Hydrogenation of Benzene Using Aqueous Solution of Polyoxometalates Reduced by CO over Gold Catalysts
Aqueous polyoxometalate (H3PMo12O40) solution reduced by CO with liquid water using gold nanoparticle catalysts at room temperature, which contains protons in liquid water and electrons associated with the reduced polyoxometalate, can produce gaseous H2 or can hydrogenate benzene over an electrochem...
Saved in:
Published in | Journal of the American Chemical Society Vol. 127; no. 31; pp. 10790 - 10791 |
---|---|
Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
10.08.2005
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | Aqueous polyoxometalate (H3PMo12O40) solution reduced by CO with liquid water using gold nanoparticle catalysts at room temperature, which contains protons in liquid water and electrons associated with the reduced polyoxometalate, can produce gaseous H2 or can hydrogenate benzene over an electrochemical cell consisting of a simple carbon anode, a proton-exchange membrane, and a Pt- or Rh-based cathode. In the present cell, H2 can be produced from the reduced H3PMo12O40 solution at voltages that are lower by about 1.15 V compared to water electrolysis. |
---|---|
AbstractList | Aqueous polyoxometalate (H3PMo12O40) solution reduced by CO with liquid water using gold nanoparticle catalysts at room temperature, which contains protons in liquid water and electrons associated with the reduced polyoxometalate, can produce gaseous H2 or can hydrogenate benzene over an electrochemical cell consisting of a simple carbon anode, a proton-exchange membrane, and a Pt- or Rh-based cathode. In the present cell, H2 can be produced from the reduced H3PMo12O40 solution at voltages that are lower by about 1.15 V compared to water electrolysis. |
Author | Voitl, Tobias Kim, Won Bae Rodriguez-Rivera, Gabriel J Evans, Steven T Dumesic, James A |
Author_xml | – sequence: 1 givenname: Gabriel J surname: Rodriguez-Rivera fullname: Rodriguez-Rivera, Gabriel J – sequence: 2 givenname: Won Bae surname: Kim fullname: Kim, Won Bae – sequence: 3 givenname: Steven T surname: Evans fullname: Evans, Steven T – sequence: 4 givenname: Tobias surname: Voitl fullname: Voitl, Tobias – sequence: 5 givenname: James A surname: Dumesic fullname: Dumesic, James A |
BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17004828$$DView record in Pascal Francis https://www.ncbi.nlm.nih.gov/pubmed/16076159$$D View this record in MEDLINE/PubMed |
BookMark | eNptkE1v1DAQhi1URLeFA38A-QISh4DtxF_HEkELVLRiW3G0vM64ypK1i52ghl-PV7t0L5yskZ95Z-Y5QUchBkDoJSXvKGH0_doSzhpe-ydoQTkjFadMHKEFIYRVUon6GJ3kvC5lwxR9ho6pIFJQrhcILuYuxTsIduxjwNHjDxD-QAB8m_twh89-TRCnjJdxmP4R13GY40PcwGgHO0LG36GbHHR4NeP2CsffkPB5HDrc2kLMeczP0VNvhwwv9u8puv308aa9qC6vzj-3Z5eVrRUdKyFrClpp3VBbS99oLrXUfmUlB1erjnPJoGmUtJIJKZgH4ajmUPuGeSd0fYre7HLvUyyL59Fs-uxgGGzYXmGEKt2aqgK-3YEuxZwTeHOf-o1Ns6HEbJ2aR6eFfbUPnVYb6A7kXmIBXu8Bm50dfLLB9fnAyeJdse3Qasf1eYSHx3-bfppyueTm5npp2ubrt-UX8cPwQ6512azjlEJx958F_wKGt5qz |
CODEN | JACSAT |
