1021/bi0003689 10.1021/ar00028a011 10.1016/0022-328X(91)80181-I 10.1021/om00060a019 10.1021/cr940442r 10.1021/ma980324w 10.1021/ja00181a060 10.1021/ja00291a074 10.1021/ja045794m 10.1021/ja9604830 10.1021/om00118a046 10.1021/ja9638770 10.1021/ja9839769 10.1021/ja982683c 10.1021/om00018a017 10.1002/1521-3765(20000901)6:17<3287::AID-CHEM3287>3.0.CO;2-J 10.1039/a804295k 10.1021/om970242g 10.1002/anie.199622561 10.1021/om9609628 10.1021/ma980196b 10.1021/ma961331s 10.1038/22139 10.1080/15321797608065770 10.1021/ja00297a070 10.1002/1521-4095(200012)12:23<1855::AID-ADMA1855>3.0.CO;2-P 10.1002/anie.199014121 10.1021/om970227b 10.1021/cr990252m 10.1021/om030407n |
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| Keywords | ASYMMETRIC CATALYSIS OLEFIN POLYMERIZATION CATALYSTS CONSTRAINED GEOMETRY CATALYSTS THERMODYNAMIC STABILITY ADDITION POLYMERIZATION PROPYLENE POLYMERIZATION METALLOCENIUM ION-PAIRS METAL-ALKYL AMINE ELIMINATION COMONOMER ENCHAINMENT Titanium Organic compounds Ethylene Reaction mechanism NMR spectrometry Transition metal Complexes Kinetic parameter Complex catalyst Rate constant Catalyst activity Complex catalyst copolymerization Ring opening copolymerization Carbon 13 |
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| References | Natori, I (WOS:000073983000007) 1998; 36 Guo, N (WOS:000221671400020) 2004; 126 Diamond, GM (WOS:A1996VH29300022) 1996; 15 Gibson, VC (WOS:000180319600008) 2003; 103 Sammis, GM (WOS:000223279300027) 2004; 126 (WOS:000232780900052.4) 1999 Spaleck, W (WOS:000073192200023) 1998; 128 Li, HB (WOS:000224140400025) 2004; 43 AGBOSSOU, SK (WOS:A1990CZ98500046) 1990; 9 Baird, MC (WOS:000086603100011) 2000; 100 Lanza, G (WOS:000166045000019) 2000; 122 Kaminsky, W (WOS:000223071800001) 2004; 42 Britovsek, GJP (WOS:000078704200001) 1999; 38 Takeuchi, D (WOS:000169988300028) 2001; 40 Stahl, NG (WOS:000231052100046) 2005; 127 Horton, AD (WOS:A1996UQ71900003) 1996; 15 Chase, PA (WOS:000166045000055) 2000; 122 BENSON SW (WOS:000232780900052.12) 1976 Lanza, G (WOS:000171031800007) 2001; 20 Hannig, F (WOS:000223690200022) 2004; 23 YANG, XM (WOS:A1994PP75400022) 1994; 116 (WOS:000232780900052.1) 1992 Carpenetti, DW (WOS:A1996UB30700009) 1996; 15 Stoebenau, EJ (WOS:000223799900028) 2004; 126 Molenveld, P (WOS:000085689100001) 2000; 29 Lanza, G (WOS:000179717300017) 2002; 21 BOCHMANN, M (WOS:A1994NR47800017) 1994; 13 Noh, SK (WOS:000181147000008) 2003; 667 MARKS TJ (WOS:000232780900052.94) 1999; 15 ISAACS NS (WOS:000232780900052.65) 1987 PENG, TS (WOS:A1992HV67500020) 1992; 114 Takeuchi, D (WOS:000174434400047) 2002 Li, HB (WOS:000185154300010) 2003; 125 CLAWSON, L (WOS:A1985AJD7800070) 1985; 107 Scherer, W (WOS:000220658400005) 2004; 43 Shaffer, TD (WOS:000075174800059) 1998; 31 BOCHMANN, M (WOS:A1994PZ70600037) 1994; 484 Casey, CP (WOS:000171860700046) 2001; 123 Prosenc, MH (WOS:A1997XU43800006) 1997; 16 Song, FQ (WOS:000227533800037) 2005; 24 BRADLEY, DC (WOS:A1976BX61200005) 1976; 9 CHERDRON, H (WOS:A1994QD96500009) 1994; 223 Diamond, GM (WOS:A1996VE26600016) 1996; 118 Lewis, SP (WOS:000186834500018) 2003; 125 MCMILLEN, DF (WOS:A1982PP03300020) 1982; 33 CARR, N (WOS:A1992JQ03100001) 1992 Pedeutour, JN (WOS:000171666500002) 2001; 22 Beck, S (WOS:000167031300027) 2001; 123 Kawabe, M (WOS:000170694400043) 2001; 202 Klosin, J (WOS:000169545500005) 2001; 20 PROSENC, MH (WOS:A1992KC39200019) 1992; 11 Brandow, CG (WOS:000171405800022) 2001; 20 Li, LT (WOS:000178792400030) 2002; 124 SILVERSTEIN RM (WOS:000232780900052.126) 1991 SOGA K (WOS:000232780900052.128) 1994 BARLOS, K (WOS:A1978FW07200002) 1978; 31 Kleinschmidt, R (WOS:000087952600011) 2000; 157 Lewis, SP (WOS:000226240900022) 2005; 127 Liu, ZX (WOS:000172239900009) 2001; 123 Krishnan, R (WOS:000182137800011) 2003; 125 Landis, CR (WOS:000178514700002) 2002; 124 SCHMIDT, GF (WOS:A1985ADB5900073) 1985; 107 Ness, JS (WOS:000173478200006) 2002; 35 Park, JT (WOS:000086226600012) 2000; 19 GEHLSEN, MD (WOS:A1993LR35200009) 1993; 26 Chen, MC (WOS:000220752300047) 2004; 126 Chum, PS (WOS:000166291800010) 2000; 12 Williams, VC (WOS:000079810800045) 1999; 121 Barsan, F (WOS:000077657000001) 1998; 31 Konsler, RG (WOS:000076666800036) 1998; 120 GEHLSEN, MD (WOS:A1995RC14800010) 1995; 33 GLADYSZ JA (WOS:000232780900052.55) 2000; 100 Wang, JX (WOS:000224633400003) 2004; 23 LIDE DR (WOS:000232780900052.91) Zuccaccia, C (WOS:000188834900041) 2004; 126 Sawamura, M (WOS:A1996UD46400038) 1996; 118 KAMINSKY W (WOS:000232780900052.71) 1997; 127 Grubbs, RH (WOS:A1996TV82800004) 1996; 29 FU P (WOS:000232780900052.51) Abramo, GP (WOS:000179404200003) 2002; 124 BRANDRUP J (WOS:000232780900052.19) 1975 Hahn, SF (WOS:000180364900013) 2003; 36 Stoebenau, EJ (WOS:000181555600016) 2003; 125 Natori, I (WOS:A1997XE76000038) 1997; 30 PIERS, WE (WOS:A1990EL77000060) 1990; 112 Hucul, DA (WOS:000166291800023) 2000; 12 Yang, SH (WOS:000227085400052) 2005; 38 (WOS:000232780900052.3) 1993 Soga, K (WOS:000073192200022) 1998; 128 Bruice, TC (WOS:000174597800001) 2002; 35 Carazo-Salas, RE (WOS:000081324900057) 1999; 400 Coevoet, D (WOS:000080208500039) 1999; 200 Zhao, J (WOS:000167372100032) 2001; 34 BRINTZINGER, HH (WOS:A1995RF70200001) 1995; 34 MENGER, FM (WOS:A1993KY06800011) 1993; 26 BROOKHART, M (WOS:A1988Q818900001) 1988; 36 McKnight, AL (WOS:A1997XG56200019) 1997; 16 Takeuchi, D (WOS:000179864800004) 2002; 35 FERRY JD (WOS:000232780900052.49) 1970 Metz, MV (WOS:000178255000015) 2002; 21 Jia, L (WOS:A1997WL92900006) 1997; 16 Casey, CP (WOS:000181235800049) 2003; 125 DEVORE, DD (WOS:A1995RJ36300005) 1995; 14 KULSHRESTHA AK (WOS:000232780900052.79) 2000 McKnight, AL (WOS:000080179200002) 1999; 32 Bochmann, M (WOS:A1996TU46500001) 1996 Yan, XF (WOS:000073192200011) 1998; 128 Diamond, GM (WOS:A1996VH29300020) 1996; 15 McKnight, AL (WOS:000076981900006) 1998; 98 Christopher, JN (WOS:A1997XG56200039) 1997; 16 Green, MLH (WOS:000079915100007) 1999 Lancaster, SJ (WOS:000173638200003) 2002; 21 Matthews, RC (WOS:A1996VU20400025) 1996; 35 Trost, BM (WOS:000181235800023) 2003; 125 Molenveld, P (WOS:A1997WQ02000030) 1997; 119 Carpentier, JF (WOS:000166843900013) 2001; 123 Jacobsen, EN (WOS:000087894400013) 2000; 33 Rybtchinski, B (WOS:000089260100018) 2000; 6 Feng, SG (WOS:000079502900009) 1999; 18 LAPPERT MF (WOS:000232780900052.85) 1980 SCHOCK, LE (WOS:A1988Q949000020) 1988; 110 Christopher, JN (WOS:A1996VH29300021) 1996; 15 Guzei, IA (WOS:000087633000007) 2000; 56 Beswick, CL (WOS:000090137000012) 2000; 122 Metz, MV (WOS:000086418600039) 2000; 39 COTTER, WD (WOS:A1991GL22800027) 1991; 417 Moore, DR (WOS:000185578500042) 2003; 125 Bouwkamp, MW (WOS:000178966700016) 2002; 124 SAHGAL, A (WOS:A1978FK51900013) 1978; 56 KING, WA (WOS:A1995QN47500046) 1995; 229 KRAULEDAT, H (WOS:A1990EU00600015) 1990; 29 MARKS, TJ (WOS:A1992HD75200001) 1992; 25 Forlini, F (WOS:000085644700002) 2000; 201 BREITMAIER E (WOS:000232780900052.21) 1987 JOHNSTON, NW (WOS:A1976CB64100003) 1976; C 14 Harrison, D (WOS:000073192200006) 1998; 128 O'Brien, DP (WOS:000080854100019) 1999; 121 (WOS:000232780900052.2) 1992 YANG, XM (WOS:A1991FJ12100076) 1991; 113 Bruice, TC (WOS:000087374100001) 2000; 39 Collman, JP (WOS:000188934400009) 2004; 104 Deck, PA (WOS:000072368600016) 1998; 120 PAGE MI (WOS:000232780900052.111) 1984 Atiqullah, M (WOS:000076559000016) 1998; 34 Soga, K (WOS:A1996VY45800020) 1996; 197 JAMES DE (WOS:000232780900052.67) 1985; 6 Barsan F. (ja052995xb00021/ja052995xb00021_2) 1998; 31 Lanza G. (ja052995xb00018/ja052995xb00018_1) 2002; 21 Schmidt G. F. (ja052995xb00039/ja052995xb00039_7) 1985; 107 Ness J. S. (ja052995xb00011/ja052995xb00011_2) 2002; 35 Cotter W. D. (ja052995xb00035/ja052995xb00035_5) 1991; 417 Beck S. (ja052995xb00013/ja052995xb00013_3) 2001; 123 Stahl N. G. (ja052995xb00013/ja052995xb00013_8) 2005; 127 Scherer W. (ja052995xb00035/ja052995xb00035_1) 2004; 43 Prosenc M. H. (ja052995xb00035/ja052995xb00035_2) 1997; 16 Mathews R. C. (ja052995xb00002/ja052995xb00002_8) 1996; 35 Horton A. D. (ja052995xb00032/ja052995xb00032_1) 1996; 15 King W. A. (ja052995xb00030/ja052995xb00030_1) 1995; 229 Beswick C. L. (ja052995xb00017/ja052995xb00017_2) 2000; 122 Carpentier J.