Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)2/Pyridine - Ye, Xuan; Liu, Guosheng; Popp, Brian V; Stahl, Shannon S (Journal of organic chemistry, 2011)
Keywords: Alkenes - chemistry; Amination; Catalysis; Catalysts: preparations and properties; Chemistry; Exact sciences and technology; General and physical chemistry; Heterocyclic compounds; Heterocyclic compounds with only one n hetero atom and condensed derivatives; Kinetics and mechanisms; Ligands; Molecular Structure; Organic chemistry; Organometallic Compounds - chemistry; Oxidation-Reduction; Palladium - chemistry; Preparations and properties; Pyridines - chemistry; Reactivity and mechanisms; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Bond length; Nitrogen heterocycle; Ligand; Hydrides; Pyrrolidine derivatives; Chemical reduction; Alkene; Amination; Wacker Oxidation; Reaction mechanism; Palladium II Acetate; Intramolecular reaction; Catalytic reaction; Theoretical study; Stepwise mechanism; Aerobe; Acetic acid derivative; Experimental study; Steady state; Pyridine; Cyclization; Transition state; Density functional method; Chelates; Catalyst; Ethylenic compound; Nucleophile