CitedBy_id | crossref_primary_10_1016_j_apcata_2009_02_048 crossref_primary_10_1039_b514860j crossref_primary_10_1016_j_apsusc_2020_147709 crossref_primary_10_1080_00032719_2010_546031 crossref_primary_10_1016_j_coelec_2022_101207 crossref_primary_10_1002_chem_200901261 crossref_primary_10_1002_ange_200904647 crossref_primary_10_1080_00958972_2011_601460 crossref_primary_10_1021_acs_inorgchem_6b02167 crossref_primary_10_1080_00958972_2010_534467 crossref_primary_10_1021_cr200260m crossref_primary_10_1002_anie_200904647 crossref_primary_10_1002_ajoc_202300309 crossref_primary_10_1002_slct_201602070 crossref_primary_10_1021_jp077098p crossref_primary_10_1039_D0CY01722A crossref_primary_10_1039_c3gc00090g crossref_primary_10_1039_c1gc15307b |
Cites_doi | 10.1039/b211685e 10.1021/jp953326g 10.1016/0920-5861(95)00083-R 10.1016/j.molcata.2003.10.040 10.1002/anie.200461601 10.1016/S0920-5861(99)00288-6 10.1021/jp049421j 10.1126/science.1100860 10.1103/PhysRevB.68.075420 10.1002/anie.200351664 |
ContentType | Journal Article |
Copyright | Copyright © 2005 American Chemical Society 2005 INIST-CNRS |
Copyright_xml | – notice: Copyright © 2005 American Chemical Society – notice: 2005 INIST-CNRS |
DBID | BSCLL IQODW NPM AAYXX CITATION 7X8 |
DOI | 10.1021/ja052453f |
DatabaseName | Istex Pascal-Francis PubMed CrossRef MEDLINE - Academic |
DatabaseTitle | PubMed CrossRef MEDLINE - Academic |
DatabaseTitleList | PubMed MEDLINE - Academic |
Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 1520-5126 |
EndPage | 10791 |
ExternalDocumentID | 10_1021_ja052453f 16076159 17004828 ark_67375_TPS_C4KNSJ6W_5 b363453793 |
Genre | Journal Article |
GroupedDBID | - .K2 02 186 4.4 53G 55A 5GY 5RE 5VS 7~N 85S AABXI ABDEX ABFLS ABMVS ABPPZ ABPTK ABUCX ABUFD ACGFS ACJ ACNCT ACS AEESW AENEX AETEA AFEFF AFFDN AFFNX AFMIJ AIDAL ALMA_UNASSIGNED_HOLDINGS ANTXH AQSVZ BAANH BKOMP CS3 DU5 DZ EBS ED ED~ EJD ET F20 F5P GJ GNL IH9 IHE JG JG~ K2 K78 LG6 NHB OHT P2P ROL RXW TAE TAF TN5 UHB UI2 UKR UNC UPT UQL VF5 VG9 VQA W1F WH7 X XFK YZZ ZCG ZE2 ZHY --- -DZ -ET -~X .DC .GJ 6TJ AAYOK ABFRP ABJNI ABQRX ACBEA ACGFO ADHLV AGHSJ AGXLV AHGAQ BSCLL GGK IH2 XOL XSW YQT ZCA ~02 .HR 1WB 3EH 3O- 41~ AAUPJ AAYJJ ABHMW ABTAH ABWLT ACBNA ACKIV AFDAS AGJRR AI. D0S IQODW MVM P-O RNS UBC UBX VH1 X7L YXA YXE YYP ZGI ZY4 AAHBH CUPRZ NPM AAYXX CITATION 7X8 |
ID | FETCH-LOGICAL-a381t-6731e989941a37f4957979fba75ec38d5572e4487a726762fe6c195e3f42fc693 |
IEDL.DBID | ACS |
ISSN | 0002-7863 |
IngestDate | Fri Aug 16 02:17:52 EDT 2024 Thu Sep 26 23:55:23 EDT 2024 Sat Sep 28 07:45:48 EDT 2024 Sun Oct 29 17:09:39 EDT 2023 Wed Jan 17 04:51:55 EST 2024 Thu Aug 27 13:41:59 EDT 2020 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 31 |
Keywords | Mixed catalyst Hydrogen transfer Catalytic reaction Hydrocarbon Electrocatalysts Experimental study Hydrogenation Cyclic voltammetry Heteropolyacid Benzene Reaction mechanism Carbon monoxide Kinetic parameter Aqueous solution Rate constant Electrochemical reaction |
Language | English |
License | CC BY 4.0 |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-a381t-6731e989941a37f4957979fba75ec38d5572e4487a726762fe6c195e3f42fc693 |
Notes | ark:/67375/TPS-C4KNSJ6W-5 istex:D88C2EAED56CF7064E3199D2EA1E2D94A9D41E9D ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
PMID | 16076159 |
PQID | 68448918 |
PQPubID | 23479 |
PageCount | 2 |
ParticipantIDs | proquest_miscellaneous_68448918 crossref_primary_10_1021_ja052453f pubmed_primary_16076159 pascalfrancis_primary_17004828 istex_primary_ark_67375_TPS_C4KNSJ6W_5 acs_journals_10_1021_ja052453f |
ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N ACJ VG9 W1F ANTXH ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 |
PublicationCentury | 2000 |
PublicationDate | 2005-08-10 |
PublicationDateYYYYMMDD | 2005-08-10 |
PublicationDate_xml | – month: 08 year: 2005 text: 2005-08-10 day: 10 |
PublicationDecade | 2000 |
PublicationPlace | Washington, DC |
PublicationPlace_xml | – name: Washington, DC – name: United States |
PublicationTitle | Journal of the American Chemical Society |
PublicationTitleAlternate | J. Am. Chem. Soc |
PublicationYear | 2005 |
Publisher | American Chemical Society |
Publisher_xml | – name: American Chemical Society |
References | Desai S. K. (ja052453fb00004/ja052453fb00004_1) 2003; 68 Kim W. B. (ja052453fb00003/ja052453fb00003_1) 2005; 44 Davda R. R. (ja052453fb00001/ja052453fb00001_1) 2003; 42 ja052453fb00008/ja052453fb00008_1 Gomez-Romero P. (ja052453fb00009/ja052453fb00009_1) 1996; 100 Itoh N. (ja052453fb00006/ja052453fb00006_1) 2000; 56 ja052453fb00007/ja052453fb00007_1 Saeys M. (ja052453fb00010/ja052453fb00010_1) 2005; 109 Kim W. B. (ja052453fb00002/ja052453fb00002_1) 2004; 305 Itoh N. (ja052453fb00005/ja052453fb00005_1) 1995; 25 |
References_xml | – ident: ja052453fb00007/ja052453fb00007_1 doi: 10.1039/b211685e – volume: 100 start-page: 12448 year: 1996 ident: ja052453fb00009/ja052453fb00009_1 publication-title: J. Phys. Chem. doi: 10.1021/jp953326g contributor: fullname: Gomez-Romero P. – volume: 25 start-page: 351 year: 1995 ident: ja052453fb00005/ja052453fb00005_1 publication-title: Catal. Today doi: 10.1016/0920-5861(95)00083-R contributor: fullname: Itoh N. – ident: ja052453fb00008/ja052453fb00008_1 doi: 10.1016/j.molcata.2003.10.040 – volume: 44 start-page: 778 year: 2005 ident: ja052453fb00003/ja052453fb00003_1 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200461601 contributor: fullname: Kim W. B. – volume: 56 start-page: 307 year: 2000 ident: ja052453fb00006/ja052453fb00006_1 publication-title: Catal. Today doi: 10.1016/S0920-5861(99)00288-6 contributor: fullname: Itoh N. – volume: 109 start-page: 2064 year: 2005 ident: ja052453fb00010/ja052453fb00010_1 publication-title: J. Phys. Chem. B doi: 10.1021/jp049421j contributor: fullname: Saeys M. – volume: 305 start-page: 1280 year: 2004 ident: ja052453fb00002/ja052453fb00002_1 publication-title: Science doi: 10.1126/science.1100860 contributor: fullname: Kim W. B. – volume: 68 start-page: 075420 year: 2003 ident: ja052453fb00004/ja052453fb00004_1 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.68.075420 contributor: fullname: Desai S. K. – volume: 42 start-page: 4068 year: 2003 ident: ja052453fb00001/ja052453fb00001_1 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200351664 contributor: fullname: Davda R. R. |
SSID | ssj0004281 |
Score | 1.9624008 |
Snippet | Aqueous polyoxometalate (H3PMo12O40) solution reduced by CO with liquid water using gold nanoparticle catalysts at room temperature, which contains protons in... |
SourceID | proquest crossref pubmed pascalfrancis istex acs |
SourceType | Aggregation Database Index Database Publisher |
StartPage | 10790 |
SubjectTerms | Chemistry Electrochemistry Exact sciences and technology General and physical chemistry Kinetics and mechanism of reactions |