-F. (ja052995xb00037/ja052995xb00037_3) 2001; 123 Jia L. (ja052995xb00007/ja052995xb00007_2) 1996; 118 Molenveld P. (ja052995xb00002/ja052995xb00002_7) 1997; 119 Bradley D. C. (ja052995xb00014/ja052995xb00014_8) 1976; 9 McKnight A. L. (ja052995xb00005/ja052995xb00005_2) 1998; 98 Trost B. M. (ja052995xb00002/ja052995xb00002_3) 2003; 125 Carpenetti D. W. (ja052995xb00014/ja052995xb00014_6) 1996; 15 Christopher J. N. (ja052995xb00014/ja052995xb00014_1) 1997; 16 Bochmann M. (ja052995xb00013/ja052995xb00013_7) 1994; 13 Cherdron H. (ja052995xb00009/ja052995xb00009_5) 1994; 223 Sammis G. M. (ja052995xb00002/ja052995xb00002_1) 2004; 126 Stoebenau E. J. (ja052995xb00037/ja052995xb00037_1) 2004; 126 McKnight A. L. (ja052995xb00016/ja052995xb00016_4) 1997; 16 For (ja052995xb00004/ja052995xb00004_1) 2004; 37 Johnston N. W. (ja052995xb00029/ja052995xb00029_1) 1976; 14 Similar (ja052995xb00006/ja052995xb00006_1) 2005; 127 Shaffer T. D. (ja052995xb00028/ja052995xb00028_1) 1998; 31 Kulshrestha A. K. (ja052995xb00009/ja052995xb00009_1) 2000 Natori I. (ja052995xb00009/ja052995xb00009_3) 1998 Light (ja052995xb00024/ja052995xb00024_1) 2005; 38 Guzei I. A. (ja052995xb00020/ja052995xb00020_1) 2000; 56 Kawabe M. (ja052995xb00039/ja052995xb00039_2) 2001; 202 Molenveld P. (ja052995xb00002/ja052995xb00002_5) 2000; 29 Lide D. R. (ja052995xb00034/ja052995xb00034_1) Soga K. (ja052995xb00005/ja052995xb00005_4) 1996; 197 Page M. (ja052995xb00001/ja052995xb00001_8) 1984 Collman J. P. (ja052995xb00001/ja052995xb00001_1) 2004; 104 Jia L. (ja052995xb00007/ja052995xb00007_3) 1996; 118 Jacobsen E. N. (ja052995xb00002/ja052995xb00002_4) 2000; 33 O'Brien D. P. (ja052995xb00001/ja052995xb00001_5) 1999; 121 Casey C. P. (ja052995xb00036/ja052995xb00036_1) 2003; 125 Takeuchi D. (ja052995xb00008/ja052995xb00008_3) 2001; 14 Devore D. D. (ja052995xb00005/ja052995xb00005_5) 1995; 14 Carr N. (ja052995xb00039/ja052995xb00039_4) 1992; 18 Canich J. M. (ja052995xb00005/ja052995xb00005_7) 1991 Carazo-Salas R. E. (ja052995xb00001/ja052995xb00001_6) 1999; 400 Hahn S. F. (ja052995xb00011/ja052995xb00011_1) 2003; 36 Bruice T. C. (ja052995xb00001/ja052995xb00001_3) 2002; 35 Christopher J. N. (ja052995xb00014/ja052995xb00014_3) 1996; 15 ja052995xb00014/ja052995xb00014_7 ja052995xb00005/ja052995xb00005_6 Benson S. W. (ja052995xb00031/ja052995xb00031_3) 1976 Rybtchinski B. (ja052995xb00039/ja052995xb00039_3) 2000; 6 Stoebenau E. J. (ja052995xb00037/ja052995xb00037_2) 2003; 125 Menger F. M. (ja052995xb00001/ja052995xb00001_7) 1993; 26 Moore D. R. (ja052995xb00002/ja052995xb00002_2) 2003; 125 McKnight A. L. (ja052995xb00009/ja052995xb00009_2) 1999; 32 Yang X. (ja052995xb00013/ja052995xb00013_6) 1991; 113 Gehlsen M. (ja052995xb00011/ja052995xb00011_4) 1993; 26 ja052995xb00027/ja052995xb00027_1 Piers W. E. (ja052995xb00035/ja052995xb00035_7) 1990; 112 Brookhart M. (ja052995xb00035/ja052995xb00035_8) 1988; 36 Krauledat H. (ja052995xb00035/ja052995xb00035_6) 1990; 29 Agbossou S. K. (ja052995xb00039/ja052995xb00039_6) 1990; 9 Natori I. (ja052995xb00009/ja052995xb00009_4) 1997; 30 Barlos K. (ja052995xb00015/ja052995xb00015_1) 1978; 31 Klosin J. (ja052995xb00016/ja052995xb00016_1) 2001; 20 Feng S. (ja052995xb00016/ja052995xb00016_3) 1999; 18 ja052995xb00031/ja052995xb00031_1 Bouwkamp M. W. (ja052995xb00039/ja052995xb00039_1) 2002; 124 Yang X. (ja052995xb00013/ja052995xb00013_5) 1994; 116 McMillan D. F. (ja052995xb00031/ja052995xb00031_2) 1982; 33 Grubbs R. H. (ja052995xb00036/ja052995xb00036_4) 1996; 29 The (ja052995xb00023/ja052995xb00023_1) Grubbs R. H. (ja052995xb00035/ja052995xb00035_3) 1996; 29 Clawson L. (ja052995xb00035/ja052995xb00035_9) 1985; 107 Chum P. S. (ja052995xb00005/ja052995xb00005_1) 2000; 12 ja052995xb00005/ja052995xb00005_3 Jensen T. R. (ja052995xb00007/ja052995xb00007_1) 2004; 23 Schock L. E. (ja052995xb00030/ja052995xb00030_2) 1988; 110 Yang X. M. (ja052995xb00007/ja052995xb00007_4) 1994; 27 Prosenc M. H. (ja052995xb00035/ja052995xb00035_4) 1992; 11 Takeuchi D. (ja052995xb00008/ja052995xb00008_1) 2002; 35 Diamond G. M. (ja052995xb00014/ja052995xb00014_4) 1996; 15 Chase P. A. (ja052995xb00013/ja052995xb00013_4) 2000; 122 Hannig F. (ja052995xb00013/ja052995xb00013_2) 2004; 23 Deck P. A. (ja052995xb00017/ja052995xb00017_3) 1998; 120 Landis C. R. (ja052995xb00036/ja052995xb00036_2) 2002; 124 Devore D. D. (ja052995xb00005/ja052995xb00005_8) Diamond G. M. (ja052995xb00014/ja052995xb00014_5) 1996; 118 Gehlsen M. D. (ja052995xb00011/ja052995xb00011_3) 1995 Yang X. M. (ja052995xb00007/ja052995xb00007_5) 1993; 115 Zuccaccia C. (ja052995xb00017/ja052995xb00017_1) 2004; 126 For (ja052995xb00003/ja052995xb00003_1) 2004 Hucul D. A. (ja052995xb00010/ja052995xb00010_2) 2000; 12 Baird M. C. (ja052995xb00021/ja052995xb00021_1) 2000; 100 ja052995xb00033/ja052995xb00033_1 Casey C. P. (ja052995xb00036/ja052995xb00036_3) 2001; 123 Lanza G. (ja052995xb00018/ja052995xb00018_3) 2000; 122 Liu Z. (ja052995xb00026/ja052995xb00026_1) 2001; 123 Peng T. S. (ja052995xb00039/ja052995xb00039_5) 1992; 114 Zhao J. (ja052995xb00010/ja052995xb00010_1) 2001; 34 ja052995xb00025/ja052995xb00025_1 Konsler R. G. (ja052995xb00002/ja052995xb00002_6) 1998; 120 Park J. T. (ja052995xb00016/ja052995xb00016_2) 2000; 19 Diamond G. M. (ja052995xb00014/ja052995xb00014_2) 1996; 15 Bruice T. C. (ja052995xb00001/ja052995xb00001_4) 2000; 39 Lanza G. (ja052995xb00018/ja052995xb00018_2) 2001; 20 James D. (ja052995xb00009/ja052995xb00009_6) 1985; 6 Breitmaier E. (ja052995xb00022/ja052995xb00022_1) 1987 Brandow C. G. (ja052995xb00038/ja052995xb00038_1) 2001; 20 Krishnan R. (ja052995xb00001/ja052995xb00001_2) 2003; 125 Takeuchi D. (ja052995xb00008/ja052995xb00008_2) 2002; 646 Ferry J. D. (ja052995xb00027/ja052995xb00027_2) 1970 Song F. (ja052995xb00013/ja052995xb00013_1) 2005; 24 Sawamura M. (ja052995xb00002/ja052995xb00002_9) 1996; 118 |
| References_xml | – volume: 229 start-page: 343 year: 1995 ident: WOS:A1995QN47500046 article-title: METAL-SILICON BONDING ENERGETICS IN ORGANO-GROUP-4 AND ORGANO-F-ELEMENT COMPLEXES - IMPLICATIONS FOR BONDING AND REACTIVITY publication-title: INORGANICA CHIMICA ACTA contributor: fullname: KING, WA – volume: 120 start-page: 1772 year: 1998 ident: WOS:000072368600016 article-title: Highly electrophilic olefin polymerization catalysts. Quantitative reaction coordinates for fluoroarylborane/alumoxane methide abstraction and ion-pair reorganization in group 4 metallocene and "constrained geometry" catalysts publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Deck, PA – volume: 34 start-page: 1511 year: 1998 ident: WOS:000076559000016 article-title: Modeling the solubility of ethylene and propylene in a typical polymerization diluent: Some selected situations publication-title: EUROPEAN POLYMER JOURNAL contributor: fullname: Atiqullah, M – volume: 16 start-page: 2879 year: 1997 ident: WOS:A1997XG56200019 article-title: Selectivity in propylene polymerization with group 4 Cp-amido catalysts publication-title: ORGANOMETALLICS contributor: fullname: McKnight, AL – volume: 6 year: 1985 ident: WOS:000232780900052.67 publication-title: ENCY POLYM SCI ENG contributor: fullname: JAMES DE – volume: 43 start-page: 4937 year: 2004 ident: WOS:000224140400025 article-title: Polynuclear olefin polymerization catalysis: Proximity and cocatalyst effects lead to significantly increased polyethylene molecular weight and comonomer enchainment levels publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.200460288 contributor: fullname: Li, HB – volume: 35 start-page: 602 year: 2002 ident: WOS:000173478200006 article-title: Molecular weight effects in the hydrogenation of model polystyrenes using platinum supported on wide-pore silica publication-title: MACROMOLECULES doi: 10.1021/ma010960l contributor: fullname: Ness, JS – volume: 21 start-page: 5594 year: 2002 ident: WOS:000179717300017 article-title: Energetic, structural, and dynamic aspects of ethylene polymerization mediated by homogeneous single-site "constrained geometry catalysts" in the presence of cocatalyst and solvation: An investigation at the ab initio quantum chemical level publication-title: ORGANOMETALLICS doi: 10.1021/om0207764 contributor: fullname: Lanza, G – volume: 100 year: 2000 ident: WOS:000232780900052.55 publication-title: CHEM REV contributor: fullname: GLADYSZ JA – volume: 31 start-page: 363 year: 1978 ident: WOS:A1978FW07200002 article-title: N-14 NMR-STUDIES ON SOME TRIMETHYLSILYLAMINE DERIVATIVES publication-title: JOURNAL OF MAGNETIC RESONANCE contributor: fullname: BARLOS, K – volume: 122 start-page: 12764 year: 2000 ident: WOS:000166045000019 article-title: Ligand substituent, anion, and solvation effects on ion pair structure, thermodynamic stability, and structural mobility in "constrained geometry" olefin polymerization catalysts: An ab initio quantum chemical investigation publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja000571r contributor: fullname: Lanza, G – volume: 39 start-page: 6267 year: 2000 ident: WOS:000087374100001 article-title: Chemical basis for enzyme catalysis publication-title: BIOCHEMISTRY contributor: fullname: Bruice, TC – volume: 201 start-page: 401 year: 2000 ident: WOS:000085644700002 article-title: C-13 NMR studies of zirconocene-catalyzed propylene/1-hexene copolymers: in-depth investigation of the effect of solvent polarity publication-title: MACROMOLECULAR CHEMISTRY AND PHYSICS contributor: fullname: Forlini, F – volume: 202 start-page: 2440 year: 2001 ident: WOS:000170694400043 article-title: Solvent effect on beta-hydride elimination reaction in syndiospecific styrene polymerization with cyclopentadienyltitanium trichloride (CpTiCl3)/methylalumoxane (MAO) catalytic system publication-title: MACROMOLECULAR CHEMISTRY AND PHYSICS contributor: fullname: Kawabe, M – volume: 36 start-page: 1 year: 1988 ident: WOS:A1988Q818900001 article-title: CARBON HYDROGEN TRANSITION-METAL BONDS publication-title: PROGRESS IN INORGANIC CHEMISTRY contributor: fullname: BROOKHART, M – volume: 114 start-page: 4174 year: 1992 ident: WOS:A1992HV67500020 article-title: MECHANISM OF EQUILIBRATION OF DIASTEREOMERIC CHIRAL