Recognition of Carboxylate Anions and Carboxylic Acids by Selenium-Based New Chromogenic Fluorescent Sensor: A Remarkable Fluorescence Enhancement of Hindered Carboxylates
A selenium metal-based new fluorescence sensor 5-pivaloylamino-1,2,5-selenodiazolo[3,4-d]pyrimidin-7-(6H)-one (receptor 1) has been reported for the recognition of monocarboxylic acids and carboxylate anions both by UV−vis and fluorescence methods. Receptor 1 recognizes carboxylate anions more than...
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Published in | Organic letters Vol. 11; no. 19; pp. 4350 - 4353 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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01.10.2009
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Abstract | A selenium metal-based new fluorescence sensor 5-pivaloylamino-1,2,5-selenodiazolo[3,4-d]pyrimidin-7-(6H)-one (receptor 1) has been reported for the recognition of monocarboxylic acids and carboxylate anions both by UV−vis and fluorescence methods. Receptor 1 recognizes carboxylate anions more than monocarboxylic acids and it is a selective sensor for carboxylates with specially hindered carboxylate anions. The changes of fluorescence intensity are remarkably enhanced with red shift in presence of bulky carboxylate anions. The X-ray crystal structure of receptor 1 with pivalic acid has been reported. |
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AbstractList | A selenium metal-based new fluorescence sensor 5-pivaloylamino-1,2,5-selenodiazolo[3,4-d]pyrimidin-7-(6H)-one (receptor 1) has been reported for the recognition of monocarboxylic acids and carboxylate anions both by UV-vis and fluorescence methods. Receptor 1 recognizes carboxylate anions more than monocarboxylic acids and it is a selective sensor for carboxylates with specially hindered carboxylate anions. The changes of fluorescence intensity are remarkably enhanced with red shift in presence of bulky carboxylate anions. The X-ray crystal structure of receptor 1 with pivalic acid has been reported.A selenium metal-based new fluorescence sensor 5-pivaloylamino-1,2,5-selenodiazolo[3,4-d]pyrimidin-7-(6H)-one (receptor 1) has been reported for the recognition of monocarboxylic acids and carboxylate anions both by UV-vis and fluorescence methods. Receptor 1 recognizes carboxylate anions more than monocarboxylic acids and it is a selective sensor for carboxylates with specially hindered carboxylate anions. The changes of fluorescence intensity are remarkably enhanced with red shift in presence of bulky carboxylate anions. The X-ray crystal structure of receptor 1 with pivalic acid has been reported. A selenium metal-based new fluorescence sensor 5-pivaloylamino-1,2,5-selenodiazolo[3,4-d]pyrimidin-7-(6H)-one (receptor 1) has been reported for the recognition of monocarboxylic acids and carboxylate anions both by UV-vis and fluorescence methods. Receptor 1 recognizes carboxylate anions more than monocarboxylic acids and it is a selective sensor for carboxylates with specially hindered carboxylate anions. The changes of fluorescence intensity are remarkably enhanced with red shift in presence of bulky carboxylate anions. The X-ray crystal structure of receptor 1 with pivalic acid has been reported. A selenium metal-based new fluorescence sensor 5-pivaloylamino-1,2,5-selenodiazolo[3,4-d]pyrimidin-7-(6H)-one (receptor 1) has been reported for the recognition of monocarboxylic acids and carboxylate anions both by UV−vis and fluorescence methods. Receptor 1 recognizes carboxylate anions more than monocarboxylic acids and it is a selective sensor for carboxylates with specially hindered carboxylate anions. The changes of fluorescence intensity are remarkably enhanced with red shift in presence of bulky carboxylate anions. The X-ray crystal structure of receptor 1 with pivalic acid has been reported. |
Author | Fun, Hoong-Kun Goswami, Shyamaprosad Hazra, Anita Chakrabarty, Rinku |
Author_xml | – sequence: 1 givenname: Shyamaprosad surname: Goswami fullname: Goswami, Shyamaprosad email: spgoswamical@yahoo.com, hkfun@usm.my – sequence: 2 givenname: Anita surname: Hazra fullname: Hazra, Anita – sequence: 3 givenname: Rinku surname: Chakrabarty fullname: Chakrabarty, Rinku – sequence: 4 givenname: Hoong-Kun surname: Fun fullname: Fun, Hoong-Kun |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/19728733$$D View this record in MEDLINE/PubMed |
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Snippet | A selenium metal-based new fluorescence sensor 5-pivaloylamino-1,2,5-selenodiazolo[3,4-d]pyrimidin-7-(6H)-one (receptor 1) has been reported for the... |
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SubjectTerms | Carboxylic Acids - chemistry Chemistry Chemistry, Organic Crystallography, X-Ray Fluorescence Fluorescent Dyes - chemistry Models, Molecular Molecular Structure Organoselenium Compounds - chemistry Physical Sciences Science & Technology |
Title | Recognition of Carboxylate Anions and Carboxylic Acids by Selenium-Based New Chromogenic Fluorescent Sensor: A Remarkable Fluorescence Enhancement of Hindered Carboxylates |
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