Reductive Electrosynthesis of Crystalline Metal–Organic Frameworks

Electroreduction of oxoanions affords hydroxide equivalents that induce selective deposition of crystalline metal–organic frameworks (MOFs) on conductive surfaces. The method is illustrated by cathodic electrodeposition of Zn4O(BDC)3 (MOF-5; BDC = 1,4-benzenedicarboxylate), which is deposited at roo...

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 133; no. 33; pp. 12926 - 12929
Main Authors Li, Minyuan, Dincă, Mircea
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 24.08.2011
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