RHENIUM ALKENE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+BF4- - THE METAL TRAVERSES BETWEEN ALKENE ENANTIOFACES WITHOUT DISSOCIATION publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: PENG, TS – volume: 12 start-page: 1759 year: 2000 ident: WOS:000166291800010 article-title: Materials properties derived from INSITE metallocene catalysts publication-title: ADVANCED MATERIALS contributor: fullname: Chum, PS – volume: 157 start-page: 83 year: 2000 ident: WOS:000087952600011 article-title: Stereospecific propylene polymerization using half-sandwich metallocene/MAO systems: a mechanistic insight publication-title: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL contributor: fullname: Kleinschmidt, R – volume: 21 start-page: 451 year: 2002 ident: WOS:000173638200003 article-title: [H2N{B(C6F5)(3)}(2)](-): A new, remarkably stable diborate anion for metallocene polymerization catalysts publication-title: ORGANOMETALLICS doi: 10.1021/om010942s contributor: fullname: Lancaster, SJ – start-page: 646 year: 2002 ident: WOS:000174434400047 article-title: Ni-complex-catalysed addition polymerisation of 2-phenyl-1-methylenecylopropane to afford a polymer with cyclopropylidene groups publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/b111697e contributor: fullname: Takeuchi, D – year: 1992 ident: WOS:000232780900052.1 – volume: 42 start-page: 3911 year: 2004 ident: WOS:000223071800001 article-title: The discovery of metallocene catalysts and their present state of the art publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY doi: 10.1002/pola.20292 contributor: fullname: Kaminsky, W – volume: 40 start-page: 2685 year: 2001 ident: WOS:000169988300028 article-title: Ring-opening polymerization of 1-methylene-2-phenylcyclopropane catalyzed by a Pd complex to afford regioregulated polymers publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION contributor: fullname: Takeuchi, D – volume: 25 start-page: 57 year: 1992 ident: WOS:A1992HD75200001 article-title: SURFACE-BOUND METAL HYDROCARBYLS - ORGANOMETALLIC CONNECTIONS BETWEEN HETEROGENEOUS AND HOMOGENEOUS CATALYSIS publication-title: ACCOUNTS OF CHEMICAL RESEARCH contributor: fullname: MARKS, TJ – year: 1994 ident: WOS:000232780900052.128 publication-title: CATALYST DESIGN TAIL contributor: fullname: SOGA K – volume: 128 start-page: 273 year: 1998 ident: WOS:000073192200022 article-title: Synthesis of a dinuclear ansa-zirconocene catalyst having a biphenyl bridge and application to ethene polymerization publication-title: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL contributor: fullname: Soga, K – volume: 15 start-page: 2675 year: 1996 ident: WOS:A1996UQ71900003 article-title: Direct observation of beta-methyl elimination in cationic neopentyl complexes: Ligand effects on the reversible elimination of isobutene publication-title: ORGANOMETALLICS contributor: fullname: Horton, AD – volume: 33 start-page: 1527 year: 1995 ident: WOS:A1995RC14800010 article-title: SYNTHESIS AND CHARACTERIZATION OF POLY(VINYLCYCLOHEXANE) DERIVATIVES publication-title: JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS contributor: fullname: GEHLSEN, MD – volume: 125 start-page: 10788 year: 2003 ident: WOS:000185154300010 article-title: Catalyst/cocatalyst nuclearity effects in single-site olefin polymerization. Significantly enhanced 1-octene and isobutene comonomer enchainment in ethylene polymerizations mediated by binuclear catalysts and cocatalysts publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja036289c contributor: fullname: Li, HB – volume: 200 start-page: 1208 year: 1999 ident: WOS:000080208500039 article-title: Activation of iPr(CpFluo)ZrCl2 by methylaluminoxane, 3 Kinetic investigation of the syndiospecific hex-1-ene polymerization in hydrocarbon and chlorinated media publication-title: MACROMOLECULAR CHEMISTRY AND PHYSICS contributor: fullname: Coevoet, D – volume: 15 start-page: 4030 year: 1996 ident: WOS:A1996VH29300020 article-title: Synthesis of group 4 metal rac-(EBI)M(NR(2))(2) complexes by amine elimination. Scope and limitations publication-title: ORGANOMETALLICS contributor: fullname: Diamond, GM – volume: 127 start-page: 10898 year: 2005 ident: WOS:000231052100046 article-title: B(C6F5)(3)- vs Al(C6F5)(3)-derived metallocenium ion pairs. Structural, thermochemical, and structural dynamic divergences publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja0429622 contributor: fullname: Stahl, NG – volume: 113 start-page: 3623 year: 1991 ident: WOS:A1991FJ12100076 article-title: CATION-LIKE HOMOGENEOUS OLEFIN POLYMERIZATION CATALYSTS BASED UPON ZIRCONOCENE ALKYLS AND TRIS(PENTAFLUOROPHENYL)BORANE publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: YANG, XM – volume: 107 start-page: 1443 year: 1985 ident: WOS:A1985ADB5900073 article-title: IMPLICATIONS OF 3-CENTER, 2-ELECTRON M-H-C BONDING FOR RELATED ALKYL MIGRATION REACTIONS - DESIGN AND STUDY OF AN ETHYLENE POLYMERIZATION CATALYST publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: SCHMIDT, GF – volume: 38 start-page: 1402 year: 2005 ident: WOS:000227085400052 article-title: Effect of solvent polarity on the initiation and the propagation of ethylene polymerization with constrained geometry catalyst/MAO catalytic system: A density functional study with the conductor-like screening model publication-title: MACROMOLECULES doi: 10.1021/ma0481961 contributor: fullname: Yang, SH – volume: 122 start-page: 10358 year: 2000 ident: WOS:000090137000012 article-title: Metal-alkyl group effects on the thermodynamic stability and stereochemical mobility of B(C6F5)(3)-derived Zr and Hf metallocenium ion-pairs publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja000810a contributor: fullname: Beswick, CL – volume: 15 start-page: 4045 year: 1996 ident: WOS:A1996VH29300022 article-title: Synthesis of Me(2)Si-bridged ansa-zirconocenes by amine elimination publication-title: ORGANOMETALLICS contributor: fullname: Diamond, GM – volume: 32 start-page: 2816 year: 1999 ident: WOS:000080179200002 article-title: Ethylene norbornene copolymerizations with titanium CpA catalysts publication-title: MACROMOLECULES contributor: fullname: McKnight, AL – volume: 400 start-page: 178 year: 1999 ident: WOS:000081324900057 article-title: Generation of GTP-bound Ran by RCC1 is required for chromatin-induced mitotic spindle formation publication-title: NATURE contributor: fullname: Carazo-Salas, RE – volume: 15 year: 1999 ident: WOS:000232780900052.94 publication-title: TOP CATAL contributor: fullname: MARKS TJ – volume: 26 start-page: 4122 year: 1993 ident: WOS:A1993LR35200009 article-title: HETEROGENEOUS CATALYTIC-HYDROGENATION OF POLY(STYRENE) - THERMODYNAMICS OF POLY(VINYLCYCLOHEXANE) CONTAINING DIBLOCK COPOLYMERS publication-title: MACROMOLECULES contributor: fullname: GEHLSEN, MD – volume: 33 start-page: 493 year: 1982 ident: WOS:A1982PP03300020 article-title: HYDROCARBON BOND-DISSOCIATION ENERGIES publication-title: ANNUAL REVIEW OF PHYSICAL CHEMISTRY contributor: fullname: MCMILLEN, DF – volume: 120 start-page: 10780 year: 1998 ident: WOS:000076666800036 article-title: Cooperative asymmetric catalysis with dimeric salen complexes publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Konsler, RG – volume: 103 start-page: 283 year: 2003 ident: WOS:000180319600008 article-title: Advances in non-metallocene olefin polymerization catalysis publication-title: CHEMICAL REVIEWS doi: 10.1021/cr980461r contributor: fullname: Gibson, VC – volume: 484 start-page: C10 year: 1994 ident: WOS:A1994PZ70600037 article-title: FACILE ALPHA-H ELIMINATION IN CATIONIC ZIRCONIUM ALKYL COMPLEXES - FORMATION OF MU-CH2 COMPLEXES AS A POSSIBLE DEACTIVATION PATHWAY IN POLYMERIZATION CATALYSIS publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY contributor: fullname: BOCHMANN, M – volume: 417 start-page: C1 year: 1991 ident: WOS:A1991GL22800027 article-title: INVESTIGATIONS OF THE MAGNITUDE OF STERIC AND ALPHA-DEUTERIUM KINETIC ISOTOPE EFFECTS IN A CARBON CARBON BOND-FORMING REACTION OF A PERMETHYLSCANDOCENE COMPLEX publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY contributor: fullname: COTTER, WD – start-page: 2653 year: 1992 ident: WOS:A1992JQ03100001 article-title: PLATINUM ETHYL COMPLEXES WITH BETA-AGOSTIC PT-H-C BONDING publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS contributor: fullname: CARR, N – volume: 33 start-page: 421 year: 2000 ident: WOS:000087894400013 article-title: Asymmetric catalysis of epoxide ring opening reactions publication-title: ACCOUNTS OF CHEMICAL RESEARCH doi: 10.1021/ar960061v contributor: fullname: Jacobsen, EN – volume: 24 start-page: 1315 year: 2005 ident: WOS:000227533800037 article-title: Synthesis, ion aggregation, alkyl bonding modes, and dynamics of 14-electron metallocenium ion pairs [(SBI)MCH2SiMe3+center dot center dot center dot X-] (M = Zr, Hf): Inner-sphere (X = MeB(C6F5)(3)) versus outer-sphere (X = B(C6F5)(4)) structures and the implications for "continuous" or "intermittent" alkene polymerization mechanisms publication-title: ORGANOMETALLICS doi: 10.1021/om049248d contributor: fullname: Song, FQ – volume: 118 start-page: 3309 year: 1996 ident: WOS:A1996UD46400038 article-title: An enantioselective two-component catalyst system: Rh-Pd-catalyzed allylic alkylation of activated nitriles publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Sawamura, M – volume: 34 start-page: 1143 year: 1995 ident: WOS:A1995RF70200001 article-title: STEREOSPECIFIC OLEFIN POLYMERIZATION WITH CHIRAL METALLOCENE CATALYSTS publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION contributor: fullname: BRINTZINGER, HH – volume: 31 start-page: 8439 year: 1998 ident: WOS:000077657000001 article-title: Polymerization of isobutylene and the copolymerization of isobutylene and isoprene initiated by the metallocene derivative Cp*TiMe2(mu-Me)B(C6F5)(3) publication-title: MACROMOLECULES contributor: fullname: Barsan, F – volume: 127 start-page: 46 year: 2005 ident: WOS:000226240900022 article-title: Aqueous suspension polymerization of isobutene initiated by 1,2-C6F4[B(C6F5)(2)](2) publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja0445387 contributor: fullname: Lewis, SP – volume: 35 start-page: 2253 year: 1996 ident: WOS:A1996VU20400025 article-title: Bimetallic hydroformylation catalysis: In situ characterization of a dinuclear rhodium(II) dihydrido complex with the largest Rh-H NMR coupling constant publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH contributor: fullname: Matthews, RC – volume: 15 start-page: 1572 year: 1996 ident: WOS:A1996UB30700009 article-title: Application of amine elimination for the efficient preparation of electrophilic ansa-monocyclopentadienyl group 4 complexes containing an appended amido functionality. Structural characterization of [(C5H4) SiMe(2)(N-t-Bu)] ZrCl2 (NMe(2)H) publication-title: ORGANOMETALLICS contributor: fullname: Carpenetti, DW – start-page: 255 year: 1996 ident: WOS:A1996TU46500001 article-title: Cationic Group 4 metallocene complexes and their role in polymerisation catalysis: The chemistry of well defined Ziegler catalysts publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS contributor: fullname: Bochmann, M – year: 1999 ident: WOS:000232780900052.4 – volume: 12 start-page: 1855 year: 2000 ident: WOS:000166291800023 article-title: Catalytic hydrogenation of polystyrene publication-title: ADVANCED MATERIALS contributor: fullname: Hucul, DA – volume: 116 start-page: 10015 year: 1994 ident: WOS:A1994PP75400022 article-title: CATIONIC ZIRCONOCENE OLEFIN POLYMERIZATION CATALYSTS BASED ON THE ORGANO-LEWIS ACID TRIS(PENTAFLUOROPHENYL)BORANE - A SYNTHETIC, STRUCTURAL, SOLUTION DYNAMIC, AND POLYMERIZATION CATALYTIC STUDY publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: YANG, XM – volume: 23 start-page: 5112 year: 2004 ident: WOS:000224633400003 article-title: Covalently linked heterobimetallic catalysis for olefin polymerization publication-title: ORGANOMETALLICS doi: 10.1021/om049481b contributor: fullname: Wang, JX – volume: 20 start-page: 2663 year: 2001 ident: WOS:000169545500005 article-title: Heteroatom-substituted constrained-geometry complexes. Dramatic substituent effect on catalyst efficiency and polymer molecular weight publication-title: ORGANOMETALLICS doi: 10.1021/om010016d contributor: fullname: Klosin, J – year: 1987 ident: WOS:000232780900052.21 publication-title: CARBON 13 NMR SPECTR contributor: fullname: BREITMAIER E – volume: 16 start-page: 842 year: 1997 ident: WOS:A1997WL92900006 article-title: Cationic metallocene polymerization catalysts based on tetrakis(pentafluorophenyl)borate and its derivatives. Probing the limits of anion ''noncoordination'' via a synthetic, solution dynamic, structural, and catalytic olefin polymerization study publication-title: ORGANOMETALLICS contributor: fullname: Jia, L – volume: 107 start-page: 3377 year: 1985 ident: WOS:A1985AJD7800070 article-title: OLEFIN INSERTION IN A METAL ALKYL IN A ZIEGLER POLYMERIZATION SYSTEM publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: CLAWSON, L – volume: 126 start-page: 11170 year: 2004 ident: WOS:000223799900028 article-title: Alkyne and alkene complexes of a d(0) zirconocene aryl cation publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Stoebenau, EJ – volume: 122 start-page: 12911 year: 2000 ident: WOS:000166045000055 article-title: New fluorinated 9-borafluorene Lewis acids publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja005607u contributor: fullname: Chase, PA – volume: 23 start-page: 4495 year: 2004 ident: WOS:000223690200022 article-title: Structural and spectroscopic evidence for intramolecular agostic M center dot center dot center dot H-C and dative Zr <- F-C(ortho) interactions in the zwitterionic metal complexes [(C5H4)SiMe2(N-t-Bu)]M(+)(mu-C4H6)B(-)(C6F5)(3), M = Ti, Zr publication-title: ORGANOMETALLICS doi: 10.1021/om040057k contributor: fullname: Hannig, F – volume: 127 start-page: 144 year: 1997 ident: WOS:000232780900052.71 publication-title: ADV POLYM SCI contributor: fullname: KAMINSKY W – ident: WOS:000232780900052.51 publication-title: UNPUB contributor: fullname: FU P – volume: 9 start-page: 1184 year: 1990 ident: WOS:A1990CZ98500046 article-title: SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE CHIRAL RHENIUM PHENYL COMPLEX (ETA-5-C5H5)RE(NO)(PPH3)(C6H5) publication-title: ORGANOMETALLICS contributor: fullname: AGBOSSOU, SK – volume: 121 start-page: 3244 year: 1999 ident: WOS:000079810800045 article-title: New bifunctional perfluoroaryl boranes. Synthesis and reactivity of the ortho-phenylene-bridged diboranes 1,2-[B(C6F5)(2)](2)C6X4 (X = H, F)' publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Williams, VC – volume: 125 start-page: 2641 year: 2003 ident: WOS:000181235800049 article-title: Structural dependence of thermodynamics of alkene binding to yttrium alkyl complexes and of kinetics of alkyl migration to coordinated alkenes publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja0209971 contributor: fullname: Casey, CP – volume: 126 start-page: 6542 year: 2004 ident: WOS:000221671400020 article-title: Bimetallic catalysis for styrene homopolymerization and ethylene-styrene copolymerization. Exceptional comonomer selectivity and insertion regiochemistry publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja048761f contributor: fullname: Guo, N – volume: 123 start-page: 1483 year: 2001 ident: WOS:000167031300027 article-title: Anion exchange in alkyl-zirconocene borate ion pairs. Are solvated alkyl-zirconocene cations relevant intermediates? publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja003531w contributor: fullname: Beck, S – volume: 15 start-page: 4038 year: 1996 ident: WOS:A1996VH29300021 article-title: Synthesis, structure, and reactivity of rac-Me(2)Si(indenyl)(2)Zr(NMe(2))(2) publication-title: ORGANOMETALLICS contributor: fullname: Christopher, JN – volume: 6 start-page: 3287 year: 2000 ident: WOS:000089260100018 article-title: Solvent-stabilized alkylrhodium(III) hydride complexes: A special mode of reversible C-H bond elimination involving an agostic intermediate publication-title: CHEMISTRY-A EUROPEAN JOURNAL contributor: fullname: Rybtchinski, B – volume: 123 start-page: 10762 year: 2001 ident: WOS:000171860700046 article-title: Direct, observation of a nonchelated metal-alkyl-alkene complex and measurement of the rate of alkyl migration to a coordinated alkene publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja011510b contributor: fullname: Casey, CP – volume: 20 start-page: 4253 year: 2001 ident: WOS:000171405800022 article-title: Ancillary ligand and olefin substituent effects on olefin dissociation for cationic zirconocene complexes bearing a coordinated pendant olefin publication-title: ORGANOMETALLICS doi: 10.1021/om010363n contributor: fullname: Brandow, CG – volume: 29 start-page: 85 year: 1996 ident: WOS:A1996TV82800004 article-title: alpha-Agostic interactions and olefin insertion in metallocene polymerization catalysts publication-title: ACCOUNTS OF CHEMICAL RESEARCH contributor: fullname: Grubbs, RH – volume: 29 start-page: 75 year: 2000 ident: WOS:000085689100001 article-title: Dinuclear metallo-phosphodiesterase models: application of calix[4]arenes as molecular scaffolds publication-title: CHEMICAL SOCIETY REVIEWS contributor: fullname: Molenveld, P – volume: 36 start-page: 71 year: 2003 ident: WOS:000180364900013 article-title: High glass transition temperature polyolefins obtained by the catalytic hydrogenation of polyindene publication-title: MACROMOLECULES doi: 10.1021/ma021084u contributor: fullname: Hahn, SF – volume: 126 start-page: 4605 year: 2004 ident: WOS:000220752300047 article-title: Marked counteranion effects on single-site olefin polymerization processes. Correlations of ion pair structure and dynamics with polymerization activity, chain transfer, and syndioselectivity publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Chen, MC – volume: 125 start-page: 4422 year: 2003 ident: WOS:000182137800011 article-title: Thiolate-bridged nickel-copper complexes: A binuclear model for the catalytic site of acetyl coenzyme A