Title | Hydrogenation of Benzene Using Aqueous Solution of Polyoxometalates Reduced by CO over Gold Catalysts |
URI | http://dx.doi.org/10.1021/ja052453f https://api.istex.fr/ark:/67375/TPS-C4KNSJ6W-5/fulltext.pdf https://www.ncbi.nlm.nih.gov/pubmed/16076159 https://search.proquest.com/docview/68448918 |
Volume | 127 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwhV1LU9RAEO5COOgF37KoOKWWt1CbSeaRIwZxC0ukXCi5pSbzuIAJtclWsfx6u5MNK6XofSbJdHemv57u_gbgvVN67NzYR94KHaVGhygTtow8T4yMgy6DpObkr0dycpoenomzNXh3RwafEz_QWPBUJOEebHCqHCT8k09XzY9cxwPGVVomA33Q71PJ9djmluvZICleUSmkaVAaob_G4m6c2fmbg4ewP3Tt9GUm57vztty113-SOP5rKY9gc4k32V5vII9hzVdP4H4-XPP2FPxk4WY1mlGnIlYH9tFX17gDsq6agO3hZ9bzhg3nZzTiuL5Y1Ff1T4_InbAq-04EsN6xcsHyb4yqQtnn-sKxnA6HFk3bPIPTg08n-SRa3r0QGfThLXUExD7DYCyNTaJCStk8lYXSKOFtop0QinsM7ZRRXOKGGry0cSZ8ElIerMyS57Be1ZXfAiasMsbgzoEBa-oRkHKlbYl-0DmZOOFGsIPKKZb_TlN0aXGOYckgrRG8HfRWXPYcHH8b9KHT6M0IMzunojUlipPjaZGnX46mh_JHIfB1t1S-eiQx_WMAOoI3gw0UqAtKoJiKJF1IjSvOYhzxojeN1VxJ50Ei2_7fWl7Cg478tSPVfQXr7WzuXyOsacudzqx_AZyp794 |
link.rule.ids | 315,786,790,2782,27109,27957,27958,57093,57143 |
linkProvider | American Chemical Society |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1LT9wwELZaONALpS_YPsCqqt6CNg8_cqQRdMtji7qLys1y_LgACdpkJZZf3xln0y1Vq_Y-duyZiWfGM_OZkA9WyKG1Qxc5w2SUaemjnJkyckmqeexl6Tk2J5-N-egiO75kl0uYHOyFgUU0MFMTkvgrdAGECRqyJGOpf0zWmYA4HN2gYrLqgUxk3Lu6QvK0RxH6dShaINM8sEDryMw7rIjUDTDFd69Z_N3dDGbn6Gn3flFYcKg2udqft-W-uf8Ny_H_drRFNpfeJz3o1OUZeeSq52Sj6B99e0HcaGFnNShVEBitPf3kqns4D2moLaAHsNp63tD-Ng0pzuvrRX1X3zjw49Fzpd8QDtZZWi5o8ZVijSj9XF9bWuBV0aJpm5fk4uhwWoyi5UsMkQaL3mJ_QOxyCM2yWKfCZ5jbE7kvtWDOpNIyJhIHgZ7QIuFwvHrHTZwzl_os8Ybn6SuyVtWV2yGUGaG1hnMEwtfMgXuaCGlKsIrW8tQyOyC7wCy1_JMaFZLkCQQpPbcG5H0vPnXbIXL8iehjEOxPCj27whI2wdT0fKKK7GQ8OebfFYPPPZD8akrE_YdwdED2elVQIAtMp-gKOa24hB3nMVBsdxqyGsvxdojlr_-1lz2yMZqenarTL-OTN-RJgIUNcLtvyVo7m7t34PC05W7Q9B8WHPhJ |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1Lb9QwELaglYBLeRa2QGshxC3V5uFHjiWwLC1sV2wrerMcPy4tSbXJSt3-ema8SZciENzHiT0z9sx4Zj4T8tYKObR26CJnmIwyLX2UM1NGLkk1j70sPcfm5K8TPj7NDs_YWRcoYi8MTKKBLzUhiY-7-tL6DmEAoYKGLMlY6u-STYYPd6MrVMzWfZCJjHt3V0ie9khCvw5FK2SaW1ZoExl6hVWRugHG-NWLFn93OYPpGT0kxzeTDhUn5_uLttw317_hOf7_qh6Rrc4LpQcrtXlM7rjqCblf9I-_PSVuvLTzGpQrCI7Wnr531TWcizTUGNADmHG9aGh_q4YU0_piWV_VPxz48-jB0m8IC-ssLZe0OKZYK0o_1ReWFnhltGza5hk5HX08KcZR9yJDpMGyt9gnELscQrQs1qnwGeb4RO5LLZgzqbSMicRBwCe0SDgcs95xE-fMpT5LvOF5uk02qrpyLwhlRmit4TyBMDZz4KYmQpoSrKO1PLXMDsguMEx1O6pRIVmeQLDSc2tA3vQiVJcrZI4_Eb0Lwr2h0PNzLGUTTJ1MZ6rIjiazQ_5dMfjdLemvP4n4_xCWDsherw4KZIFpFV0hpxWXsOI8BornKy1Zj-V4S8TynX-tZY_cm34YqS-fJ0cvyYOADhtQd1-RjXa-cK_B72nL3aDsPwEmFPrD |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Hydrogenation+of+Benzene+Using+Aqueous+Solution+of+Polyoxometalates+Reduced+by+CO+over+Gold+Catalysts&rft.jtitle=Journal+of+the+American+Chemical+Society&rft.au=Rodriguez-Rivera%2C+Gabriel+J&rft.au=Kim%2C+Won+Bae&rft.au=Evans%2C+Steven+T&rft.au=Voitl%2C+Tobias&rft.date=2005-08-10&rft.pub=American+Chemical+Society&rft.issn=0002-7863&rft.eissn=1520-5126&rft.volume=127&rft.issue=31&rft.spage=10790&rft.epage=10791&rft_id=info:doi/10.1021%2Fja052453f&rft.externalDocID=b363453793 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0002-7863&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0002-7863&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0002-7863&client=summon |