synthase? publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja0346577 contributor: fullname: Krishnan, R – year: 1992 ident: WOS:000232780900052.2 – volume: 128 start-page: 65 year: 1998 ident: WOS:000073192200006 article-title: Olefin polymerization using supported metallocene catalysts: development of high activity catalysts for use in slurry and gas phase ethylene polymerizations publication-title: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL contributor: fullname: Harrison, D – volume: 124 start-page: 12062 year: 2002 ident: WOS:000178514700002 article-title: Heavy-atom kinetic isotope effects, cocatalysts, and the propagation transition state for polymerization of 1-hexene using the rac-(C2H4(1-indenyl)(2))ZrMe2 catalyst precursor publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja026608k contributor: fullname: Landis, CR – volume: 197 start-page: 4237 year: 1996 ident: WOS:A1996VY45800020 article-title: Structures of polyethylene and copolymers of ethylene with 1-octene and oligoethylene produced with the Cp(2)ZrCl(2) and [(C(5)Me(4))SiMe(2)N(t-Bu)]TiCl2 catalysts publication-title: MACROMOLECULAR CHEMISTRY AND PHYSICS contributor: fullname: Soga, K – volume: 13 start-page: 2235 year: 1994 ident: WOS:A1994NR47800017 article-title: SYNTHESIS OF BASE-FREE CATIONIC ZIRCONIUM METHYL AND BENZYL COMPLEXES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF (C5H3(SIME3)2-1,3)2ZRME(MU-ME)B(C6F5)3 publication-title: ORGANOMETALLICS contributor: fullname: BOCHMANN, M – start-page: 282 year: 1987 ident: WOS:000232780900052.65 publication-title: PHYSICAL ORGANIC CHE contributor: fullname: ISAACS NS – year: 1970 ident: WOS:000232780900052.49 publication-title: VISCOELASTIC PROPERT contributor: fullname: FERRY JD – volume: 34 start-page: 1737 year: 2001 ident: WOS:000167372100032 article-title: Thermal and viscoelastic behavior of hydrogenated polystyrene publication-title: MACROMOLECULES doi: 10.1021/ma0015929 contributor: fullname: Zhao, J – volume: 128 start-page: 279 year: 1998 ident: WOS:000073192200023 article-title: New bridged zirconocenes for olefin polymerization: Binuclear and hybrid structures publication-title: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL contributor: fullname: Spaleck, W – volume: 14 start-page: 3132 year: 1995 ident: WOS:A1995RJ36300005 article-title: CONSTRAINED-GEOMETRY TITANIUM(II) DIENE COMPLEXES - STRUCTURAL DIVERSITY AND OLEFIN POLYMERIZATION ACTIVITY publication-title: ORGANOMETALLICS contributor: fullname: DEVORE, DD – volume: 98 start-page: 2587 year: 1998 ident: WOS:000076981900006 article-title: Group 4 ansa-cyclopentadienyl-amido catalysts for olefin polymerization publication-title: CHEMICAL REVIEWS contributor: fullname: McKnight, AL – volume: 43 start-page: 1782 year: 2004 ident: WOS:000220658400005 article-title: Agostic interactions in d(0) metal alkyl complexes publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.200200548 contributor: fullname: Scherer, W – ident: WOS:000232780900052.91 publication-title: CRC HDB THERMOPHYSIC contributor: fullname: LIDE DR – volume: 56 start-page: 635 year: 2000 ident: WOS:000087633000007 article-title: The bis(eta(5)-cyclopentadienyl)methylzirconium(IV) methyltris(pentafluorophenyl)borate ion pair publication-title: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS contributor: fullname: Guzei, IA – volume: C 14 start-page: 215 year: 1976 ident: WOS:A1976CB64100003 article-title: SEQUENCE DISTRIBUTION - GLASS-TRANSITION EFFECTS publication-title: JOURNAL OF MACROMOLECULAR SCIENCE-REVIEWS IN MACROMOLECULAR CHEMISTRY AND PHYSICS contributor: fullname: JOHNSTON, NW – start-page: 500 year: 1980 ident: WOS:000232780900052.85 publication-title: METAL METALLOID AMID contributor: fullname: LAPPERT MF – volume: 9 start-page: 273 year: 1976 ident: WOS:A1976BX61200005 article-title: TRANSITION-METAL DIALKYLAMIDES AND DISILYLAMIDES publication-title: ACCOUNTS OF CHEMICAL RESEARCH contributor: fullname: BRADLEY, DC – volume: 123 start-page: 898 year: 2001 ident: WOS:000166843900013 article-title: Solution structures and dynamic properties of chelated d(0) metal olefin complexes {eta(5):eta(1)-(C5R4SiMe2NBu)-Bu-t}Ti(OCMe(2)CH(2)Ch(2)CH=CH2)(+) (R = H, Me): Models for the {eta(5):eta(1)-(C5R4SiMe2NBu)-Bu-t}Ti(R ')(olefin)(+) intermediates in "constrained geometry" catalysts publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja003209l contributor: fullname: Carpentier, JF – volume: 110 start-page: 7701 year: 1988 ident: WOS:A1988Q949000020 article-title: ORGANOMETALLIC THERMOCHEMISTRY - METAL HYDROCARBYL, HYDRIDE, HALIDE, CARBONYL, AMIDE, AND ALKOXIDE BOND ENTHALPY RELATIONSHIPS AND THEIR IMPLICATIONS IN PENTAMETHYLCYCLOPENTADIENYL AND CYCLOPENTADIENYL COMPLEXES OF ZIRCONIUM AND HAFNIUM publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: SCHOCK, LE – volume: 112 start-page: 9406 year: 1990 ident: WOS:A1990EL77000060 article-title: ALPHA-AGOSTIC ASSISTANCE IN ZIEGLER-NATTA POLYMERIZATION OF OLEFINS - DEUTERIUM ISOTOPIC PERTURBATION OF STEREOCHEMISTRY INDICATING COORDINATION OF AN ALPHA-C-H BOND IN CHAIN PROPAGATION publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: PIERS, WE – volume: 126 start-page: 9928 year: 2004 ident: WOS:000223279300027 article-title: Cooperative dual catalysis: Application to the highly enantioselective conjugate cyanation of unsaturated imides publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja046653n contributor: fullname: Sammis, GM – volume: 667 start-page: 53 year: 2003 ident: WOS:000181147000008 article-title: Syntheses of dinuclear titanium constrained geometry complexes with polymethylene bridges and their copolymerization properties publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY contributor: fullname: Noh, SK – volume: 36 start-page: 1657 year: 1998 ident: WOS:000073983000007 article-title: Hydrocarbon polymers containing six-membered rings in the main chain. Microstructure and properties of poly(1,3-cyclohexadiene) publication-title: JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS contributor: fullname: Natori, I – start-page: 143 year: 1975 ident: WOS:000232780900052.19 publication-title: POLYM HDB contributor: fullname: BRANDRUP J – volume: 125 start-page: 11911 year: 2003 ident: WOS:000185578500042 article-title: Mechanism of the alternating copolymerization of epoxides and CO2 using beta-diiminate zinc catalysts: Evidence for a bimetallic epoxide enchainment publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja030085e contributor: fullname: Moore, DR – start-page: 215 year: 1991 ident: WOS:000232780900052.126 publication-title: SPECTROMETRIC IDENTI contributor: fullname: SILVERSTEIN RM – volume: 118 start-page: 8024 year: 1996 ident: WOS:A1996VE26600016 article-title: Efficient synthesis of chiral ansa-metallocenes by amine elimination. Synthesis, structure, and reactivity of rac-(EBI)Zr(NMe(2))(2) publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Diamond, GM – volume: 128 start-page: 119 year: 1998 ident: WOS:000073192200011 article-title: Homo- and hetero-binuclear ansa-metallocenes of the group 4 transition metals as homogeneous co-catalysts for the polymerisation of ethene and propene publication-title: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL contributor: fullname: Yan, XF – volume: 31 start-page: 5145 year: 1998 ident: WOS:000075174800059 article-title: Metallocene-catalyzed copolymerization of ethylene and isobutylene to substantially alternating copolymers publication-title: MACROMOLECULES contributor: fullname: Shaffer, TD – year: 1976 ident: WOS:000232780900052.12 publication-title: THEMOCHEMICAL KINETI contributor: fullname: BENSON SW – volume: 18 start-page: 1159 year: 1999 ident: WOS:000079502900009 article-title: Synthesis and characterization of cyclohexadienyl-based constrained geometry complexes publication-title: ORGANOMETALLICS contributor: fullname: Feng, SG – volume: 56 start-page: 354 year: 1978 ident: WOS:A1978FK51900013 article-title: SOLUBILITY OF ETHYLENE IN SEVERAL POLAR AND NONPOLAR-SOLVENTS publication-title: CANADIAN JOURNAL OF CHEMICAL ENGINEERING contributor: fullname: SAHGAL, A – volume: 35 start-page: 139 year: 2002 ident: WOS:000174597800001 article-title: A view at the millennium: The efficiency of enzymatic catalysis publication-title: ACCOUNTS OF CHEMICAL RESEARCH doi: 10.1021/ar0001665 contributor: fullname: Bruice, TC – volume: 16 start-page: 3044 year: 1997 ident: WOS:A1997XG56200039 article-title: Synthesis and structures of rac-Me2Si(eta(5)-1-indenyl)(2)Hf(NMe2)(2) and {Me2Si(eta(5)-1-indenyl)(eta(3)-2-indenyl)}Hf(NMe2)(2) publication-title: ORGANOMETALLICS contributor: fullname: Christopher, JN – volume: 38 start-page: 428 year: 1999 ident: WOS:000078704200001 article-title: The search for new-generation olefin polymerization catalysts: Life beyond metallocenes publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION contributor: fullname: Britovsek, GJP – year: 2000 ident: WOS:000232780900052.79 publication-title: HDB POLYOLEFINS contributor: fullname: KULSHRESTHA AK – volume: 121 start-page: 5259 year: 1999 ident: WOS:000080854100019 article-title: High affinity surface binding of a strongly dimerizing vancomycin-group antibiotic to a model of resistant bacteria publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: O'Brien, DP – volume: 104 start-page: 561 year: 2004 ident: WOS:000188934400009 article-title: Functional analogues of cytochrome c oxidase, myoglobin, and hemoglobin publication-title: CHEMICAL REVIEWS doi: 10.1021/cr0206059 contributor: fullname: Collman, JP – volume: 124 start-page: 12725 year: 2002 ident: WOS:000178792400030 article-title: Catalyst/cocatalyst nuclearity effects in single-site polymerization. Enhanced polyethylene branching and alpha-olefin comonomer enchainment in polymerizations mediated by binuclear catalysts and cocatalysts via a new enchainment pathway publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja0201698 contributor: fullname: Li, LT – year: 1993 ident: WOS:000232780900052.3 – volume: 29 start-page: 1412 year: 1990 ident: WOS:A1990EU00600015 article-title: ISOTOPE EFFECTS ASSOCIATED WITH ALPHA-OLEFIN INSERTION IN ZIRCONOCENE-BASED POLYMERIZATION CATALYSTS - EVIDENCE FOR AN ALPHA-AGOSTIC TRANSITION-STATE publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION contributor: fullname: KRAULEDAT, H – volume: 19 start-page: 1269 year: 2000 ident: WOS:000086226600012 article-title: Cyclopentadienyl-hydrazido titanium complexes: Synthesis, structure, reactivity, and catalytic properties publication-title: ORGANOMETALLICS contributor: fullname: Park, JT – volume: 11 start-page: 4036 year: 1992 ident: WOS:A1992KC39200019 article-title: AGOSTIC ASSISTANCE TO OLEFIN INSERTION IN ALKYLZIRCONOCENE CATIONS - A MOLECULAR-ORBITAL STUDY BY THE EXTENDED HUCKEL-METHOD publication-title: ORGANOMETALLICS contributor: fullname: PROSENC, MH – volume: 124 start-page: 12956 year: 2002 ident: WOS:000178966700016 article-title: Structure of the decamethyl titanocene cation, a metallocene with two agostic C-H bonds, and its interaction with fluorocarbons publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja027617w contributor: fullname: Bouwkamp, MW – start-page: 1 year: 1984 ident: WOS:000232780900052.111 publication-title: CHEM ENZYME ACTION contributor: fullname: PAGE MI – volume: 125 start-page: 14686 year: 2003 ident: WOS:000186834500018 article-title: Isobutene polymerization using a chelating diborane co-initiator publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja037725y contributor: fullname: Lewis, SP – volume: 16 start-page: 3889 year: 1997 ident: WOS:A1997XU43800006 article-title: Zirconium-alkyl isomerizations in zirconocene-catalyzed olefin polymerization: A density functional study publication-title: ORGANOMETALLICS contributor: fullname: Prosenc, MH – volume: 124 start-page: 13966 year: 2002 ident: WOS:000179404200003 article-title: Polynuclear catalysis: Enhancement of enchainment cooperativity between different single-site olefin polymerization catalysts by ion pairing with a binuclear cocatalyst publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja020870b contributor: fullname: Abramo, GP – volume: 21 start-page: 4159 year: 2002 ident: WOS:000178255000015 article-title: New perfluoroarylborane activators for single-site olefin polymerization. Acidity and cocatalytic properties of a "superacidic" perfluorodiboraanthracene publication-title: ORGANOMETALLICS doi: 10.1021/om020079b contributor: fullname: Metz, MV – volume: 125 start-page: 3222 year: 2003 ident: WOS:000181555600016 article-title: Coordination of alkenes and alkynes to a cationic d(0) zirconocene alkoxide complex publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja029963j contributor: fullname: Stoebenau, EJ – volume: 26 start-page: 206 year: 1993 ident: WOS:A1993KY06800011 article-title: ENZYME REACTIVITY FROM AN ORGANIC PERSPECTIVE publication-title: ACCOUNTS OF CHEMICAL RESEARCH contributor: fullname: MENGER, FM – volume: 39 start-page: 1312 year: 2000 ident: WOS:000086418600039 article-title: Organo-Lewis acid cocatalysts in single-site olefin polymerization - A highly acidic perfluorodiboraanthracene publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION contributor: fullname: Metz, MV – volume: 119 start-page: 2948 year: 1997 ident: WOS:A1997WQ02000030 article-title: Highly efficient phosphate diester transesterification by a calix[4]arene-based dinuclear zinc(II) catalyst publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Molenveld, P – volume: 223 start-page: 121 year: 1994 ident: WOS:A1994QD96500009 article-title: CYCLOOLEFIN COPOLYMERS - A NEW CLASS OF TRANSPARENT THERMOPLASTIC POLYMERS publication-title: ANGEWANDTE MAKROMOLEKULARE CHEMIE contributor: fullname: CHERDRON, H – volume: 126 start-page: 1448 year: 2004 ident: WOS:000188834900041 article-title: NOE and PGSE NMR spectroscopic studies of solution structure and aggregation in metallocenium ion-pairs publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja0387296 contributor: fullname: Zuccaccia, C – start-page: 1049 year: 1999 ident: WOS:000079915100007 article-title: Synthesis of heterobinuclear metallocenes containing bridging ansa-bis-eta-cyclopentadienyl ligands publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS contributor: fullname: Green, MLH – volume: 20 start-page: 4006 year: 2001 ident: WOS:000171031800007 article-title: Metal and ancillary ligand structural effects on ethylene insertion processes at cationic group 4 centers. A systematic, comparative quantum chemical investigation at various ab initio levels publication-title: ORGANOMETALLICS doi: 10.1021/om0102899 contributor: fullname: Lanza, G – volume: 123 start-page: 11193 year: 2001 ident: WOS:000172239900009 article-title: Kinetics of initiation, propagation, and termination for the [rac-(C2H4(1-indenyl)(2))ZrMe][MeB(C6F5)(3)]-catalyzed polymerization of 1-hexene publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja016072n contributor: fullname: Liu, ZX – volume: 30 start-page: 3696 year: 1997 ident: WOS:A1997XE76000038 article-title: Synthesis of polymers with an alicyclic structure in the main chain. Living anionic polymerization of 1,3-cyclohexadiene with the n-butyllithium/N,N,N',N'-tetramethylethylenediamine system publication-title: MACROMOLECULES contributor: fullname: Natori, I – volume: 35 start-page: 9628 year: 2002 ident: WOS:000179864800004 article-title: Addition polymerization of 2-aryl- and 2-ethoxycarbonyl-1-methlenecyclopropanes promoted by nickel complexes publication-title: MACROMOLECULES doi: 10.1021/ma020988c contributor: fullname: Takeuchi, D – volume: 125 start-page: 2410 year: 2003 ident: WOS:000181235800023 article-title: Desymmetrization of meso 1,3-and 1,4-diols with a dinuclear zinc asymmetric catalyst publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja029708z contributor: fullname: Trost, BM – volume: 22 start-page: 1095 year: 2001 ident: WOS:000171666500002 article-title: Reactivity of metallocene catalysts for olefin polymerization: Influence of activator nature and structure publication-title: MACROMOLECULAR RAPID COMMUNICATIONS contributor: fullname: Pedeutour, JN – volume: 100 start-page: 1471 year: 2000 ident: WOS:000086603100011 article-title: Carbocationic alkene polymerizations initiated by organotransition metal complexes: An alternative, unusual role for soluble Ziegler-Natta catalysts publication-title: CHEMICAL REVIEWS contributor: fullname: Baird, MC – volume: 36 start-page: 124 year: 1988 ident: ja052995xb00035/ja052995xb00035_8 publication-title: Prog. Inorg. Chem. contributor: fullname: Brookhart M. – volume: 14 start-page: 3134 year: 1995 ident: ja052995xb00005/ja052995xb00005_5 publication-title: Organometallics doi: 10.1021/om00007a005 contributor: fullname: Devore D. D. – volume: 197 start-page: 4251 year: 1996 ident: ja052995xb00005/ja052995xb00005_4 publication-title: Macromol. Chem. Phys. doi: 10.1002/macp.1996.021971220 contributor: fullname: Soga K. – volume: 122 start-page: 12777 year: 2000 ident: ja052995xb00018/ja052995xb00018_3 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja000571r contributor: fullname: Lanza G. – volume: 123 start-page: 10763 year: 2001 ident: ja052995xb00036/ja052995xb00036_3 publication-title: J. Am. Chem. Soc. contributor: fullname: Casey C. P. – volume: 56 start-page: 636 year: 2000 ident: ja052995xb00020/ja052995xb00020_1 publication-title: Acta Crystallogr. contributor: fullname: Guzei I. A. – volume-title: Carbon-13 NMR Spectroscopy year: 1987 ident: ja052995xb00022/ja052995xb00022_1 contributor: fullname: Breitmaier E. – volume: 35 start-page: 9633 year: 2002 ident: ja052995xb00008/ja052995xb00008_1 publication-title: Macromolecules doi: 10.1021/ma020988c contributor: fullname: Takeuchi D. – volume: 26 start-page: 4127 year: 1993 ident: ja052995xb00011/ja052995xb00011_4 publication-title: Macromolecules doi: 10.1021/ma00068a009 contributor: fullname: Gehlsen M. – volume: 223 start-page: 133 year: 1994 ident: ja052995xb00009/ja052995xb00009_5 publication-title: Angew. Makromol. Chem. doi: 10.1002/apmc.1994.052230109 contributor: fullname: Cherdron H. – volume: 125 start-page: 2651 year: 2003 ident: ja052995xb00036/ja052995xb00036_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0209971 contributor: fullname: Casey C. P. – volume: 125 start-page: 3223 year: 2003 ident: ja052995xb00037/ja052995xb00037_2 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja029963j contributor: fullname: Stoebenau E. J. – volume: 126 start-page: 9929 year: 2004 ident: ja052995xb00002/ja052995xb00002_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja046653n contributor: fullname: Sammis G. M. – volume-title: Viscoelastic Properties of Polymers year: 1970 ident: ja052995xb00027/ja052995xb00027_2 contributor: fullname: Ferry J. D. – volume: 118 start-page: 3310 year: 1996 ident: ja052995xb00002/ja052995xb00002_9 publication-title: J. Am. Chem. Soc. contributor: fullname: Sawamura M. – volume: 15 start-page: 4044 year: 1996 ident: ja052995xb00014/ja052995xb00014_3 publication-title: Organometallics doi: 10.1021/om960104b contributor: fullname: Christopher J. N. – ident: ja052995xb00025/ja052995xb00025_1 – volume: 110 start-page: 7715 year: 1988 ident: ja052995xb00030/ja052995xb00030_2 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00231a020 contributor: fullname: Schock L. E. – volume: 29 start-page: 93 year: 1996 ident: ja052995xb00035/ja052995xb00035_3 publication-title: Acc. Chem. Res. doi: 10.1021/ar9501683 contributor: fullname: Grubbs R. H. – volume: 123 start-page: 909 year: 2001 ident: ja052995xb00037/ja052995xb00037_3 publication-title: J. Am. Chem. Soc. contributor: fullname: Carpentier J.-F. – ident: ja052995xb00027/ja052995xb00027_1 – volume: 18 start-page: 1167 year: 1999 ident: ja052995xb00016/ja052995xb00016_3 publication-title: Organometallics contributor: fullname: Feng S. – volume: 115 start-page: 3393 year: 1993 ident: ja052995xb00007/ja052995xb00007_5 publication-title: J. Am. Chem. Soc. contributor: fullname: Yang X. M. – volume: 20 start-page: 2665 year: 2001 ident: ja052995xb00016/ja052995xb00016_1 publication-title: Organometallics doi: 10.1021/om010016d contributor: fullname: Klosin J. – volume: 32 start-page: 2825 year: 1999 ident: ja052995xb00009/ja052995xb00009_2 publication-title: Macromolecules doi: 10.1021/ma981365v contributor: fullname: McKnight A. L. – volume: 21 start-page: 5612 year: 2002 ident: ja052995xb00018/ja052995xb00018_1 publication-title: J. Organometallics doi: 10.1021/om0207764 contributor: fullname: Lanza G. – volume: 18 start-page: 2662 year: 1992 ident: ja052995xb00039/ja052995xb00039_4 publication-title: J. Chem. Soc., Dalton Trans. contributor: fullname: Carr N. – ident: ja052995xb00005/ja052995xb00005_3 doi: 10.1016/S1381-1169(97)00163-5 – volume: 124 start-page: 12957 year: 2002 ident: ja052995xb00039/ja052995xb00039_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja027617w contributor: fullname: Bouwkamp M. W. – volume: 15 start-page: 4037 year: 1996 ident: ja052995xb00014/ja052995xb00014_2 publication-title: Organometallics contributor: fullname: Diamond G. M. – volume: 9 start-page: 280 year: 1976 ident: ja052995xb00014/ja052995xb00014_8 publication-title: Acc. Chem. Res. doi: 10.1021/ar50103a005 contributor: fullname: Bradley D. C. – volume-title: CRC Handbook of Thermophysical and Thermochemical Data ident: ja052995xb00034/ja052995xb00034_1 contributor: fullname: Lide D. R. – volume: 39 start-page: 6274 year: 2000 ident: ja052995xb00001/ja052995xb00001_4 publication-title: J. Biochemistry doi: 10.1021/bi0003689 contributor: fullname: Bruice T. C. – volume: 120 start-page: 1784 year: 1998 ident: ja052995xb00017/ja052995xb00017_3 publication-title: J. Am. Chem. Soc. contributor: fullname: Deck P. A. – volume: 33 start-page: 431 year: 2000 ident: ja052995xb00002/ja052995xb00002_4 publication-title: Acc. Chem. Res. doi: 10.1021/ar960061v contributor: fullname: Jacobsen E. N. – volume-title: Part B: Polym. Phys year: 1995 ident: ja052995xb00011/ja052995xb00011_3 contributor: fullname: Gehlsen M. D. – volume: 26 start-page: 212 year: 1993 ident: ja052995xb00001/ja052995xb00001_7 publication-title: Acc. Chem. Res. doi: 10.1021/ar00028a011 contributor: fullname: Menger F. M. – volume: 417 start-page: C6 year: 1991 ident: ja052995xb00035/ja052995xb00035_5 publication-title: J. Organomet. Chem. doi: 10.1016/0022-328X(91)80181-I contributor: fullname: Cotter W. D. – start-page: 54 volume-title: The Chemistry of Enzyme Action year: 1984 ident: ja052995xb00001/ja052995xb00001_8 contributor: fullname: Page M. – volume: 116 start-page: 10031 year: 1994 ident: ja052995xb00013/ja052995xb00013_5 publication-title: J. Am. Chem. Soc. contributor: fullname: Yang X. – volume: 11 start-page: 4041 year: 1992 ident: ja052995xb00035/ja052995xb00035_4 publication-title: Organometallics doi: 10.1021/om00060a019 contributor: fullname: Prosenc M. H. – volume: 104 start-page: 588 year: 2004 ident: ja052995xb00001/ja052995xb00001_1 publication-title: Chem. Rev. doi: 10.1021/cr0206059 contributor: fullname: Collman J. P. – volume: 98 start-page: 2598 year: 1998 ident: ja052995xb00005/ja052995xb00005_2 publication-title: Chem. Rev. doi: 10.1021/cr940442r contributor: fullname: McKnight A. L. – volume: 14 start-page: 2688 year: 2001 ident: ja052995xb00008/ja052995xb00008_3 publication-title: Angew. Chem., Int. Ed. contributor: fullname: Takeuchi D. – volume: 31 start-page: 376 year: 1978 ident: ja052995xb00015/ja052995xb00015_1 publication-title: J. Magn. Reson. contributor: fullname: Barlos K. – volume: 31 start-page: 8447 year: 1998 ident: ja052995xb00021/ja052995xb00021_2 publication-title: Macromolecules doi: 10.1021/ma980324w contributor: fullname: Barsan F. – volume: 112 start-page: 9407 year: 1990 ident: ja052995xb00035/ja052995xb00035_7 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00181a060 contributor: fullname: Piers W. E. – volume: 15 start-page: 4053 year: 1996 ident: ja052995xb00014/ja052995xb00014_4 publication-title: Organometallics contributor: fullname: Diamond G. M. – volume: 107 start-page: 1444 year: 1985 ident: ja052995xb00039/ja052995xb00039_7 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00291a074 contributor: fullname: Schmidt G. F. – volume-title: W. J. Polym. Sci., Part B: Polym. Chem. year: 2004 ident: ja052995xb00003/ja052995xb00003_1 contributor: fullname: For – volume: 126 start-page: 11171 year: 2004 ident: ja052995xb00037/ja052995xb00037_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja045794m contributor: fullname: Stoebenau E. J. – volume: 122 start-page: 12912 year: 2000 ident: ja052995xb00013/ja052995xb00013_4 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja005607u contributor: fullname: Chase P. A. – volume: 118 start-page: 8033 year: 1996 ident: ja052995xb00014/ja052995xb00014_5 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja9604830 contributor: fullname: Diamond G. M. – volume: 24 start-page: 1328 year: 2005 ident: ja052995xb00013/ja052995xb00013_1 publication-title: Organometallics contributor: fullname: Song F. – ident: ja052995xb00014/ja052995xb00014_7 – volume: 27 start-page: 4626 year: 1994 ident: ja052995xb00007/ja052995xb00007_4 publication-title: J. Macromolecules contributor: fullname: Yang X. M. – volume: 127 start-page: 10909 year: 2005 ident: ja052995xb00013/ja052995xb00013_8 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0429622 contributor: fullname: Stahl N. G. – volume: 43 start-page: 1806 year: 2004 ident: ja052995xb00035/ja052995xb00035_1 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200200548 contributor: fullname: Scherer W. – volume: 9 start-page: 1191 year: 1990 ident: ja052995xb00039/ja052995xb00039_6 publication-title: Organometallics doi: 10.1021/om00118a046 contributor: fullname: Agbossou S. K. – volume: 113 start-page: 2625 year: 1991 ident: ja052995xb00013/ja052995xb00013_6 publication-title: J. Am. Chem. Soc. contributor: fullname: Yang X. – volume: 119 start-page: 2949 year: 1997 ident: ja052995xb00002/ja052995xb00002_7 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja9638770 contributor: fullname: Molenveld P. – volume: 33 start-page: 532 year: 1982 ident: ja052995xb00031/ja052995xb00031_2 publication-title: Annu. Rev. Phys. Chem. contributor: fullname: McMillan D. F. – volume: 121 start-page: 5265 year: 1999 ident: ja052995xb00001/ja052995xb00001_5 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja9839769 contributor: fullname: O'Brien D. P. – volume-title: November 25, 1992. ident: ja052995xb00005/ja052995xb00005_8 contributor: fullname: Devore D. D. – volume: 124 start-page: 12063 year: 2002 ident: ja052995xb00036/ja052995xb00036_2 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja026608k contributor: fullname: Landis C. R. – volume: 120 start-page: 10781 year: 1998 ident: ja052995xb00002/ja052995xb00002_6 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja982683c contributor: fullname: Konsler R. G. – volume: 13 start-page: 2243 year: 1994 ident: ja052995xb00013/ja052995xb00013_7 publication-title: Organometallics doi: 10.1021/om00018a017 contributor: fullname: Bochmann M. – volume: 122 start-page: 10370 year: 2000 ident: ja052995xb00017/ja052995xb00017_2 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja000810a contributor: fullname: Beswick C. L. – volume: 6 start-page: 3292 year: 2000 ident: ja052995xb00039/ja052995xb00039_3 publication-title: Chem.Eur. J. doi: 10.1002/1521-3765(20000901)6:17<3287::AID-CHEM3287>3.0.CO;2-J contributor: fullname: Rybtchinski B. – volume: 29 start-page: 86 year: 2000 ident: ja052995xb00002/ja052995xb00002_5 publication-title: Chem. Soc. Rev. doi: 10.1039/a804295k contributor: fullname: Molenveld P. – volume: 16 start-page: 3050 year: 1997 ident: ja052995xb00014/ja052995xb00014_1 publication-title: Organometallics doi: 10.1021/om970242g contributor: fullname: Christopher J. N. – volume: 125 start-page: 4423 year: 2003 ident: ja052995xb00001/ja052995xb00001_2 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0346577 contributor: fullname: Krishnan R. – volume: 126 start-page: 1464 year: 2004 ident: ja052995xb00017/ja052995xb00017_1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0387296 contributor: fullname: Zuccaccia C. – volume: 23 start-page: 4502 year: 2004 ident: ja052995xb00013/ja052995xb00013_2 publication-title: Organometallics doi: 10.1021/om040057k contributor: fullname: Hannig F. – volume: 35 start-page: 2256 year: 1996 ident: ja052995xb00002/ja052995xb00002_8 publication-title: Angew. Chem., Int. Ed. Engl. doi: 10.1002/anie.199622561 contributor: fullname: Mathews R. C. – volume: 125 start-page: 2411 year: 2003 ident: ja052995xb00002/ja052995xb00002_3 publication-title: J. Am. Chem. Soc. contributor: fullname: Trost B. M. – volume: 16 start-page: 2885 year: 1997 ident: ja052995xb00016/ja052995xb00016_4 publication-title: Organometallics doi: 10.1021/om9609628 contributor: fullname: McKnight A. L. – volume: 31 start-page: 5147 year: 1998 ident: ja052995xb00028/ja052995xb00028_1 publication-title: Macromolecules doi: 10.1021/ma980196b contributor: fullname: Shaffer T. D. – volume: 35 start-page: 609 year: 2002 ident: ja052995xb00011/ja052995xb00011_2 publication-title: Macromolecules contributor: fullname: Ness J. S. – volume: 34 start-page: 1741 year: 2001 ident: ja052995xb00010/ja052995xb00010_1 publication-title: Macromolecules contributor: fullname: Zhao J. – volume: 118 start-page: 7913 year: 1996 ident: ja052995xb00007/ja052995xb00007_2 publication-title: J. Am. Chem. Soc. contributor: fullname: Jia L. – volume: 20 start-page: 4261 year: 2001 ident: ja052995xb00038/ja052995xb00038_1 publication-title: Organometallics doi: 10.1021/om010363n contributor: fullname: Brandow C. G. – volume: 30 start-page: 3697 year: 1997 ident: ja052995xb00009/ja052995xb00009_4 publication-title: Macromolecules doi: 10.1021/ma961331s contributor: fullname: Natori I. – volume: 400 start-page: 181 year: 1999 ident: ja052995xb00001/ja052995xb00001_6 publication-title: Nature doi: 10.1038/22139 contributor: fullname: Carazo-Salas R. E. – volume: 19 start-page: 1276 year: 2000 ident: ja052995xb00016/ja052995xb00016_2 publication-title: Organometallics contributor: fullname: Park J. T. – volume: 14 start-page: 250 year: 1976 ident: ja052995xb00029/ja052995xb00029_1 publication-title: J. Macromol. Sci., Rev. Macromol. Chem. doi: 10.1080/15321797608065770 contributor: fullname: Johnston N. W. – volume: 12 start-page: 1767 year: 2000 ident: ja052995xb00005/ja052995xb00005_1 publication-title: J. Adv. Mater. contributor: fullname: Chum P. S. – volume: 107 start-page: 3378 year: 1985 ident: ja052995xb00035/ja052995xb00035_9 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00297a070 contributor: fullname: Clawson L. – volume: 29 start-page: 93 year: 1996 ident: ja052995xb00036/ja052995xb00036_4 publication-title: Acc. Chem. Res. doi: 10.1021/ar9501683 contributor: fullname: Grubbs R. H. – volume-title: Part B: Polym. Phys year: 1998 ident: ja052995xb00009/ja052995xb00009_3 contributor: fullname: Natori I. – volume: 38 start-page: 1409 year: 2005 ident: ja052995xb00024/ja052995xb00024_1 publication-title: Macromolecules contributor: fullname: Light – volume: 123 start-page: 11207 year: 2001 ident: ja052995xb00026/ja052995xb00026_1 publication-title: J. Am. Chem. Soc. contributor: fullname: Liu Z. – volume: 20 start-page: 4017 year: 2001 ident: ja052995xb00018/ja052995xb00018_2 publication-title: J. Organometallics doi: 10.1021/om0102899 contributor: fullname: Lanza G. – volume: 12 start-page: 1858 year: 2000 ident: ja052995xb00010/ja052995xb00010_2 publication-title: Adv. Mater. doi: 10.1002/1521-4095(200012)12:23<1855::AID-ADMA1855>3.0.CO;2-P contributor: fullname: Hucul D. A. – volume-title: Patent Appl. EP 420 436-A1 year: 1991 ident: ja052995xb00005/ja052995xb00005_7 contributor: fullname: Canich J. M. – ident: ja052995xb00031/ja052995xb00031_1 – volume: 646 start-page: 467 year: 2002 ident: ja052995xb00008/ja052995xb00008_2 publication-title: Chem. Commun. contributor: fullname: Takeuchi D. – volume: 29 start-page: 1413 year: 1990 ident: ja052995xb00035/ja052995xb00035_6 publication-title: Angew. Chem., Int. Ed. Engl. doi: 10.1002/anie.199014121 contributor: fullname: Krauledat H. – volume: 15 start-page: 1581 year: 1996 ident: ja052995xb00014/ja052995xb00014_6 publication-title: Organometallics contributor: fullname: Carpenetti D. W. – volume: 229 start-page: 354 year: 1995 ident: ja052995xb00030/ja052995xb00030_1 publication-title: J. Inorg. Chim. Acta contributor: fullname: King W. A. – volume: 202 start-page: 2446 year: 2001 ident: ja052995xb00039/ja052995xb00039_2 publication-title: Macromol. Chem. Phys. contributor: fullname: Kawabe M. – volume: 35 start-page: 148 year: 2002 ident: ja052995xb00001/ja052995xb00001_3 publication-title: Acc. Chem. Res. doi: 10.1021/ar0001665 contributor: fullname: Bruice T. C. – volume-title: Handbook of Polyolefins year: 2000 ident: ja052995xb00009/ja052995xb00009_1 contributor: fullname: Kulshrestha A. K. – volume: 16 start-page: 3894 year: 1997 ident: ja052995xb00035/ja052995xb00035_2 publication-title: Organometallics doi: 10.1021/om970227b contributor: fullname: Prosenc M. H. – volume: 36 start-page: 76 year: 2003 ident: ja052995xb00011/ja052995xb00011_1 publication-title: Macromolecules contributor: fullname: Hahn S. F. – volume: 15 start-page: 2677 year: 1996 ident: ja052995xb00032/ja052995xb00032_1 publication-title: Organometallics contributor: fullname: Horton A. D. – volume: 100 start-page: 1478 year: 2000 ident: ja052995xb00021/ja052995xb00021_1 publication-title: Chem. Rev. doi: 10.1021/cr990252m contributor: fullname: Baird M. C. – ident: ja052995xb00023/ja052995xb00023_1 publication-title: J. Macromolecules, in press. contributor: fullname: The – volume: 114 start-page: 4181 year: 1992 ident: ja052995xb00039/ja052995xb00039_5 publication-title: J. Am. Chem. Soc. contributor: fullname: Peng T. S. – ident: ja052995xb00005/ja052995xb00005_6 – ident: ja052995xb00033/ja052995xb00033_1 – volume: 125 start-page: 11924 year: 2003 ident: ja052995xb00002/ja052995xb00002_2 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja030085e contributor: fullname: Moore D. R. – volume: 37 start-page: 4940 year: 2004 ident: ja052995xb00004/ja052995xb00004_1 publication-title: J. Angew. Chem., Int. Ed. contributor: fullname: For – volume: 127 start-page: 47 year: 2005 ident: ja052995xb00006/ja052995xb00006_1 publication-title: J. Am. Chem. Soc. contributor: fullname: Similar – volume-title: Thermochemical Kinetics year: 1976 ident: ja052995xb00031/ja052995xb00031_3 contributor: fullname: Benson S. W. – volume: 6 volume-title: Encyclopedia of Polymer Science and Engineering year: 1985 ident: ja052995xb00009/ja052995xb00009_6 contributor: fullname: James D. – volume: 118 start-page: 1548 year: 1996 ident: ja052995xb00007/ja052995xb00007_3 publication-title: J. Am. Chem. Soc. contributor: fullname: Jia L. – volume: 23 start-page: 754 year: 2004 ident: ja052995xb00007/ja052995xb00007_1 publication-title: J. Organometallics doi: 10.1021/om030407n contributor: fullname: Jensen T. R. – volume: 123 start-page: 1489 year: 2001 ident: ja052995xb00013/ja052995xb00013_3 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja003531w contributor: fullname: Beck S. |
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| Snippet | This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs), (μ-CH2CH2-3,3‘){(η5-indenyl)[1-Me2Si( t... This contribution describes the implementation of the binuclear organotitanium "constrained geometry catalysts" (CGCs),... |
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| SubjectTerms | Alkenes - chemical synthesis Alkenes - chemistry Applied sciences Carbon Isotopes Catalysis Chemistry Chemistry, Multidisciplinary Copolymerization Crystallography, X-Ray Ethylenes - chemistry Exact sciences and technology Magnetic Resonance Spectroscopy Metals, Heavy - chemistry Models, Molecular Molecular Structure Organic polymers Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Physical Sciences Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts Science & Technology |
| Title | Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene: Enhanced Enchainment Mediated by Binuclear Catalysts and Cocatalysts |
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